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    Polymeric nanoemulsion as drag reducer for multiphase flow
    164.
    发明授权
    Polymeric nanoemulsion as drag reducer for multiphase flow 有权
    聚合纳米乳液作为多相流动的减阻剂

    公开(公告)号：US07468402B2

    公开(公告)日：2008-12-23

    申请号：US11068400

    申请日：2005-02-28

    Applicant: Jiang Yang ,  Steven Jeremy Weghorn

    Inventor： Jiang Yang ,  Steven Jeremy Weghorn

    IPC: B05D5/08

    CPC classification number: C10L1/1985 ,  C10L1/143 ,  C10L1/146 ,  C10L1/1802 ,  C10L1/1955 ,  C10L1/1963 ,  C10L1/2364 ,  C10M173/00 ,  C10M2201/02 ,  C10M2203/10 ,  C10M2209/084 ,  C10M2209/104 ,  C10M2209/12 ,  C10M2217/024 ,  C10N2220/082 ,  C10N2220/14 ,  C10N2230/24 ,  C10N2250/02

    Abstract: Polymeric nanoemulsions facilitate flow and reduce drag and friction in multiphase pipelines containing both oil and water (e.g., oil/water, oil/water/gas, oil/water/solids, and oil/water/gas/solids) such as are used for oil or gas production, gathering, and transmission; hydrotransport of oilsand or heavy oil slurries and the like. Specific examples of suitable drag reducing polymers include polyacrylamide. The emulsions have a hydrocarbon external phase, droplets of an aqueous internal phase having water-soluble polymer dissolved therein, where the droplets have an average particle size below about 200 nm, and at least one surfactant to form a stable nanoemulsion. The nanoemulsions advantageously have a low viscosity of about 200 cP or less.

    Abstract translation: 聚合纳米乳液促进流动并减少包含油和水（例如油/水，油/水/气体，油/水/固体和油/水/气/固体）的多相管道中的阻力和摩擦，例如用于 石油或天然气的生产，采集和传输; 油或重油浆料的水运输等。 合适的减阻聚合物的具体实例包括聚丙烯酰胺。 乳液具有烃外相，其中水溶性聚合物溶于其中的水相内水相，其中液滴具有低于约200nm的平均粒度，以及至少一种表面活性剂以形成稳定的纳米乳液。 纳米乳液有利地具有约200cP或更低的低粘度。

    Multifunctional additive for fuel oils
    166.
    发明授权
    Multifunctional additive for fuel oils 有权
    燃油多功能添加剂

    公开(公告)号：US07435271B2

    公开(公告)日：2008-10-14

    申请号：US10668005

    申请日：2003-09-22

    Applicant: Matthias Krull ,  Werner Reimann

    Inventor： Matthias Krull ,  Werner Reimann

    IPC: C10L1/18 ,  C10L1/22

    CPC classification number: C10L10/08 ,  C10L1/143 ,  C10L1/1852 ,  C10L1/1881 ,  C10L1/191 ,  C10L1/1973 ,  C10L1/1981 ,  C10L1/2225 ,  C10L1/224 ,  C10L1/2364 ,  C10L1/24 ,  C10L10/04 ,  C10L10/14

    Abstract: The invention relates to additives for improving cold-flow and lubricating properties of fuel oils, comprising A) 5-95% by weight of at least one oil-soluble amphiphile of the formula  in which R1 is an alkyl, alkenyl, hydroxyalkyl or aromatic radical having 1 to 50 carbon atoms, X is NH, NR3, O or S, y is 1, 2, 3 or 4, R2 is hydrogen or an alkyl radical carrying hydroxyl groups and having 2 to 10 carbon atoms and R3 is an alkyl radical carrying nitrogen and/or hydroxyl groups and having 2 to 10 carbon atoms or C1-C20-alkyl, and B) 5 to 95% by weight of a terpolymer containing from 10 to 35 mol % of structural units derived from the vinyl ester of a carboxylic acid having 2 to 4 carbon atoms, from 1 to 15 mol % of structural units derived from the vinyl ester of a neocarboxylic acid having 8 to 15 carbon atoms, and structural units of ethylene to 100 mol %, having a melt viscosity, measured at 140° C., of from 20 to 10,000 mPas.

