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11.发明申请ETHYLENE-STYRENE COPOLYMERS AND PHENOL-TRIAZOLE TYPE COMPLEXES, CATALYSTS, AND PROCESSES FOR POLYMERIZING 审中-公开乙烯 - 苯乙烯共聚物和苯酚 - 三唑类复合物，催化剂和聚合方法
公开(公告)号：WO2003087177A2
公开(公告)日：2003-10-23
申请号：PCT/US2003/011456
申请日：2003-04-11
Applicant: SYMYX TECHNOLOGIES, INC. , BRUMMER, Oliver , DIAMOND, Gary, M. , GOH, Christopher , LaPointe, Anne, M. , LECLERC, Margarete, K. , LONGMIRE, James , SHOEMAKER, James, A., W.
Inventor： BRUMMER, Oliver , DIAMOND, Gary, M. , GOH, Christopher , LaPointe, Anne, M. , LECLERC, Margarete, K. , LONGMIRE, James , SHOEMAKER, James, A., W.
IPC: C08F210/00
CPC classification number: C08F210/02 , C07D249/06 , C07F7/00 , C07F7/006 , C08F4/65908 , C08F4/65912 , C08F4/659 , C08F4/64 , C08F212/08 , C08F2500/03
Abstract: Metal-ligand complexes that are useful as precusors to catalysts for the polymerization of olefins are provided. Certain of the catalysts are particularly effective at polymerizing ethylene and styrene into copolymers having novel properties, including a low molecular weight and close comparison between vinyl and methyl end groups.
Abstract translation: 提供了可用作催化剂用于烯烃聚合的前提物的金属 - 配体络合物。 某些催化剂特别有效地将乙烯和苯乙烯聚合成具有新特性的共聚物，包括低分子量和乙烯基和甲基端基之间的紧密比较。
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12.发明申请
公开(公告)号：WO2008085659A1
公开(公告)日：2008-07-17
申请号：PCT/US2007/087456
申请日：2007-12-13
Applicant: EXXONMOBIL CHEMICAL PATENTS INC. , ACKERMAN, Lily, J. , DIAMOND, Gary, M. , HALL, Keith, A. , LONGMIRE, James, M. , MURPHY, Vincent, J. , VERDUGO, Dawn
Inventor： ACKERMAN, Lily, J. , DIAMOND, Gary, M. , HALL, Keith, A. , LONGMIRE, James, M. , MURPHY, Vincent, J. , VERDUGO, Dawn
CPC classification number: C07F11/005 , B01J31/143 , B01J31/146 , B01J31/2217 , B01J2231/20 , B01J2531/62 , C07C2/32 , C07C2531/14 , C07C2531/22
Abstract: The present invention provides a method of producing oligomers of olefins, comprising reacting olefins with a catalyst under oligomerization conditions. The catalyst can be the product of the combination of a chromium compound and a pyridyl ether compound. In particular embodiments, the catalyst compound can be used to trimerize or tetramerize ethylene to 1 - hexene, 1 -octene, or mixtures of 1 -hexene and 1 -octene.
Abstract translation: 本发明提供一种生产烯烃低聚物的方法，包括在低聚条件下使烯烃与催化剂反应。 催化剂可以是铬化合物和吡啶基醚化合物的组合的产物。 在具体实施方案中，催化剂化合物可用于将乙烯三聚或四聚为1-己烯，1-辛烯或1-己烯和1-辛烯的混合物。
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13.发明申请
公开(公告)号：WO2007075299A3
公开(公告)日：2007-07-05
申请号：PCT/US2006/046867
申请日：2006-12-08
Applicant: DOW GLOBAL TECHNOLOGIES INC. , SYMYX TECHNOLOGIES, INC. , KLOSIN, Jerzy , ACKERMAN, Lily , BEI, Xiaohong , DIAMOND, Gary, M. , LONGMIRE, James , MURPHY, Vince , NAVA-SALGADO, Victor , SHOEMAKER, James A., W.
Inventor： KLOSIN, Jerzy , ACKERMAN, Lily , BEI, Xiaohong , DIAMOND, Gary, M. , LONGMIRE, James , MURPHY, Vince , NAVA-SALGADO, Victor , SHOEMAKER, James A., W.
Abstract: Metal complexes comprising certain polydentate heteroatom containing ligands, catalysts, and coordination polymerization processes employing the same are suitably employed to prepare polymers having desirable physical properties.
