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    A process for the production of cross-linkable macromolecular compounds
    172.
    发明专利
    A process for the production of cross-linkable macromolecular compounds 未知

    公开(公告)号：GB890776A

    公开(公告)日：1962-03-07

    申请号：GB4385160

    申请日：1960-12-21

    Applicant: BASF AG

    Inventor： KESSLER HANSJUERGEN ,  PENNING ERNST ,  WILHELM HANS ,  REINHARD HANS

    IPC: C08F220/28 ,  C08F222/18 ,  D06M15/263

    Abstract: A method of making an easily cross-linkable polymer comprises copolymerizing (1) 0,5-50% by weight of an ester of a polymerizable a ,b -ethylenically unsaturated mono- or di-carboxylic acid with a dihydric or higher polyhydric alcohol which bears a chlorine atom at the a -position to a free hydroxyl group and (2) 99,5-50% by weight of one or more unsaturated polymerizable compounds. The esters (1) may be esters of acrylic, methacrylic, maleic or fumaric acid with 3-chlorpropane-diol-(1,2), 2,3-dichlorbutane-diol-(1,4), 3-chlorbutane-triol-(1,2,4), 1,4-dichlorbutane-diol-(2,3), 3-chlor-2-methylpropane-diol-(1,2), or 3-chlor-2-chlormethylpropane-diol-(1,2). Compounds (2) can be acrylic, methacrylic or maleic acid, methyl, ethyl, or butyl acrylate or methacrylate, acrylamide, methacrylamide, acrylonitrile, vinyl acetate, vinyl propionate, acrolein, methyl allyl ketone, isopropenyl ketone, allyl or methallyl alcohol, allyl methyl and ethyl ethers, allyl acetate or propionate, ethylene, propylene, butadiene, vinyl methyl or ethyl ether, vinyl chloride, vinylidene chloride or cyanide, N-vinyl pyrrolidone, N-vinyl carbazole, styrene or mono- or di-methyl styrene. The copolymers may be prepared by bulk, solution, emulsion, suspension or precipitation polymerization, using conventional catalysts, such as peroxides, azo compounds, or redox systems, for example potassium persulphate and azo bis isobutyronitrile. The polymers can be cross-linked at room temperatures by agents which split off hydrogen halide, such as metal oxides, hydroxides and alcoholates. These polymers can be mixed with other polymers.

    Coloured polymers
    173.
    发明专利
    Coloured polymers 未知

    公开(公告)号：GB877402A

    公开(公告)日：1961-09-13

    申请号：GB1509960

    申请日：1960-04-29

    Applicant: BASF AG

    Inventor： KREHBIEL GUENTER ,  LANGE GUENTER ,  PENNING ERNST ,  WILHELM HANS

    IPC: C08F2/02 ,  C08F2/44 ,  C08F20/60 ,  C08F20/62 ,  C08F26/00 ,  C08F28/00 ,  C08K5/00 ,  C09B1/36 ,  C09B67/42 ,  C09B69/10

    Abstract: Coloured polymers are made by copolymerizing one or more dyestuffs of the azo or anthraquinone series which contains the group: in which R1 represents a hydrogen or halogen atom a methyl group, R2 a hydrogen or halogen atom and X a phenylene, >C=0 or -SO2- radical, and one or more other unsaturated polymerizable compounds, e.g. vinyl and vinylidene chlorides, acrylic and chloroacrylic acids and esters thereof, such as iso-octyl acrylate, methyl methacrylate, acrylamide, methacrylamide, methylene bis-acrylamide, acrylonitrile, crotonic acid, maleic anhydride, maleic and fumaric esters, vinylidene cyanide, vinyl and allyl esters of organic acids, such as vinyl acetate, styrene, divinyl benzene, vinyl sulphonic acid, N-vinylcarbazole, N-vinylpyrrolidone, divinyl sulphone and vinyl ethers. Polymerizable dyestuffs specified include those described in Specifications 719,282, 747,454, 830,876, 858,183 and 875,946, in French Specification 1,118,705 and in Belgian Specification 566,099. Polymerization may take place in bulk, solution, suspension or emulsion with the aid of initiators such as azodiisobutyronitrile, benzoyl peroxide, hydrogen peroxide and potassium persulphate Polymerization solvents specified are benzene, toluene, a mixture of toluene and acetone, ethanol, butanol, butyrolactone and N-methyl-pyrrolidone. In aqueous medium polymerizations, dispersing agents such as a mixture of turkey red oil and sodium di-isobutylnaphthalene sulphonate and a mixture of an alkyl aryl sulphonate and the reaction product of pentaerythritol, glycerin and epichlorhydrin may be used. During the course of the reaction further quantities of reactants, e.g. monomer, solvent and catalyst, may be added.ALSO:Dyestuffs of the anthraquinone or azo series are described which contain the group:- in which R1 represents a hydrogen or halogen atom or a methyl group, R2 a hydrogen or halogen atom and X a phenylene, >C=O or -SO2- radical. Such dyestuffs and means for preparing them are described in Specifications 719,282, 747,454, 830,876, 858,183 and 875,946, in French Specification 1,118,705 and in Belgian Specification 566,099. In examples dyestuffs are described which are obtained by: (3) coupling diazotized 1-amino-4-acryloylaminobenzene with 1-hydroxy-naphthalene- 4-sulphonic acid; (4) coupling diazotized 4-aminostyrene with 2-hydroxynaphthalene; (6) coupling diazotized 4-aminostyrene with the sodium salt of 1-(2-chloro-5-sulphophenyl)-3-methylpyrazolone-(5); (9) reacting 1, 4-diamino- 2-acetylanthraquinone with acrylyl or chloracrylyl chloride; (11) reacting 1- amino- 4- (2- phenylquinazolyl-(4))- amino-anthraquinone with acrylyl chloride; (12) reacting 1-amino- 5-benzoylaminoanthraquinone with acrylyl chloride; (15) coupling diazotized 1-acrylylamino-3-aminobenzene with 1-butyl- 3-hydroxy-7-methyl- 1, 2, 3, 4-tetrahydroquinoline; (16) coupling diazotized 4-amino-41-ethene-sulphonyl-amino-diphenyl sulphide with 1-phenyl-5-pyrazolone-3-carboxylic acid ethyl ester; and (17) coupling diazotized 1-acryloylamino- 4-aminobenzene with 1-(2-chloro- 5-sulphophenyl)-3-methylpyrazolone-(5).

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