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1.发明申请PHENOL-HETEROCYCLIC LIGANDS, METAL COMPLEXES, AND THEIR USES AS CATALYSTS 审中-公开酚 - 杂环配体，金属络合物及其用作催化剂
公开(公告)号：WO2006066126A2
公开(公告)日：2006-06-22
申请号：PCT/US2005/045766
申请日：2005-12-16
Applicant: SYMYX TECHNOLOGIES, INC. , LECLERC, Margarete, K. , BEI, Xiahong , LONGMIRE, James , DIAMOND, Gary, M. , SHOEMAKER, James, A., W. , LAPOINTE, Anne, M. , ACKERMAN, Lily
Inventor： LECLERC, Margarete, K. , BEI, Xiahong , LONGMIRE, James , DIAMOND, Gary, M. , SHOEMAKER, James, A., W. , LAPOINTE, Anne, M. , ACKERMAN, Lily
IPC: C07F7/00 , C07F7/28 , C08F10/00 , C08F12/00 , C08F4/76 , C07D231/12 , C07D231/56 , C07D233/54 , C07D235/06 , C07D271/06 , C07D277/20
CPC classification number: C07D271/06 , C07D277/22 , C07F7/00 , C07F7/006 , C08F4/65908 , C08F4/65912 , C08F10/00 , C08F12/08 , C08F110/06 , C08F110/14 , C08F210/16 , C08F4/659 , C08F2500/03 , C08F210/14 , C08F4/64048 , C08F2500/06
Abstract: Ligands, compositions, and metal-ligand complexes that incorporate phenol-heterocyclic compounds are disclosed that are useful in the catalysis of transformations such as the polymerization of monomers into polymers. The catalysts have high performance characteristics, including high comonomer incorporation into ethylene/olefin copolymers, where such olefins are for example, 1-octene, propylene or styrene. The catalysts particularly polymerize styrene to form polystyrene.
Abstract translation: 公开了掺入酚 - 杂环化合物的配体，组合物和金属 - 配体络合物，其可用于催化转化，例如将单体聚合成聚合物。 催化剂具有高性能特征，包括高共聚单体掺入到乙烯/烯烃共聚物中，其中这些烯烃是例如1-辛烯，丙烯或苯乙烯。 催化剂特别聚合苯乙烯以形成聚苯乙烯。
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2.发明申请SYSTEM AND METHOD FOR RAPID CHROMATOGRAPHY WITH FLUID TEMPERATURE AND MOBILE PHASE COMPOSITION CONTROL 审中-公开具有流体温度和移动相组成控制的快速色谱的系统和方法
公开(公告)号：WO2006029017A1
公开(公告)日：2006-03-16
申请号：PCT/US2005/031417
申请日：2005-09-02
Applicant: SYMYX TECHNOLOGIES, INC. , PETRO, Miroslav , DIAMOND, Gary, M. , McWAID, Thomas, Harding , HALL, Keith, Anthony , LI, Song , TREVOR G., Frank
Inventor： PETRO, Miroslav , DIAMOND, Gary, M. , McWAID, Thomas, Harding , HALL, Keith, Anthony , LI, Song , TREVOR G., Frank
CPC classification number: G01N30/30 , B01D15/161 , B01D15/166 , G01N30/20 , G01N30/28 , G01N30/32 , G01N30/34 , G01N30/80
Abstract: The invention relates to liquid chromatography techniques for rapidly characterizing samples, such as polymer solutions, emulsions and dispersions, and to devices for implementing such techniques. The system includes a design that provides the ability to perform chromatographic separations by using mobile phase composition gradients and temperature gradients during separations. The invention accomplishes this by providing mixing zones for a plurality of fluids as well as heated and chilled feeds feeding the fluids to the mixing zones. Additionally, the system provides the ability to analyze separated components with a detector and/or collect separated fractions into vessels of a fraction collector for further separation and/or analysis.