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14.发明申请POLYDENTATE HETEROATOM LIGAND CONTAINING METAL COMPLEXES, CATALYSTS AND METHODS OF MAKING AND USING THE SAME 审中-公开包含金属复合物，催化剂及其制备和使用方法的聚异戊二烯配位体
公开(公告)号：WO2007075299A2
公开(公告)日：2007-07-05
申请号：PCT/US2006046867
申请日：2006-12-08
Applicant: DOW GLOBAL TECHNOLOGIES INC , SYMYX TECHNOLOGIES INC , KLOSIN JERZY , ACKERMAN LILY , BEI XIAOHONG , DIAMOND GARY M , LONGMIRE JAMES , MURPHY VINCE , NAVA-SALGADO VICTOR , SHOEMAKER JAMES A W
Inventor： KLOSIN JERZY , ACKERMAN LILY , BEI XIAOHONG , DIAMOND GARY M , LONGMIRE JAMES , MURPHY VINCE , NAVA-SALGADO VICTOR , SHOEMAKER JAMES A W
IPC: B01J31/22
CPC classification number: B01J31/2204 , B01J2231/122 , B01J2531/0238 , B01J2531/46 , B01J2531/48 , B01J2531/49 , C07F7/006 , C08F4/65908 , C08F4/65912 , C08F10/00 , C08F110/06 , C08F112/08 , C08F4/659 , C08F4/64193 , C08F4/64196
Abstract: Metal complexes comprising certain polydentate heteroatom containing ligands, catalysts, and coordination polymerization processes employing the same are suitably employed to prepare polymers having desirable physical properties.
Abstract translation: 包含某些多齿杂原子的配体的金属络合物，催化剂和使用其的配位聚合方法适合用于制备具有所需物理性质的聚合物。
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15.发明申请
公开(公告)号：WO2005108406A1
公开(公告)日：2005-11-17
申请号：PCT/US2005/014670
申请日：2005-04-28
Applicant: SYMYX TECNOLOGIES, INC , BOUSSIE, Thomas, R. , BRUEMMER, Oliver , DIAMOND, Gary, M. , LAPOINTE, Anne, M. , LECLERC, Margarete, K. , MICKLATCHER, Cynthia , SUN, Pu , BEI, Xiaohong
Inventor： BOUSSIE, Thomas, R. , BRUEMMER, Oliver , DIAMOND, Gary, M. , LAPOINTE, Anne, M. , LECLERC, Margarete, K. , MICKLATCHER, Cynthia , SUN, Pu , BEI, Xiaohong
IPC: C07F7/00
CPC classification number: C07F7/006 , C08F4/65908 , C08F4/65912 , C08F10/00 , C08F110/06 , C08F210/16 , C08F4/64193 , C08F4/659 , C08F2500/03 , C08F2500/01 , C08F210/14
Abstract: Ligands, compositions, metal-ligand complexes and arrays with substituted bridged bis-biaromatic ligands and method of making and using the same, are disclosed that are useful in the catalysis of transformations such as the polymerization of monomers into polymers. The catalyts have high performance characteristics, including higher comonomer incorporation into ethylene/olefin copolymers, where such olefins are for exmaple, 1-octene, propylene or styrene. The catalysts also polymerize propylene into isotactic polypropylene.
Abstract translation: 公开了配体，组合物，金属 - 配体配合物和具有取代的桥连双双芳族配体的阵列及其制备和使用它们的方法，其可用于催化转化，例如将单体聚合成聚合物。 催化剂具有高性能特征，包括较高的共聚单体引入到乙烯/烯烃共聚物中，其中这些烯烃用于例示，1-辛烯，丙烯或苯乙烯。 催化剂还将丙烯聚合成全同立构聚丙烯。
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Patent Agency Ranking16.发明申请ETHYLENE/ALPHA-OLEFIN COPOLYMER MADE WITH A NON-SINGLE-SITE/SINGLE-SITE CATALYST COMBINATION, ITS PREPARATION AND USE 审中-公开乙烯/丙烯共聚物与非单一位点/单个催化剂组合制备，其制备和使用
公开(公告)号：WO2003048213A1
公开(公告)日：2003-06-12
申请号：PCT/US2002/032806
申请日：2002-10-11
Applicant: EXXONMOBIL CHEMICAL PATENTS, INC. , NOWLIN, Thomas, E. , SHIRODKAR, Pradeep, P. , MINK, Robert, I. , DIAMOND, Gary, M. , PAUL, Jill, H. , KALE, Lawrence, T. , DACKSON, Keith
Inventor： NOWLIN, Thomas, E. , SHIRODKAR, Pradeep, P. , MINK, Robert, I. , DIAMOND, Gary, M. , PAUL, Jill, H. , KALE, Lawrence, T. , DACKSON, Keith
IPC: C08F2/06
CPC classification number: C08F210/02 , C08F4/65912 , C08F4/65916 , C08F4/65927 , C08F210/16 , C08L23/0815 , C08L2205/02 , C08L2205/025 , C08L2314/02 , C08L2314/06 , Y10T428/31855 , C08F4/65904 , C08F2/06 , C08F4/6546 , C08L2666/04 , C08F210/14 , C08F2500/08 , C08F2500/12 , C08F2500/26
Abstract: An ethylene/α-olefin copolymer comprising a component produced by a non-single-site polymerization catalyst and a component produced by a single-site polymerization catalyst, its preparation and use are described. The copolymer has an α-olefin content of 5 to 20 percent by weight and shows at least two CRYSTAF peak temperatures differing by at least 15 °C and/or at least two DSC melting peak temperatures differing by at least 15 °C.
