公开(公告)号：JPS60258236A

公开(公告)日：1985-12-20

申请号：JP11394184

申请日：1984-06-05

Applicant: BRIDGESTONE CORP

Inventor： TOMITA SEISUKE ,  NIWA HIDEYUKI ,  HASHIMOTO TAKATSUGU

IPC: C08L9/00 ,  A63B37/00 ,  A63B37/04 ,  C08L7/00 ,  C08L21/00 ,  C08L83/00 ,  C08L83/04

Abstract: PURPOSE:A rubber composition that is composed of a specific silicone rubber, a specific polybutadiene rubber, a hardness regulator, a weight regulator and a curing agent, thus giving golf balls guaranteeing long carries with high impact resilience. CONSTITUTION:The rubber component containing (A) 4-100wt% of a silicone rubber of more than 800 polymerization degree based on siloxane units and (B) 96-0wt% of polybutadiene rubber which has more than 30 of Mooney viscosity and more than 40% of cis-1,4-bonds, is combined with (C) a hardness regulator, (D) a weight regulator and (E) a curing agent. Component A used includes 0.1- 100%, preferably 5-35% of vinyl group based on the whole side chains.

公开(公告)号：JPS6081234A

公开(公告)日：1985-05-09

申请号：JP18938083

申请日：1983-10-12

Applicant: BRIDGESTONE CORP

Inventor： HASHIMOTO TAKATSUGU ,  OOHASHI TAKASHI

IPC: C08L9/06 ,  C08L7/00 ,  C08L21/00 ,  C08L23/00 ,  C08L33/00 ,  C08L33/02 ,  C08L101/00

Abstract: PURPOSE:To provide a composition having extremely high slip resistance even in wet state, and exhibiting excellent impact and oscillation absorbing property, by mixing a styrene-butadiene copolymer having high styrene content with a general-purpose rubber, adding a reinforcing agent, etc. to the mixture, and curing with heat. CONSTITUTION:The objective composition having an impact resilience of 0-30% can be produced by compounding (A) 100pts.wt. of a rubber mixture composed of (i) a styrene-butadiene copolymer having high styrene content wherein the styrene-content is adjusted to 45-70(wt)%, preferably 55-65% by the polymerization or blending process and (ii) 5-65%, preferably 20-50% general-purpose rubber based on the whole rubber mixture, with (B) 0-100parts of a filler, (C) 5-80parts of a reinforcing agent, (D) 0-60parts of a plasticizer and (E) a vulcanizing agent and a vulcanization accelerator, and curing the composition by heating at 110-180 deg.C.

公开(公告)号：JPS59196331A

公开(公告)日：1984-11-07

申请号：JP7123183

申请日：1983-04-22

Applicant: Bridgestone Corp

Inventor： HASHIMOTO TAKATSUGU ,  SUZUKI AKIRA ,  KATAOKA NOBUYUKI ,  SAITOU TASUKU ,  OOHASHI TAKASHI

IPC: C08J9/06 ,  C08J9/04

Abstract: PURPOSE: A low-resilience rubber foam suitable as a shoe material capable of absorbing a strong impact resulting from walking or running, prepared by adding a filler, a plasticizer, a blowing agent, and a vulcanizing agent to a specified rubber mixture and expanding and curing the mixture by heating.
CONSTITUTION: A low-resilience rubber foam having a resilience of 0W35%, obtained by mixing 100pts.wt. high-styrene content styrene-butadiene copolymer/ general-purpose rubber mixture comprising a high-styrene content styrene-butadiene copolymer of a styrene content controlled at 53W75wt% during polymerization or by blending and 40wt% or below, based on the total mixed rubber weight, general-purpose rubber with 30W300pts.wt. filler, 5W60pts.wt. plasticizer, 0.5W50pts.wt. blowing agent, and a vulcanizing agent and expanding and curing the resulting mixture by heating. This foam is suitable as a shoe material capable of absorbing a strong impact resulting from walking or running and of protecting the nervous system or joint system of food.
COPYRIGHT: (C)1984,JPO&Japio