Abstract translation: 本发明涉及用于快速表征样品的液相色谱技术，例如聚合物溶液，乳液和分散体，以及用于实施这些技术的装置。 该系统包括通过在分离期间使用流动相组成梯度和温度梯度提供进行色谱分离的能力的设计。 本发明通过为多种流体提供混合区域以及将流体供给到混合区域的加热和冷冻进料来实现。 此外，该系统提供了利用检测器分析分离的组分和/或将分离的馏分收集到馏分收集器的容器中用于进一步分离和/或分析的能力。
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3.发明申请
公开(公告)号：WO2005108406B1
公开(公告)日：2006-02-09
申请号：PCT/US2005014670
申请日：2005-04-28
Applicant: SYMYX TECNOLOGIES INC , BOUSSIE THOMAS R , BRUEMMER OLIVER , DIAMOND GARY M , LAPOINTE ANNE M , LECLERC MARGARETE K , MICKLATCHER CYNTHIA , SUN PU , BEI XIAOHONG
Inventor： BOUSSIE THOMAS R , BRUEMMER OLIVER , DIAMOND GARY M , LAPOINTE ANNE M , LECLERC MARGARETE K , MICKLATCHER CYNTHIA , SUN PU , BEI XIAOHONG
IPC: C07F5/00 , C07F7/00 , C07F9/00 , C07F11/00 , C08F4/659 , C08F10/00 , C08F110/06 , C08F210/16
CPC classification number: C07F7/006 , C08F4/65908 , C08F4/65912 , C08F10/00 , C08F110/06 , C08F210/16 , C08F4/64193 , C08F4/659 , C08F2500/03 , C08F2500/01 , C08F210/14
Abstract: Ligands, compositions, metal-ligand complexes and arrays with substituted bridged bis-biaromatic ligands and method of making and using the same, are disclosed that are useful in the catalysis of transformations such as the polymerization of monomers into polymers. The catalyts have high performance characteristics, including higher comonomer incorporation into ethylene/olefin copolymers, where such olefins are for exmaple, 1-octene, propylene or styrene. The catalysts also polymerize propylene into isotactic polypropylene.
Abstract translation: 公开了配体，组合物，金属 - 配体配合物和具有取代的桥连双双芳族配体的阵列及其制备和使用它们的方法，其可用于催化转化，例如将单体聚合成聚合物。 催化剂具有高性能特征，包括较高的共聚单体引入到乙烯/烯烃共聚物中，其中这些烯烃用于例示，1-辛烯，丙烯或苯乙烯。 催化剂还将丙烯聚合成全同立构聚丙烯。
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公开(公告)号：WO2002090393A1
公开(公告)日：2002-11-14
申请号：PCT/US2002/010326
申请日：2002-04-04
Applicant: EXXONMOBIL CHEMICAL PATENTS INC. , BARRY, David, B. , DIAMOND, Gary, M. , FRUITWALA, Hitesh, A. , ONG, S., Christine , WANG, Chunming
Inventor： BARRY, David, B. , DIAMOND, Gary, M. , FRUITWALA, Hitesh, A. , ONG, S., Christine , WANG, Chunming
IPC: C08F4/44
CPC classification number: C08F210/16 , C08F4/65912 , C08F4/65916 , C08F4/65925 , C08F4/6565 , C08F4/65904 , C08F210/14 , C08F2500/07 , C08F2500/12 , C08F2500/13
Abstract: The invention provides ethylene/α-olefin copolymers exhibiting improved environmental stress cracking resistance properties, and methods for the production of the copolymers in a single reactor by means of a bimetallic catalyst including a Ziegler component and a metallocene component.
Abstract translation: 本发明提供了具有改进的耐环境应力开裂性能的乙烯/α-烯烃共聚物，以及通过包括齐格勒组分和茂金属组分的双金属催化剂在单个反应器中制备共聚物的方法。
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公开(公告)号：WO2008143739A2
公开(公告)日：2008-11-27
申请号：PCT/US2008/004200
申请日：2008-03-31
Applicant: SYMYX TECHNOLOGIES, INC. , DIAMOND, Gary, M. , HALL, Keith, A. , McWAID, Thomas, Harding , MURPHY, Vince , MYSLOVATY, Michael , SHOEMAKER, James, A., W. , SIDHU, Robbie, Singh , TURNER, Howard , DIAS, Eric , SPITKOVSKY, Mikhail
Inventor： DIAMOND, Gary, M. , HALL, Keith, A. , McWAID, Thomas, Harding , MURPHY, Vince , MYSLOVATY, Michael , SHOEMAKER, James, A., W. , SIDHU, Robbie, Singh , TURNER, Howard , DIAS, Eric , SPITKOVSKY, Mikhail
CPC classification number: C40B60/14 , B01J19/0046 , B01J2219/00283 , B01J2219/00308 , B01J2219/00389 , B01J2219/00477 , B01J2219/00481 , B01J2219/00495 , B01J2219/00585 , B01J2219/00599 , B01J2219/00601 , B01J2219/00689 , B01J2219/00691 , B01J2219/00695 , B01J2219/00698 , B01J2219/0072 , B01J2219/00736 , F16K27/003
Abstract: In one embodiment, a parallel batch reactor for effecting chemical reactions includes a vessel block comprising reactor vessels for receiving components of a reaction and a valve block removably attached to the vessel block. The valve block includes a first plurality of valves in fluid communication with an inlet port for supplying pressurized fluid to the reactor vessels and configured to fluidically isolate one or more of the reactor vessels from at least one of the other reactor vessels. The valve block further includes a second plurality of valves in fluid communication with the reactor vessels for injecting chemical components into the pressurized reactor vessels or sampling chemical components from the pressurized reactor vessels. The vessel block and valve block are configured to sustain an operating pressure of at least 15 psig.