Abstract translation: 描述了包含由非单位点聚合催化剂制备的组分和通过单中心聚合催化剂制备的组分的乙烯/α-烯烃共聚物，其制备和用途。 该共聚物的α-烯烃含量为5至20重量％，并且显示出至少两个不同于至少15℃的至少两个CRYSTAF峰温度和/或至少两个DSC熔融峰温度相差至少15℃。
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公开(公告)号：WO2006099053A1
公开(公告)日：2006-09-21
申请号：PCT/US2006/008429
申请日：2006-03-09
Applicant: EXXONMOBIL CHEMICAL PATENTS INC. , MCCONVILLE, David H. , ACKERMAN, Lily J. , LI, Robert T , BEI, Xiaohong , KUCHTA, Matthew, C. , BOUSSIE, Thomas, R. , WALZER, John, F. Jr. , DIAMOND, Gary M. , RIX, Francis C. , HALL, Keith A. , LA POINTE, Anne M. , LONGMIRE, James M. , MURPHY, Vincent J. , SUN, Pu , VERDUGO, Dawn , SCHOFER, Susan , DIAS, Eric
Inventor： MCCONVILLE, David H. , ACKERMAN, Lily J. , LI, Robert T , BEI, Xiaohong , KUCHTA, Matthew, C. , BOUSSIE, Thomas, R. , WALZER, John, F. Jr. , DIAMOND, Gary M. , RIX, Francis C. , HALL, Keith A. , LA POINTE, Anne M. , LONGMIRE, James M. , MURPHY, Vincent J. , SUN, Pu , VERDUGO, Dawn , SCHOFER, Susan , DIAS, Eric
CPC classification number: C07C2/32 , C07C2531/22 , C08F10/00 , C08F110/02 , C08F2500/02 , C08F4/69103 , C08F4/69146 , C08F4/69275 , C07C11/02 , C07C11/107
Abstract: The present invention provides a method of producing oligomers of olefins, comprising reacting olefins with a catalyst under oligomerization conditions. The catalyst can be the product of the combination of a chromium compound and a heteroaryl-amine compound. In particular embodiments, the catalyst compound can be used to trimerize or tetramerize ethylene to 1-hexene, 1-octene, or mixtures of 1-hexene and 1-octene.
Abstract translation: 本发明提供一种生产烯烃低聚物的方法，包括在低聚条件下使烯烃与催化剂反应。 催化剂可以是铬化合物和杂芳基 - 胺化合物的组合的产物。 在具体实施方案中，催化剂化合物可用于将乙烯三聚或四聚为1-己烯，1-辛烯或1-己烯和1-辛烯的混合物。
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18.发明申请
公开(公告)号：WO2003087177A3
公开(公告)日：2003-10-23
申请号：PCT/US2003/011456
申请日：2003-04-11
Applicant: SYMYX TECHNOLOGIES, INC. , BRUMMER, Oliver , DIAMOND, Gary, M. , GOH, Christopher , LaPointe, Anne, M. , LECLERC, Margarete, K. , LONGMIRE, James , SHOEMAKER, James, A., W.
Inventor： BRUMMER, Oliver , DIAMOND, Gary, M. , GOH, Christopher , LaPointe, Anne, M. , LECLERC, Margarete, K. , LONGMIRE, James , SHOEMAKER, James, A., W.
