Abstract:
Carbon black-containing composite resin pre-expanded particles comprising 100 to 400 parts by mass of a polystyrene-based resin with respect to 100 parts by mass of a carbon black-containing polyolefin-based resin; having a carbon black content of 0.5 to 5.0% by mass and a bulk density of 0.015 to 0.25 g/cm 3 ; and having an outermost layer of 30 to 80 µm after undergoing the following tests: (a) one of the carbon black-containing composite resin pre-expanded particles is sliced into a 1-mm slice in such a way that cross-section surfaces of cells are exposed on both surfaces of the slice; (b) the obtained slice is immersed in toluene at 25°C for 24 hours to extract a polystyrene-based resin component as described above; (c) the cross-section surface of the slice is then subjected to magnified photographing by a microscope; (d) the obtained microscope image is observed.
Abstract:
A method of impregnating and purifying polylactic acid (PLA), wherein PLA resin beads are subjected to a liquid C02treatment, which involves impregnation and extraction comprising at least one impregnation and extraction step, in which the PLA resin beads are brought into contact with 0,01 -1000 kg pure liquid C02 /kg PLA in a reactor for a predetermined time period, at a temperature and pressure that prevents the beads from sticking together and foaming, and - a portion of the liquid C02 is drained from the PLA beads after completion of the impregnation and extraction step, at a temperature that prevents the beads from sticking together and foaming, and at which the C02 is in liquid form, while leaving at least 0,01 kg liquid C02/kg PLA, preferably 0,01-1 kg liquid C02/kg PLA in the reactor containing the PLA resin beads, followed by evacuation of C02 gas from the reactor so as to decrease the pressure to ambient pressure, whereby the remaining liquid C02 is evaporated, thereby decreasing the temperature so as to prevent foaming at ambient pressure.
Abstract translation:一种浸渍和净化聚乳酸(PLA)的方法,其中对PLA树脂珠进行液体CO 2处理,其包括浸渍和提取,其包括至少一个浸渍和提取步骤,其中PLA树脂珠与0接触, 01-1000kg纯液体CO 2 / kg PLA在反应器中预定的时间段,在防止珠子粘在一起并起泡的温度和压力下,和 - 一部分液体CO 2在完成后从PLA珠排出 的浸渍和萃取步骤,在防止珠子粘在一起并发泡的温度下,并且在其中CO 2为液体形式的温度下,同时留下至少0.01kg液体CO 2 / kg PLA,优选为0.01-1 kg PLA溶液中,然后从反应器中排出CO 2气体,以将压力降至环境压力,由此蒸发剩余的液体CO 2,从而减少 记录温度以防止在环境压力下发泡。
Abstract:
There is provided polyvinylidene fluoride resin expanded beads which have a high expansion ratio, do not shrink easily, and are capable of obtaining a molded article of the expanded beads that is excellent in mold reproducibility and dimensional stability. The polyvinylidene fluoride resin expanded beads include a polyvinylidene fluoride resin as a base resin, in which a flexural modulus of the polyvinylidene fluoride resin is 450 MPa or more, a melt flow rate (MFR) of the polyvinylidene fluoride resin is 1 g/10 min or more at 230°C and 2.16 kg load, an apparent density of the expanded beads is 25 to 150 g/L, and a closed cell content of the expanded beads is 80% or more.
Abstract:
The present invention makes it possible to simply produce a noncrosslinked polyethylene resin expansion molded article whose dimensional shrinkage factor with respect to a metal mold is small, whose deformation is small, and whose surface stretches well, by arranging a noncrosslinked polyethylene resin expanded particle to have a bulk density BD in a range of not less than 10 g/L and not more than 100 g/L, the noncrosslinked polyethylene resin expanded particle being obtained by expanding a polyethylene resin particle whose density is in a range of not less than 0.920 g/cm 3 and not more than less than 0.940 g/cm 3 , the noncrosslinked polyethylene resin expanded particle having a shrinkage factor in a range of not less than 2 % and not more than 30 %, the shrinkage factor being obtained by the following formula (1): Shrinkage Factor = BD - VBD × 100 / VBD wherein: the BD of the noncrosslinked polyethylene expanded particle is a bulk density at 23 °C and at 0.1 MPa (at a normal atmospheric pressure); and the VBD of the noncrosslinked polyethylene expanded particle is a bulk density at 23 °C and at a reduced pressure of 0.002 MPa or less.
Abstract translation:本发明使得能够简单地产生一个非交联的聚乙烯系树脂发泡成型体是谁的尺寸收缩率相对于金属模具是小,其变形较小,并且其表面延伸良好,通过设置发泡粒子一个非交联的聚乙烯树脂具有 的范围内不低于10克/升,并且不超过100克/升的堆积密度BD中,非交联的聚乙烯系树脂发泡粒子是由膨胀的聚乙烯系树脂粒子,其密度是范围为不小于0920克获得 / cm 3且不大于小于0.940克/ cm 3时,在一个范围内的不小于2%,不超过30%的具有的收缩率的非交联的聚乙烯系树脂发泡粒子时,收缩因子由下式求出 (1):收缩率= BD - VBD×100 / VBD worin:非交联的聚乙烯发泡粒子的BD为在23℃和在0.1MPa的堆积密度(在正常ATMOS pheric压力); 与非交联的聚乙烯发泡粒子的VBD是在23℃,并在0002兆帕或更小的减小的压力的堆积密度。
Abstract:
Expandable, thermally curable compositions containing at least one epoxy resin, at least one polyester, at least one blowing agent, and at least one curing agent are useful as adhesives and structural reinforcement materials. When foamed and adhered to a metal substrate surface, such polyester-modified foamable compositions can exhibit improved adhesion to the substrate surface after exposure to a corrosive environment, as compared to compositions that do not contain polyester. Furthermore, these compositions can exhibit improved flow properties in the uncured state at temperatures between 50 and 100 0C. They are granulatable, with the granules produced thereby having non-tacky surfaces at room temperature and being capable of being readily processed into molded objects by injection molding processes.
Abstract:
Styrenic polymer foams, especially expanded and/or extruded styrenic polymer foams, are flame retarded by use of one or more flame retardant additives. These additives are i) a diether of tetrabromobisphenol-S, which ether groups do not contain bromine and wherein at least one of the ether groups is an allyl group; ii) a diether of tetrabromobisphenol-S, wherein at least one of the ether groups contains bromine; iii) a substituted benzene having a total of 6 substituents on the ring and wherein at least 3 of the substituents are bromine atoms and at least two of the substituents are C1-4 alkyl groups; iv) tribromoneopentyl alcohol; v) a tris(dibromoalkyl) benzenetricarboxylate in which each dibromoalkyl group contains, independently, 3 to 8 carbon atoms; vi) a brominated polybutadiene which is partially hydrogenated and/or aryl-terminated; vii) at least one brominated allyl ether of a novolac; viii) a brominated poly(l ,3-cycloalkadiene); ix) a brominated poly(4-vinylphenol allyl ether); x) a brominated N,TSP-phenylenebismaleimide; xi) a brominated N,N'-(4,4'-methylenediphenyl)bismaleimide; xii) a brominated N,N'-ethylenebismaleimide; xiii) ethylenebis(dibromonorbornane-dicarboxrmide) ; xiv) tetrabromobisphenol-A; or xv) a combination of any two or more of i) through xiv).