Abstract:
The invention relates to a method for operating a continuous heterogeneously catalysed gas-phase partial oxidation of at least one organic compound. Said method uses compressed air as the oxygen source, said air being filtered prior to compression.
Abstract:
The invention relates to a method for rectification separation of an acrylic acid-containing liquid consisting in supplying an acrylic acid-rich material flow to a rectification column upstream of a supplying area and in carrying out an inhibiting polymerisation in the top section of the rectification column with the aid of diacrylic acid.
Abstract:
The invention relates to a method for processing (meth)acrylic acid in the presence of at least one stabilising agent. A mixture which contains the stabilising agent and is essentially devoid of (meth)acrylic acid and arising from the processing is introduced into a distilling device, and a low boiling flow which contains the stabilising agent and which is obtained from mixture is reintroduced into the preparation.
Abstract:
A method for stabilizing polymerizable compounds with respect to polymerization during preparation, storage and/or transport, wherein at least one radical interceptor containing at least two glycine units is used with the proviso that the radical ethylene diamine tetraacetic acid (EDTA), diethylene triamine pentaacetic acid (DTPA), trans-1,2-cyclohexane diamine tetraacetic acid (CYDTA) and the alkaline and alkaline earth salts thereof.
Abstract:
A method for stabilizing chemical compounds containing at least one ethylenically unsaturated bond in order to prevent undesirable radical polymerization, whereby a nitroxyl radical and a chemical compound containing chemically bonded phosphorus are added to an unsaturated compound existing in the form of a pure substance or constituent in a mixture.
Abstract:
A method of charging catalyst tubes of a bundle of catalyst tubes in a structured fashion, in which uniformly predispensed portions of formulations of shaped catalyst bodies are used for producing a section of charge.
Abstract:
Removing solids from the tubes of a tubular heat exchanger comprises introducing a drill driven by a drilling machine into a tube of the heat exchanger, and cleaning out the solids contained in the tube.
Abstract:
A stabilizer mixture (I) comprises at least one radical trap containing at least two glycerol units with the proviso that it is not ethylenediamine tetraacetic acid (EDTA), diethylenetriamine pentaacetic acid (DTPA), trans-1,2-cyclohexane diamine tetraacetic acid (CYDTA) or their alkali or alkaline earth salts, and at least one other stabilizer or costabilizer. Independent claims are included for: (1) a mixture (II) comprising a stabilizer mixture (I) and at least one polymerizable compound; and (2) a process for the stabilization of polymerizable compounds during processing, storage and/or transport by use of the radical trap.
Abstract:
Organic compound(s) is prepared by heterogeneously catalyzed partial gas-phase oxidizing of organic precursor compound(s) in a reactor loaded with catalyst, and bringing portion of components of the reaction gas starting mixture from low initial pressure to higher final pressure using a compressor. The compressor used is a radial compressor.
Abstract:
A process for the production and/or processing of mixtures containing (meth)acrylic acid and/or (meth)acrylic acid esters comprises production and/or processing in the presence of a polymerization inhibitor and at least one oxygen containing gas that is at partially dosed in at an exit rate of at least 50 mm/s.