IPC: C08F4/642
Abstract: Metal-ligand complexes that are useful as precusors to catalysts for the polymerization of olefins are provided. Certain of the catalysts are particularly effective at polymerizing ethylene and styrene into copolymers having novel properties, including a low molecular weight and close comparison between vinyl and methyl end groups.
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19.发明申请
公开(公告)号：WO2010078164A1
公开(公告)日：2010-07-08
申请号：PCT/US2009/069272
申请日：2009-12-22
Applicant: SYMYX SOLUTIONS, INC. , DIAMOND, Gary, M. , LECLERC, Margarete, K. , ZHU, Guang
Inventor： DIAMOND, Gary, M. , LECLERC, Margarete, K. , ZHU, Guang
IPC: C08F8/00
CPC classification number: C08F4/76 , C08F4/64193 , C08F10/00 , C08F110/02 , C08F2500/01 , C08F2500/03
Abstract: The field of the invention relates generally to a method for preparing very-high or ultra-high molecular weight polyethylene. More particularly, the present invention related to a method of preparing very-high or ultra-high molecular weight polyethylene using a supported catalyst comprising a support, an activator and a metal-ligand complex, as well as the catalyst itself. The present invention additionally relates to a method of using a supported catalyst comprising a support, an activator and co-supported metal-ligand complexes to obtain a bi-modal molecular weight distribution of polyethylene.
Abstract translation: 本发明的领域一般涉及制备非常高或超高分子量聚乙烯的方法。 更具体地说，本发明涉及使用包含载体，活化剂和金属 - 配体络合物的负载催化剂以及催化剂本身制备非常高或超高分子量聚乙烯的方法。 本发明还涉及使用包含载体，活化剂和共支持的金属 - 配体络合物的负载催化剂以获得聚乙烯的双峰分子量分布的方法。
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公开(公告)号：WO2008143739A3
公开(公告)日：2009-03-05
申请号：PCT/US2008004200
申请日：2008-03-31
Applicant: SYMYX TECHNOLOGIES INC , DIAMOND GARY M , HALL KEITH A , MCWAID THOMAS HARDING , MURPHY VINCE , MYSLOVATY MICHAEL , SHOEMAKER JAMES A W , SIDHU ROBBIE SINGH , TURNER HOWARD , DIAS ERIC , SPITKOVSKY MIKHAIL
Inventor： DIAMOND GARY M , HALL KEITH A , MCWAID THOMAS HARDING , MURPHY VINCE , MYSLOVATY MICHAEL , SHOEMAKER JAMES A W , SIDHU ROBBIE SINGH , TURNER HOWARD , DIAS ERIC , SPITKOVSKY MIKHAIL
CPC classification number: C40B60/14 , B01J19/0046 , B01J2219/00283 , B01J2219/00308 , B01J2219/00389 , B01J2219/00477 , B01J2219/00481 , B01J2219/00495 , B01J2219/00585 , B01J2219/00599 , B01J2219/00601 , B01J2219/00689 , B01J2219/00691 , B01J2219/00695 , B01J2219/00698 , B01J2219/0072 , B01J2219/00736 , F16K27/003
Abstract: In one embodiment, a parallel batch reactor for effecting chemical reactions includes a vessel block (24) comprising reactor vessels (32) for receiving components of a reaction and a valve block (23) removably attached to the vessel block. The valve block (22) includes a first plurality of valves (72) in fluid communication with an inlet port for supplying pressurized fluid to the reactor vessels. (32) and configured to fluidically isolate one or more of the reactor vessels from (32) at least one of the other reactor vessels (32) The valve block (22) further includes a second plurality of valves (76) in fluid communication with the reactor vessels for injecting chemical components into the pressurized reactor vessels (32) or sampling chemical components from the pressurized reactor vessels (32) The vessel block (26) and valve block (22) are configured to sustain an operating pressure of at least 15 psig. A stirring assembly (26) may also be present.
Abstract translation: 在一个实施方案中，用于实现化学反应的并行批量反应器包括容器块（24），其包含用于接收反应组分的反应器容器（32）和可移除地附接到容器块的阀块（23）。 阀块（22）包括与用于将加压流体供应到反应器容器的入口流体连通的第一多个阀（72）。 （32）并且构造成将一个或多个反应器容器与（32）中的至少一个流体地隔离在另一反应器容器（32）中。阀块（22）还包括第二多个阀（76），其与 用于将化学组分注入加压反应器容器（32）或从加压反应器容器（32）取样化学组分的反应器容器。容器块（26）和阀块（22）被构造成维持至少15的操作压力 磅。 搅拌组件（26）也可以存在。
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