Abstract translation: 目的：适用于能够吸收由步行或跑步产生的强烈冲击的鞋材的低弹性橡胶泡沫，其通过向特定的橡胶混合物中加入填料，增塑剂，发泡剂和硫化剂而制备， 通过加热固化混合物。 组成：弹性为0-35％的低弹性橡胶泡沫，通过混合100pts.wt。 高苯乙烯含量的苯乙烯 - 丁二烯共聚物/通用橡胶混合物，其包含在聚合期间或通过共混控制为53-75重量％的苯乙烯含量的苯乙烯含量高的苯乙烯 - 丁二烯共聚物，基于总混合物的40重量％或更低 橡胶重量，通用橡胶30-300pts.wt。 填料，5-60pts.wt。 增塑剂，0.5-50pts.wt。 发泡剂和硫化剂，并通过加热使所得混合物膨胀和固化。 该泡沫适合作为能够吸收由步行或跑步产生的强烈冲击并保护食物的神经系统或接合系统的鞋材料。

公开(公告)号：JPS5996139A

公开(公告)日：1984-06-02

申请号：JP20555182

申请日：1982-11-25

Applicant: BRIDGESTONE CORP

Inventor： HASHIMOTO TAKATSUGU ,  OOHASHI TAKASHI

IPC: C08J9/06

Abstract: PURPOSE:To provide the titled foam which is lightweight and has excellent energy absorptivity, vibration absorptivity, etc., by adding a filler, a plasticizer, a blowing agent, a vulcanizing agent, and a vulcanizing accelerator to a styrene/ butadiene copolymer having a high styrene content and expanding and curing it by heating. CONSTITUTION:100pts.wt. styrene/butadiene copolymer having a styrene content of 50-70wt% or mixture thereof, 30-300pts.wt. filler such as calcium carbonate or bentonite, 5-60pts.wt. plasticizer such as dioctyl phthalate or arom. oil, 2- 60pts.wt. blowing agent such as dinitrosopentatetramine, a vulcanizing agent and a vulcanizing accelerator are mixed together. The mixture is expanded and cured by heating to obtain the desired low-resilience rubber foam having low impact rebound over a wide applicable temp. range of -10 to 40 deg.C.

公开(公告)号：JPS5963547A

公开(公告)日：1984-04-11

申请号：JP17509682

申请日：1982-10-04

Applicant: Bridgestone Corp

Inventor： TAKAHASHI KIYOSHI ,  KOMATSU HARUO ,  HIYOUDOU SHINICHI ,  HASHIMOTO TAKATSUGU

IPC: G01N3/00 ,  G01N3/02 ,  G01N3/08 ,  G01N21/84 ,  G01N29/00

CPC classification number: G01N3/08 ,  G01N2203/0254

Abstract: PURPOSE:To apply biaxial tension to a test piece easily at a high speed by applying impulsive tensile force to the center part of the test piece whose circumference is fitted fixedly onto a pressure-proof block and displacement the test piece in its thickness direction. CONSTITUTION:Electrodes 14 and 16, the test piece 18, and a presser plate 20 are stacked successively on the insulating pressure-proof block 12 made of hard high- polymer material; and four bolts 22 pierce the presser plate 20, test piece 18, and pressure-proof block 12 and a nut 24 engages its tip part threadably to press the test piece 18 and electrodes 14 and 16 against the pressure-proof block 12 by the presser plate 20. An opening is made in the center of the presser plate 20 and the presser plate 20 presses the circumference of the test piece 18 fixedly against the pressure-proof block 12 except at the part corresponding to the opening 26. Consequently, the test piece 18 is capable of biaxial displacement in the direction wherein the part corresponding to the opening 26 enters the opening 26, i.e. in the thickness directions. A plug 34 is fitted in the end part of the through hole to block the through hole 32. This plug 34 exits from the through hole 32 by expansion pressure during discharge to discharge abruptly the test piece which expands in two axial directions by an impulsive wave and the expansion pressure.

