公开(公告)号：US2716115A

公开(公告)日：1955-08-23

申请号：US2716115D

CPC classification number: C07D201/04

公开(公告)号：US2573374A

公开(公告)日：1951-10-30

申请号：US2573374D

CPC classification number: C07D201/04

公开(公告)号：US2249177A

公开(公告)日：1941-07-15

申请号：US2249177D

CPC classification number: C07D201/04

公开(公告)号：US2221369A

公开(公告)日：1940-11-12

申请号：US2221369D

CPC classification number: C07D201/04

公开(公告)号：KR1020140024872A

公开(公告)日：2014-03-03

申请号：KR1020137027596

申请日：2012-04-16

Applicant: 캡 쓰리 비 브이

Inventor： 그루더트매리즈케힐드린 ,  틴지요한토마스 ,  귀트루돌프필리푸스마리아

IPC: C01B21/14 ,  C07C251/32

CPC classification number: C07C249/08 ,  C01B21/1418 ,  C07C2601/14 ,  C07C2601/20 ,  C07D201/04 ,  C07D211/76 ,  C07D227/087 ,  C07C251/44

Abstract: 액상, 기상 및 불균질 수소화 촉매를 포함하는 반응 대역에서 나이트레이트를 수소화시킴을 포함하는, 연속식 공정으로 하이드록실아민을 제조하는 방법으로서, 이 때 상기 반응 대역에서 하이드록실아민 및 아산화질소(N
2 O)가 형성되고, 기상중 아산화질소 농도를 모니터링하고, 반응 대역으로 불균질 수소화 촉매용 촉진제를 제어하면서 첨가하고/하거나 추가량의 불균질 수소화 촉매를 제어하면서 첨가함으로써 기상중 아산화질소 농도를 소정 범위 내로 유지함을 특징으로 하는 방법.

公开(公告)号：KR101100054B1

公开(公告)日：2011-12-29

申请号：KR1020040051544

申请日：2004-07-02

Applicant: 스미또모 가가꾸 가부시끼가이샤

Inventor： 요꼬따마사시 ,  고바야시요시노리 ,  기따무라마사루

IPC: C07D201/10

CPC classification number: C07D201/04 ,  Y02P20/52

Abstract: ε-카프로락탐은 고체 촉매 입자를 옥심 포함 가스와 접촉시키기 위해 촉매 층을 유동화하면서 가스 분산판의 다수의 구멍 (평균 직경: 약 3 mm 이하) 을 통해 시클로헥사논 옥심 포함 가스를 고체 촉매 입자의 층에 도입하는 단계를 포함하는 방법으로 얻는다.
상기의 제조 방법으로, 시클로헥사논 옥심 포함 원료 가스로부터 시클헥사논 옥심의 고전화율 및 ε-카프로락탐에 대한 고선택율로 ε-카프로락탐을 제조할 수 있다.
ε-카프로락탐

公开(公告)号：KR1020040042720A

公开(公告)日：2004-05-20

申请号：KR1020020071308

申请日：2002-11-15

Applicant: 한국과학기술연구원 ,  주식회사 카프로

Inventor： 김선진 ,  어용선 ,  김명훈 ,  김은지 ,  정원기 ,  김정한

IPC: B01J21/08

CPC classification number: B01J21/08 ,  B01J35/1019 ,  B01J37/08 ,  B01J37/30 ,  C07D201/04

Abstract: PURPOSE: Provided are a metal ion impregnated porous catalyst and a method for preparing thereof, which is able to increase the yield of a conversion rate of cyclohexanone oxime and ε-caprolactam and provides safe, economical, environmental-friendly and life span extended metal ion, and a method for preparing ε-caprolactam from cyclohexanone oxime using the catalyst. CONSTITUTION: The metal ion impregnated porous catalyst has pores formed by metal oxide pillar introduced between layers of layered silica compound, wherein the metal ion is impregnated in pores. The method comprises steps of (a) synthesizing a layered silica compound; (b) acid-ion exchanging the synthesized layered silica compound by acid titration; (c) forming pores between layers of layered silica compound by adding organic metal to the acid-ion exchanged layered silica compound and sintering; and (d) supporting the surface of the pores in metal ion by adding an aqueous solution of the metal ion thereto and sintering. The ε-caprolactam is prepared by gaseous beckmann conversion of cyclohexanone oxime solution using the metal ion impregnated porous catalyst.