    Abstract translation: 本发明涉及用于改善燃料油的冷流和润滑性能的添加剂，其包括A）5-95重量％的至少一种下式的油溶性两亲物，其中R 1是 具有1至50个碳原子的烷基，烯基，羟基烷基或芳族基团，X是NH，NR 3，O或S，y是1,2,3或4，R 2， SUP>是氢或带有羟基并具有2至10个碳原子的烷基，R 3是带有氮和/或羟基并具有2至10个碳原子的烷基或C 1〜20个碳原子的烷基，B）5〜95重量％的含有10〜35摩尔％的羧酸乙烯基酯的结构单元的三元共聚物 具有2至4个碳原子，1至15摩尔％的衍生自具有8至15个碳原子的新羧酸的乙烯基酯的结构单元和乙烯的结构单元至100摩尔％，其熔体粘度在140 °C，为20〜10 00 mPas。

    Additive as component of mineral oil compositions
    168.
    发明申请
    Additive as component of mineral oil compositions 有权
    添加剂作为矿物油组合物的组分

    公开(公告)号：US20070180761A1

    公开(公告)日：2007-08-09

    申请号：US10576898

    申请日：2004-10-15

    Applicant: Hiltrud Täubert ,  Wolfgang Haubold ,  Konrad Buhler ,  Torsten Meyer

    Inventor： Hiltrud Täubert ,  Wolfgang Haubold ,  Konrad Buhler ,  Torsten Meyer

    IPC: C10L1/18

    CPC classification number: C08F8/14 ,  C08F8/00 ,  C08F8/32 ,  C10L1/143 ,  C10L1/1616 ,  C10L1/1691 ,  C10L1/1881 ,  C10L1/191 ,  C10L1/1963 ,  C10L1/1966 ,  C10L1/1973 ,  C10L1/1981 ,  C10L1/1985 ,  C10L1/2222 ,  C10L1/2225 ,  C10L1/224 ,  C10L1/2364 ,  C10L10/08 ,  C10L10/14 ,  C10M145/22 ,  C10M161/00 ,  C10M2205/022 ,  C10M2205/04 ,  C10M2209/062 ,  C10M2209/084 ,  C10M2209/086 ,  C10M2209/102 ,  C10M2217/024 ,  C10N2220/021 ,  C10N2220/023 ,  C10N2220/03 ,  C10N2230/08 ,  F17D1/16 ,  C08F210/02 ,  C08F255/026 ,  C08F222/06 ,  C08F212/12 ,  C08F212/08

    Abstract: Mineral oil compositions with trace portions of additives contain as additive a comb polymer containing ester linkages, either based on a) ethylene-vinylester copolymers modified by hydroxy groups or glycidyl groups with molecular mass weight averages from 3000 to 50000 and an ethylene portion of 50 to 90 mass %, and b) partially imidated and/or partially esterified maleic anhydride copolymers, wherein in the comb polymer based on a) and b) the modified ethylene-vinylester copolymer component is connected by means of ester linkages to the partially imidated and/or partially esterified maleic anhydride copolymer component, or a comb polymer containing ester linkages based on c) ethylene-vinylester copolymers modified by acid and/or acid anhydride groups with molecular mass weight averages from 3000 to 50000 and an ethylene portion of 50 to 90 mass %, and d) polyalcohols partially esterified with C12-C40-monocarboxylic acids wherein in the comb polymer based on c) and d) the ethylene-vinylester copolymer component modified by acid and/or acid anhydride groups is connected by means of ester linkages with the polyalcohol component partially esterified with C2-C40-monocarboxylic acids. The mineral oil compositions are suitable as flowable media to be transported at low temperatures and as mineral oil fuels with high lubricity and flowability.

