公开(公告)号：EP0672453A2

公开(公告)日：1995-09-20

申请号：EP95301022.0

申请日：1995-02-17

Applicant: THE STANDARD OIL COMPANY

Inventor： Blum, Patricia Rae ,  Cirjak, Larry Michael ,  Lemanski, Michael Francis ,  Paparizos, Christos ,  Pepera, Marc Anthony ,  Suresh, Devasirvatham Dhanarah

IPC: B01J32/00 ,  B01J35/10 ,  B01J37/00 ,  C07C67/05 ,  C07C69/15 ,  B01J23/56

CPC classification number: B01J23/63 ,  B01J21/08 ,  B01J23/44 ,  B01J23/52 ,  B01J23/56 ,  B01J23/58 ,  B01J35/08 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J37/0045 ,  C07C67/055 ,  C07C69/01 ,  C07C69/15

Abstract: A process for the preparation of a fluid bed vinyl acetate (VAM) catalyst comprising impregnating a support comprising a mixture of substantially inert microspheroidal particles with a solution comprising a halide-free metal salt of Pd and M, wherein M comprises Ba, Au, La, Nb, Ce, Zn, Pb, Ca, Sr, Sb or mixtures thereof, reducing the metal salts to form a deposit of Pd and M on the support surface and impregnating the support with at least one halide-free alkali metal salt. At least 50% of the particles used for the microspheroidal support have a particle size below 100 microns, preferably below 60 microns. The pore volume of these particles is from 0.2 to 0.7cm³/g and the surface area is from 100 to 200 m²/g.

Abstract translation: 一种用于在流化床乙酸乙烯酯的制备方法，（VAM）催化剂，包含浸渍载体，其包含基本上惰性的微球颗粒的混合物与溶液包含钯和M，worin M包括钡，金，镧一个无卤化物金属盐 ，铌，铈，锌，铅，钙，锶，锑或它们的混合物，还原金属盐以形成钯和M的支撑表面上的沉积物和与至少一种无卤化物的碱金属盐浸渍载体。 用于微球形载体颗粒的至少50％具有低于100微米的粒度，优选低于60微米。 论文颗粒的孔体积为0.2至0.7厘米<3> /克，表面积为100至200m <2> / g以下。

公开(公告)号：EP0671455A2

公开(公告)日：1995-09-13

申请号：EP95301187.1

申请日：1995-02-23

Applicant: THE STANDARD OIL COMPANY

Inventor： Eppig, Christopher P. ,  Robinson, Earl T. ,  Greenough, Paul, The British Petroleum Co. P.L.C.

IPC: C10G21/00 ,  C10G21/06

CPC classification number: C10G21/00

Abstract: A process for the treatment of a hydrocarbon blend containing nitrogen-containing compounds to effect removal of a portion of the nitrogen-containing compounds therefrom comprising (a) providing a hydrocarbon blend containing nitrogen-containing compounds; (b) contacting the hydrocarbon blend with a solvent which is characterised by (i) a liquid phase density at 25°C not less than 0.90g/cm³ and (ii) a Hansen polar solubility parameter δ P , and a Hansen hydrogen bonding parameter δ H , such that at 25°C 9.0 (cal/cm³) ½ P + δ H ) ½
to remove at least a portion of the nitrogen-containing compounds to form a purified hydrocarbon mixture; and (c) separating the purified hydrocarbon blend from the solvent and the nitrogen-containing compounds.

Abstract translation: 一种用于处理含有含氮化合物的烃共混物从而除去一部分含氮化合物的方法，包括（a）提供含有含氮化合物的烃共混物; （b）使烃共混物与溶剂接触，所述溶剂的特征在于：（i）25℃下的液相密度不小于0.90g / cm 3，和（ii）Hansen极性溶度参数δP和Hansen 氢键参数δH，使得在25℃下除去至少一部分含氮化合物以形成纯化的烃混合物; 和（c）从溶剂和含氮化合物中分离纯化的烃共混物。

公开(公告)号：EP0586066A3

公开(公告)日：1995-08-02

申请号：EP93305600.4

申请日：1993-07-16

Applicant: THE STANDARD OIL COMPANY

Inventor： Coffey, Gerald P. ,  Perec, Elena Simona ,  Standish, Norman W. ,  Melamud, Lucy ,  Smola, Jeff

IPC: C08L23/02

CPC classification number: C08L23/06 ,  C08L33/20 ,  C08L51/06 ,  C08L2205/03 ,  C08L2205/08 ,  C08L2666/04 ,  C08L2666/02

Abstract: Polymer blends having improved barrier properties comprising 85 to 99.5 weight percent polyolefin and 0.5 to 15 weight percent high nitrile polymer are disclosed. In addition, containers comprising 80 to 99.5 weight percent polyolefin and 0.5 to 20 weight percent high nitrile polymer are produced having improved barrier properties.