Abstract translation: 目的：通过向试验片的中心部分施加脉冲张力，将圆周张力固定在耐压块上，并使试验片在其厚度方向上移位，使试件易于高速拉伸。 构成：电极14和16，试验片18和压板20依次层叠在由硬质高分子材料制成的绝缘耐压块12上。 并且四个螺栓22刺穿压板20，试验片18和耐压块12，并且螺母24螺纹接合其末端部分，以将压片18和电极14和16压靠在防压块12上 在压板20的中心形成开口，压板20将试验片18的圆周固定地压靠在耐压块12上，除了对应于开口26的部分之外。因此，试验 片18能够在与开口26对应的部分进入开口26的方向上，即在厚度方向上双轴移位。 插塞34装配在通孔的端部以阻塞通孔32.该插头34在放电期间通过膨胀压力从通孔32中排出，以便通过冲击波在两个轴向方向上突出地放出试验片 和膨胀压力。

公开(公告)号：JPS58179280A

公开(公告)日：1983-10-20

申请号：JP6040882

申请日：1982-04-13

Applicant: Bridgestone Corp

Inventor： HASHIMOTO TAKATSUGU ,  FUSE TADASHI ,  NAITOU TOSHIO ,  OOHASHI TAKASHI

IPC: C08L33/00 ,  C08L33/02 ,  C08L33/04 ,  C08L33/10 ,  C09J4/02

Abstract: PURPOSE: The titled composition having improved heat resistance, retention of adhesion at high temperature, and tensile strength, containing a composition comprising a polymer having a polymerizable side chain and a dihalocyclopropane structure as a polar group and a polymerization catalyst, and an organic acid polymerizable with it.
CONSTITUTION: (A) A composition having a polymerizable side chain [preferably (meth)acryloyloxy], a dihalocyclopropane structure (preferably the halogen part is chlorine or bromine) as a polar group, and ≥500 molecular weight is blended with (B) preferably 4W80pts.wt. organic acid[preferably (meth)acrylic acid]having a vinyl or methacryl group, polymerizable with the component A based on 100pts.wt. total composition, and, preferably (C) a vinyl monomer such as methyl methacrylate, etc., to give the desired composition. The amount of the methacryloyloxy group is 1/100W1/5,000mol equivalent per unit weight of the polymer having a carbon-carbon unsaturated dobule bond and ≥500 molecular weight.
COPYRIGHT: (C)1983,JPO&Japio

Abstract translation: 目的：具有改善的耐热性，高温粘附保持性和拉伸强度的标题组合物，其含有具有聚合性侧链和二卤代环丙烷结构的聚合物作为极性基团的组合物和聚合催化剂，以及可聚合有机酸 用它。 （A）具有可聚合侧链（优选（甲基）丙烯酰氧基），二卤代环丙烷结构（优选卤素部分为氯或溴）作为极性基团并且> = 500分子量的组合物与（B） 优选4-80pts.wt。 具有乙烯基或甲基丙烯酰基的有机酸[优选（甲基）丙烯酸]可以基于100pts.wt。 总组合物，和优选（C）乙烯基单体如甲基丙烯酸甲酯等，得到所需组合物。 甲基丙烯酰氧基的量为具有碳 - 碳不饱和多重键的聚合物/> = 500分子量的单位重量的1 / 100-1 / 5,000摩尔当量。

公开(公告)号：JPS58179246A

公开(公告)日：1983-10-20

申请号：JP6042982

申请日：1982-04-13

Applicant: Bridgestone Corp

Inventor： HASHIMOTO TAKATSUGU ,  OOHASHI TAKASHI

IPC: C08L7/00 ,  C08L9/06 ,  C08L21/00

Abstract: PURPOSE: The titled composition that is obtained by adding large amounts of fillers, plasticizers, vulcanizing agents and accelerators to a styrene-butadiene copolymer of high styrene content, thus showing high hardness, low resilienece and high tensile strength.
CONSTITUTION: (A) 100pts.wt. of a styrene-butadiene copolymer of 55W72wt%, preferably 63W69wt% styrene content are combined with (B) 50W300pts.wt., preferably 150W200pts.wt. of a filler such as calcium carbonate, (C) 50W100, preferably 65W85pts.wt. of a plasticizer such as aromatic oil, further a vulcanizing agent and accelerator and a reinforcing agent and they are cured at 110W 180°C.
USE: Parts of audio appliances, such as turn table, rubber sheet or the like.
COPYRIGHT: (C)1983,JPO&Japio