    Abstract translation: 具有痕量部分添加剂的矿物油组合物含有作为添加剂的含有酯键的梳形聚合物，其基于a）通过羟基或缩水甘油基改性的乙烯 - 乙烯基酯共聚物，分子质量平均值为3000-50000，乙烯部分为50〜 90质量％，和b）部分酰亚胺化和/或部分酯化的马来酸酐共聚物，其中在基于a）和b）的梳型聚合物中，改性的乙烯 - 乙烯基酯共聚物组分通过酯键连接到部分酰亚胺化和/ 或部分酯化的马来酸酐共聚物组分，或含有酯键的梳形聚合物，基于c）通过酸和/或酸酐基改性的乙烯 - 乙烯基酯共聚物，分子质量平均值为3000-50000，乙烯部分为50-90质量％ ％，和d）与C 12 -C 40单 - 一元羧酸部分酯化的多元醇，其中在梳型聚合物中基于c）a 和d）通过酸和/或酸酐基团改性的乙烯 - 乙烯基酯共聚物组分通过酯键连接到与C 2 -C 40部分酯化的多元醇组分 单 - 羧酸。 矿物油组合物适合作为在低温下运输的可流动介质和具有高润滑性和流动性的矿物油燃料。

    Additive mixture as component of mineral oil compositions
    170.
    发明申请
    Additive mixture as component of mineral oil compositions 审中-公开
    添加剂混合物作为矿物油组合物的组分

    公开(公告)号：US20070130821A1

    公开(公告)日：2007-06-14

    申请号：US10576897

    申请日：2004-10-15

    Applicant: Hiltrud Täubert ,  Wolfgang Haubold ,  Erhard Brauer ,  Torsten Meyer ,  Irene Klimek ,  Dietrich Wense

    Inventor： Hiltrud Täubert ,  Wolfgang Haubold ,  Erhard Brauer ,  Torsten Meyer ,  Irene Klimek ,  Dietrich Wense

    IPC: C10L1/18

    CPC classification number: C10L10/08 ,  C10L1/143 ,  C10L1/146 ,  C10L1/1817 ,  C10L1/1905 ,  C10L1/1915 ,  C10L1/1973 ,  C10L1/1983 ,  C10L1/2364

    Abstract: An additive mixture as component of compositions of mineral oil as the main component and trace portions of an additive mixture contains the additive components a) ethylene-vinylester copolymers with molecular mass weight averages from 3000 to 50000 and an ethylene proportion of 50 to 90 mass %, and b) mixed esters of glycerine in which 50 to 80 mol % of the hydroxy groups are esterified with unsaturated C12-C40 monocarboxylic acids and 20 to 50 mol % of the hydroxy groups are esterified with partially imidated and/or partially esterified maleic anhydride copolymers, and/or c) partially and/or completely imidated copolymers consisting of maleic anhydride and α-methylstyrene with molecular mass number averages from 1500 to 15000 and at least one terminal group based on dimeric α-methyl styrene, and/or d) wax compositions based on natural starting materials of type d1) wax-like oligomeric esters based on glyceryl monostearate and dimeric acid and/or d2) wax esters with vaseline-like consistency, based on at least two different straight-chain and/or branched C14-C36-alcohols and dimeric acid whereby the content of the additive mixture in the mineral oil is 0.005 to 1 mass % and the mass proportion of the additive components a/b or a/c or a/d is in the range from 10:90 to 90:10, respectively. The mineral oil compositions are suitable as flowable media to be transported at low temperatures and as mineral oil fuels with high lubricity and flowability.

    Abstract translation: 作为添加剂组合物的矿物油组成的添加剂混合物和添加剂混合物的痕量部分的添加剂混合物含有添加剂成分a）分子质量平均为3000〜50000，乙烯比例为50〜90质量％的乙烯 - 乙烯基酯共聚物， ，和b）甘油的混合酯，其中50-80摩尔％的羟基与不饱和C 12 -C 40单羧酸酯化和20-50摩尔％ 的羟基被部分亚酰化和/或部分酯化的马来酸酐共聚物酯化，和/或c）部分和/或完全酰亚胺化的共聚物，其由马来酸酐和α-甲基苯乙烯组成，分子量平均值为1500至15000，至少 基于二聚α-甲基苯乙烯的一个末端基团和/或d）基于d1型天然起始材料的蜡组合物基于单硬脂酸甘油酯和二聚酸的蜡状低聚酯和/或d2）蜡 基于至少两种不同的直链和/或支链C 14 -C 36 - 醇和二聚酸，其中含有凡士林样稠度的酯，由此添加剂的含量 矿物油中的混合物为0.005〜1质量％，添加成分a / b或a / c或a / d的质量比例分别为10:90〜90:10。 矿物油组合物适合作为在低温下运输的可流动介质和具有高润滑性和流动性的矿物油燃料。

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