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公开(公告)号:SG52746A1
公开(公告)日:1998-09-28
申请号:SG1996008741
申请日:1995-12-01
Applicant: BASF AG
Inventor: NESTLER GERHARD , HERBST HOLGER , HAMMON ULRICH , DARLINGTON JERRY
IPC: C07C51/44 , C07C51/46 , C07C57/055 , C07C57/07 , C07C57/075
Abstract: A process for the sepn. of (meth)acrylic acid (I) from a mixt. contg. (a) (I), (b) inert, hydrophobic organic liq. with a higher b.pt. than (I) as main component and (c) lower aldehydes as minor components, comprises rectification with the addn. of a prim. amine and/or salts thereof (II). Also claimed are processes for the prodn. of (I) by gas-phase oxidn. of a 3C/4C starting material (III). Pref. liq. (b) contains diphenyl ether (DPE), and pref. comprises a mixt. of 70-75 wt.% DPE and 25-30 wt.% biphenyl contg. 0.1-25 wt.% (w.r.t. the mixt.) of dimethyl o-phthalate. Amine (II) is a hydrazine deriv., pref. the hydrazide of a carboxylic acid, esp. pref. adipic acid dihydrazide.
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公开(公告)号:SG50765A1
公开(公告)日:1998-07-20
申请号:SG1996010696
申请日:1996-09-27
Applicant: BASF AG
Inventor: HAMMON ULRICH , SCHLIEPHAKE VOLKER , PIES WOLFGANG , RAUH ULRICH
Abstract: A process for the rectification and sepn. of unsatd. carboxylic acids (I) from the solvents in which (I) are absorbed after the synthesis reaction. The process involves interrupting the rectification and flushing out the rectification column with basic soln.
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163.
公开(公告)号:CA2259162A1
公开(公告)日:1997-12-24
申请号:CA2259162
申请日:1997-06-19
Applicant: BASF AG
Inventor: RAUH ULRICH , PIES WOLFGANG , HAMMON ULRICH , SCHLIEPHAKE VOLKER
Abstract: In a method for removing low, medium and high-boiling by-products obtained when producing acrylic acids or methacrylic acids, the gaseous low-boiling byproducts are burned, whereby low and medium-boiling by-products hat have been dissolved in water, if desired together with high-boiling by-products that have been treated with the dissolvent, are taken to the burning stage.
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公开(公告)号:CA2174654A1
公开(公告)日:1995-04-27
申请号:CA2174654
申请日:1994-10-11
Applicant: BASF AG
Inventor: TENTEN ANDREAS , HAMMON ULRICH , WEIDLICH PETER
IPC: B01J23/00 , B01J23/28 , B01J23/88 , B01J23/887 , B01J23/888 , B01J37/00 , B01J37/02 , B01J37/08 , C07B33/00 , C07B35/04 , C07C51/25 , C07C57/04 , C07C57/055 , C07C253/26
Abstract: Proposed is a method of producing catalytically active multi-metal oxide compositions containing Mo and V, the method calling for a catalyst precursor compound to be calcined at a temperature of 300 to 450 ~C in an atmosphere consisting of inert gases and/or steam plus 0.5 to 4 % by vol. of O2 and, averaged over the calcination time, 1 to 8 % by vol. of NH3.
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公开(公告)号:DE3376801D1
公开(公告)日:1988-07-07
申请号:DE3376801
申请日:1983-08-08
Applicant: BASF AG
Inventor: HOELDERICH WOLFGANG DR , RIEKERT LOTHAR DR , KOTTER MICHAEL DR , HAMMON ULRICH
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