公开(公告)号：EP0643618A1

公开(公告)日：1995-03-22

申请号：EP93901192.0

申请日：1992-12-16

Applicant: THE STANDARD OIL COMPANY

Inventor： RUHL, Robert, C. ,  HARDMAN, Stephen ,  KENYON, Michael, R. Chota Ghar ,  McFARLANE, Roderick, A.

IPC: B01J8 ,  B01J19 ,  C01B3 ,  C10L3

CPC classification number: C01B3/384 ,  B01J8/008 ,  B01J8/025 ,  B01J8/0285 ,  B01J8/0453 ,  B01J8/062 ,  B01J2208/00203 ,  B01J2208/00407 ,  B01J2208/00495 ,  B01J2208/00504 ,  B01J2208/00513 ,  B01J2208/00522 ,  B01J2208/00716 ,  B01J2208/025 ,  C01B2203/0233 ,  C01B2203/0277 ,  C01B2203/0283 ,  C01B2203/061 ,  C01B2203/062 ,  C01B2203/068 ,  C01B2203/0811 ,  C01B2203/0816 ,  C01B2203/0822 ,  C01B2203/0866 ,  C01B2203/0883 ,  C01B2203/1011 ,  C01B2203/1052 ,  C01B2203/1076 ,  C01B2203/1082 ,  C01B2203/1241 ,  C01B2203/1604 ,  C01B2203/80 ,  C01B2203/82 ,  Y02P20/128

Abstract: An endothermic reaction furnace (102) includes one or more elongated tubes (110) defining therein an endothermic reaction flow path and a combustion flow path for providing heat to drive the endothermic reaction. The combustion flow path is arranged so that fuel and combustion air are separately heated by the heat inside the furnace (102) to significantly above their autoignition temperature before being combined in a combustion zone (116) where they mix, autoignite and burn.

公开(公告)号：EP0641771A1

公开(公告)日：1995-03-08

申请号：EP93307073.2

申请日：1993-09-08

Applicant: THE STANDARD OIL COMPANY

Inventor： Friedrich, Maria S. ,  Seeley, Michael J. ,  Paparizos, Christos ,  Suresh, Dev D.

IPC: C07C253/26

CPC classification number: B01J23/22 ,  B01J23/18 ,  B01J23/8892 ,  C01C3/0216 ,  C07C253/26 ,  Y02P20/52 ,  C07C255/08

Abstract: Disclosed is a method for ammoxidizing C₃ to C₅ mono-olefins to a,b-mono-unsaturated acyclic nitriles having 3 to 5 carbon atoms and HCN by introducing such mono-olefins molecular oxygen and ammonia into a reaction zone into vapor phase contact with a solid ammoxidation catalyst, wherein the mol ratio of introduced molecular oxygen and ammonia to said introduced mono-olefin is at least 1.5 and 1.0, respectively, wherein said catalyst contains the elements and proportions indicated by the empirical formula:



        V₁Sb a M m N n O x



where

a = 0.5 to 2
M = one or more of: Sn, Ti, Fe, and Ga
m = 0.05 to 3, usually at least 0.1 and at most 1
N = one or more of: W, Bi, Mo, Li, Mg, P, Zn, Mn, Te, Ge, Nb, Zr, Cr, Al, Cu, Ce, B
n = 0.0 to 0.5,
and wherein the preparation of the catalyst includes contacting in an aqueous dispersion a vanadium compound and an antimony compound while said vanadium is in solution.