Abstract translation: 目的：通过将大量填料，增塑剂，硫化剂和促进剂加入到苯乙烯含量高的苯乙烯 - 丁二烯共聚物中而获得的标题组合物，因此显示出高硬度，低回弹性和高拉伸强度。 规定：（A）100pts.wt。 的苯乙烯含量为55-72wt％，优选63-69wt％苯乙烯含量的苯乙烯 - 丁二烯共聚物与（B）50-300pts.wt。优选150-200pts.wt。 的填料如碳酸钙，（C）50-100，优选65-85pts.wt。 的增塑剂如芳香油，还有硫化剂和促进剂和增强剂，它们在110-180℃下固化。 用途：音响电器部件，如转台，橡胶片等。

公开(公告)号：JPS57126877A

公开(公告)日：1982-08-06

申请号：JP1263981

申请日：1981-01-30

Applicant: Bridgestone Corp

Inventor： HASHIMOTO TAKATSUGU ,  YANAMI JIYOUJI ,  OOHASHI TAKASHI

IPC: C09K3/14

Abstract: PURPOSE: To provide the titled coating agent which can impart an excellent anti-slip effect to rubber goods without deteriorating rubber substrates, consisting of a solution contg. a rubber or a resin having a specified vitrification temperature.
CONSTITUTION: A rubber or a resin having a vitrification temp. of -20W5°C (e.g. a styrene-butadiene rubber having a high styrene content or dichloro-cyclopropane-modified cis-1,4-polybutadiene) is dissolved in an org. solvent such as methylene chloride.
EFFECT: When this coating agent is coated on automobile tires, this agent has an anti-slip effect on wetted roads.
COPYRIGHT: (C)1982,JPO&Japio

Abstract translation: 目的：提供可以赋予橡胶制品优异防滑效果的标题涂布剂，而不会使橡胶基材变质，而由橡胶基材组成。 具有特定玻璃化温度的橡胶或树脂。 构成：具有玻璃化温度的橡胶或树脂。 （例如具有高苯乙烯含量的苯乙烯 - 丁二烯橡胶或二氯 - 环丙烷改性的顺式-1,4-聚丁二烯）溶于有机溶剂中。 溶剂如二氯甲烷。 效果：当这种涂层剂涂覆在汽车轮胎上时，该剂对润湿道路具有防滑作用。

公开(公告)号：JPS5762272A

公开(公告)日：1982-04-15

申请号：JP13669580

申请日：1980-10-02

Applicant: Bridgestone Corp

Inventor： OOHASHI TAKASHI ,  HASHIMOTO TAKATSUGU ,  TSUBOSHIMA KEIKO

IPC: C07D251/34

Abstract: NEW MATERIAL:A compound expressed by the formula (X and Y are Cl or Br).
EXAMPLE: N,N',N"-Tris(2,2-Dichlorocyclopropylmethyl)isocyanurate.
USE: Various modifying additives, e.g. a flame retardant and a low smoking agent, particularly a cellular opening agent for a synthetic resin foam material, particularly polyurethane foam, or a hardenss increasing agent.
PROCESS: Triallyl isocyanurate is reacted with a haloform and a solution of an alkaline metallic hydroxide in a molar amount of 70 times or more that of α,β- unsaturated bonds in the presence of an onium compound consisting of a quaternary ammonium salt or quaternary phosphonium salt having at least one ≥4C aliphatic substituent group as a phase transfer catalyst to give the aimed compound expressed by the formula selectively in high yield.
COPYRIGHT: (C)1982,JPO&Japio

Abstract translation: 新材料：由式（X和Y表示为Cl或Br）表示的化合物。 实施例：N，N'，N“ - 三（2,2-二氯环丙基甲基）异氰脲酸酯。 用途：各种改性添加剂，例如 阻燃剂和低吸烟剂，特别是合成树脂泡沫材料的细胞开孔剂，特别是聚氨酯泡沫，或增硬剂。 方法：在由季铵盐或季鏻组成的鎓化合物的存在下，将三烯丙基异氰脲酸酯与卤代甲醛和碱金属氢氧化物的溶液摩尔量的摩尔量为α，β-不饱和键的70倍或更多 具有至少一个> = 4C脂族取代基的盐作为相转移催化剂，以高产率选择性地得到由式表示的目标化合物。