Abstract translation: 目的：提供一种金属离子浸渍多孔催化剂及其制备方法，其能够提高环己酮肟和ε-己内酰胺的转化率的产率，并提供安全，经济，环保和寿命延长的金属离子 以及使用该催化剂从环己酮肟制备ε-己内酰胺的方法。 构成：金属离子浸渍多孔催化剂具有由层状二氧化硅化合物层之间引入的金属氧化物柱形成的孔，其中金属离子浸渍在孔中。 该方法包括以下步骤：（a）合成层状二氧化硅化合物; （b）通过酸滴定将合成的层状二氧化硅化合物进行酸离子交换; （c）通过向酸离子交换的层状二氧化硅化合物中加入有机金属并烧结而在层状二氧化硅化合物的层之间形成孔; 和（d）通过向其中加入金属离子的水溶液并进行烧结来支撑金属离子中的孔的表面。 使用金属离子浸渍的多孔催化剂，通过环己酮肟溶液的气态贝克曼转化制备ε-己内酰胺。

公开(公告)号：KR100314982B1

公开(公告)日：2001-11-30

申请号：KR1019990039567

申请日：1999-09-15

Applicant: 아르끄마 프랑스

Inventor： 올리비에쟝 ,  드뤼뗄다미앙

IPC: C07D227/02

CPC classification number: C07D201/04

Abstract: 본발명은하기 : a - 유기용매에용해된시클로도데칸, 니트로화제및 히드로겐클로라이드를산의존재하에반응시켜시클로도데카논옥심을형성시키고, b - 전술한옥심을산의존재하에벡크만재배열반응시는것 으로구성된라우릴락탐의제조방법에있어서, 산이메탄술폰산임을특징으로하는라우릴락탐의제조방법에관한것이다.

公开(公告)号：KR1020010066865A

公开(公告)日：2001-07-11

申请号：KR1020000034494

申请日：2000-06-22

Applicant: 스미또모 가가꾸 가부시끼가이샤

Inventor： 이찌하시히로시 ,  스기따게이스께 ,  야꼬마꼬또

IPC: B01J29/06 ,  C07D201/12

CPC classification number: C01B39/40 ,  B01J29/40 ,  C07D201/04 ,  Y02P20/52 ,  Y10S423/22 ,  Y10S423/29 ,  Y10S423/34

Abstract: PURPOSE: A method for producing a pentasil type crystalline zeolite having excellent catalytic activity and reproductivity is provided. CONSTITUTION: This method for producing a pentasil type crystalline zeolite comprises (i) compounding a silicon compound with water and tetra-n-propylammonium hydroxide; (ii) obtaining a reaction solution containing a zeolite crystal by hydrothermal reaction from a mixed solution obtained by the 1st step; (iii) separating the reaction solution obtained by the 2nd step into the zeolite crystal and a solution; (iv) baking the zeolite crystal obtained by the 3rd step; and (v) treating the zeolite crystal baked by the 4th step with an aqueous solution containing ammonia and/or ammonium salt and has the molar ratio of hydroxide to silicon of 0.1-0.4 and the molar ratio potassium ion to silicon of 0-0.1 in the mixed solution prepared in the 1st step. This method for producing ε-caprolactam comprises using the pentasil type crystalline zeolite as a catalyst obtained by the method and subjecting cyclohexanone. oxime to Beckmanns rearrangernent reaction under a vapor-phase condition.

Abstract translation: 目的：提供催化活性和再生性优异的pentasil型结晶沸石的制造方法。 构成：用于制备pentasil型结晶沸石的方法包括（i）将硅化合物与水和四正丙基氢氧化铵混合; （ii）从通过第一步骤得到的混合溶液通过水热反应获得含有沸石晶体的反应溶液; （iii）将由第二步获得的反应溶液分离成沸石晶体和溶液; （iv）焙烧通过第3步获得的沸石晶体; 和（v）用含有氨和/或铵盐的水溶液处理由第四步骤焙烧的沸石晶体，并且氢氧化物与硅的摩尔比为0.1-0.4，钾离子与硅的摩尔比为0-0.1 在第一步中制备的混合溶液。 该ε-己内酰胺的制造方法包括使用pentasil型结晶沸石作为通过该方法获得的催化剂并对环己酮进行处理。 肟到贝克曼在气相条件下反向反应。

公开(公告)号：KR1020000023183A

公开(公告)日：2000-04-25

申请号：KR1019990039567

申请日：1999-09-15

Applicant: 아르끄마 프랑스

Inventor： 올리비에쟝 ,  드뤼뗄다미앙

IPC: C07D227/02

CPC classification number: C07D201/04

Abstract: PURPOSE: A process for production of lauryllactam which is useful as a monomer for producing a polyamide 12 type polymer is provided by which defects caused by using sulfonic acid in a conventional process can be reduced by using methane sulfonic acid. CONSTITUTION: A process for production of lauryllactam comprises the steps of: reacting acyclododecane, a nitrating agent and a hydrogen chloride which are dissolved in an organic solvent such as a chloroform or a chlorobenzene in the presence of a methane sulfonic acid to give a cyclododecanone oxime; and subjecting the oxime to Beckmann rearrangement in the presence of the methane sulfonic acid to give the objective lauryllactam.

Abstract translation: 目的：提供用作生产聚酰胺12型聚合物的单体的十二烷基内酰胺的制造方法，通过使用甲磺酸可以降低常规方法中使用磺酸引起的缺陷。 构成：生产月桂基内酰胺的方法包括以下步骤：在甲磺酸存在下，将溶于有机溶剂如氯仿或氯苯的acyclododecane，硝化剂和氯化氢反应，得到环十二烷酮肟 ; 并在甲磺酸存在下使肟进行贝克曼重排，得到目的月桂基内酰胺。