Abstract translation: 公开了一种通过将这样的单烯烃分子氧和氨引入到反应区与气相接触的方法，将C3至C5单烯烃氧化为具有3至5个碳原子的α-单不饱和非环状腈和HCN 固体氨氧化催化剂，其中引入的分子氧和氨与所述引入的单烯烃的摩尔比分别为至少1.5和1.0，其中所述催化剂含有元素和由经验式表示的比例：V1SbaMmNnOx其中a = 0.5至2 M = Sn，Ti，Fe和Ga中的一种或多种：m = 0.05〜3，通常为0.1以上且1N以下= W，Bi，Mo，Li，Mg，P，Zn， Mn，Te，Ge，Nb，Zr，Cr，Al，Cu，Ce，B n = 0.0〜0.5，其中催化剂的制备包括在水分散体中使钒化合物与锑化合物接触， 解。

公开(公告)号：EP0274890B1

公开(公告)日：1995-03-01

申请号：EP87311187.6

申请日：1987-12-18

Applicant: THE STANDARD OIL COMPANY

Inventor： Szabo, Louis Frank ,  Biter, William Joseph

IPC: H01L21/441 ,  H01L31/02 ,  H01L31/12

CPC classification number: G06F8/31 ,  H01L21/443 ,  H01L31/022425 ,  H01L31/073 ,  Y02E10/543 ,  Y02P70/521

公开(公告)号：EP0407665B1

公开(公告)日：1995-02-08

申请号：EP89307132.4

申请日：1989-07-13

Applicant: THE STANDARD OIL COMPANY

Inventor： Davis, James C.

IPC: B01D71/82 ,  B01D71/68 ,  B01D67/00 ,  B01D69/00 ,  B01D15/08 ,  C07K1/22 ,  B01J20/26

CPC classification number: B01D67/0093 ,  B01D67/0011 ,  B01D69/141 ,  B01D71/52 ,  B01D71/68 ,  B01D71/76 ,  B01D71/82 ,  B01D2323/12 ,  B01D2325/36 ,  B01J20/28026 ,  B01J20/28033 ,  C07K14/765 ,  C12N9/16 ,  G01N33/545

公开(公告)号：EP0490507B1

公开(公告)日：1995-01-11

申请号：EP91310737.1

申请日：1991-11-21

Applicant: THE STANDARD OIL COMPANY

Inventor： Blum, Patricia R. ,  Lemanski, Michael F. ,  Hazen, Joseph B.

IPC: B01J27/185 ,  C07C51/25 ,  C07C53/08

CPC classification number: C07C51/25 ,  C07C53/08

公开(公告)号：EP0404408B1

公开(公告)日：1993-10-13

申请号：EP90306303.0

申请日：1990-06-08

Applicant: THE STANDARD OIL COMPANY

Inventor： Budge, John R.

IPC: B01J23/80 ,  B01J23/86 ,  C07D307/33 ,  C07D307/08

CPC classification number: C07D315/00 ,  B01J23/80 ,  B01J23/868 ,  B01J37/0221 ,  C07D307/08

公开(公告)号：EP0564110A1

公开(公告)日：1993-10-06

申请号：EP93301834.3

申请日：1993-03-10

Applicant: THE STANDARD OIL COMPANY

Inventor： Brazdil, James Frank ,  Little, Ian Raymond ,  Hazen, Joseph Brian

IPC: B01J23/22 ,  B01J37/03

CPC classification number: B01J23/14 ,  B01J23/22 ,  B01J37/0236 ,  B01J37/086 ,  C07C253/24 ,  Y02P20/52 ,  C07C255/08

Abstract: Disclosed is a method of making a catalyst containing vanadium antimony and tin in the oxide state which comprises making an aqueous slurry of a mixture of source batch materials comprising compounds of the elements to be included in the final catalyst followed by drying and heat calcining the mixture to an active catalyst, using as the source batch material for tin a stannous salt of a C₁ to C₁₈ acyclic, monocarboxylic acid containing no ethylenic or acetylenic carbon-to-carbon unsaturation.

Abstract translation: 公开了一种制备含有氧化钒中的钒锑和锡的催化剂的方法，该方法包括制备含有待包含在最终催化剂中的元素化合物的源批料的混合物的水性浆料，然后干燥并加热煅烧该混合物 使用活性催化剂，使用不含烯属或炔属碳 - 碳不饱和度的C1至C18无环单羧酸锡作为锡批料。