Abstract translation: 在一个实施方案中，用于实现化学反应的并行批量反应器包括容器块，其包含用于接收反应组分的反应器容器和可移除地附接到容器块的阀块。 阀块包括与入口端口流体连通的第一多个阀，用于将加压流体供应到反应器容器并且构造成将一个或多个反应器容器与至少一个其它反应器容器进行流体隔离。 阀块还包括与反应器容器流体连通的第二多个阀，用于将化学组分注入加压反应器容器或从加压反应器容器取样化学组分。 容器块和阀块被配置为维持至少15psig的操作压力。
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Patent Agency Ranking6.发明申请METHODS FOR OLIGOMERIZING OLEFINS WITH CHROMIUM PYRIDINE THIOETHER CATALYSTS 审中-公开烯烃与吡啶二硫化物催化剂低聚的方法
公开(公告)号：WO2008085658A1
公开(公告)日：2008-07-17
申请号：PCT/US2007/087446
申请日：2007-12-13
Applicant: EXXONMOBIL CHEMICAL PATENTS INC. , ACKERMAN, Lily, J. , DIAMOND, Gary, M. , HALL, Keith, A. , LONGMIRE, James, M. , MURPHY, Vincent, J. , VERDUGO, Dawn
Inventor： ACKERMAN, Lily, J. , DIAMOND, Gary, M. , HALL, Keith, A. , LONGMIRE, James, M. , MURPHY, Vincent, J. , VERDUGO, Dawn
CPC classification number: C07F11/005 , C07C2/32
Abstract: The present invention provides a method of producing oligomers of olefins, comprising reacting olefins with a chromium based catalyst under oligomerization conditions. The catalyst can be the product of the combination of a chromium compound and a pyridyl thioether compound. In particular embodiments, the catalyst compound can be used to trimerize or tetramerize ethylene to 1 -hexene, 1 -octene, or mixtures of 1 -hexene and 1 -octene.
Abstract translation: 本发明提供了一种生产烯烃低聚物的方法，包括在低聚条件下使烯烃与铬基催化剂反应。 催化剂可以是铬化合物和吡啶基硫醚化合物的组合的产物。 在具体实施方案中，催化剂化合物可用于将乙烯三聚或四聚为1-己烯，1-辛烯或1-己烯和1-辛烯的混合物。
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7.发明申请METHODS FOR OLIGOMERIZING OLEFINS WITH CHROMIUM PYRIDINE MONO-OXAZOLINE CATALYSTS 审中-公开用烯丙基吡啶单氧杂环丁烷催化剂低聚烯烃的方法
公开(公告)号：WO2008085655A1
公开(公告)日：2008-07-17
申请号：PCT/US2007/087380
申请日：2007-12-13
Applicant: EXXONMOBIL CHEMICAL PATENTS INC. , ACKERMAN, Lily, J. , DIAMOND, Gary, M. , HALL, Keith, A. , LONGMIRE, James, M. , MICKLATCHER, Mark
Inventor： ACKERMAN, Lily, J. , DIAMOND, Gary, M. , HALL, Keith, A. , LONGMIRE, James, M. , MICKLATCHER, Mark
CPC classification number: C07F11/005
Abstract: The present invention provides a method of producing oligomers of olefins, comprising reacting olefins with a chromium based catalyst under oligomerization conditions. The catalyst can be the product of the combination of a chromium compound and a pyridyl mono-oxazoline compound. In particular embodiments, the catalyst compound can be used to trimerize or tetramerize ethylene to 1 -hexene, 1 - octene, or mixtures of 1 -hexene and 1 -octene.
Abstract translation: 本发明提供了一种生产烯烃低聚物的方法，包括在低聚条件下使烯烃与铬基催化剂反应。 催化剂可以是铬化合物和吡啶基单恶唑啉化合物的组合的产物。 在具体实施方案中，催化剂化合物可用于将乙烯三聚或四聚为1-己烯，1-辛烯或1-己烯和1-辛烯的混合物。
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8.发明申请METHODS FOR OLIGOMERIZING OLEFINS WITH CHROMIUM PYRIDINE PHOSPHINO CATALYSTS 审中-公开用烯丙基磷酰基催化剂低聚烯烃的方法
公开(公告)号：WO2008085653A1
公开(公告)日：2008-07-17
申请号：PCT/US2007/087340
申请日：2007-12-13
Applicant: EXXONMOBIL CHEMICAL PATENTS INC. , ACKERMAN, Lily, J. , DIAMOND, Gary, M. , HALL, Keith, A. , LONGMIRE, James, M. , MURPHY, Vincent, J. , NAVA-SALGADO, Victor, O.
Inventor： ACKERMAN, Lily, J. , DIAMOND, Gary, M. , HALL, Keith, A. , LONGMIRE, James, M. , MURPHY, Vincent, J. , NAVA-SALGADO, Victor, O.
CPC classification number: C07F11/005 , B01J31/189 , B01J2231/20 , B01J2531/62 , C07C2/36 , C07C2531/14 , C07C2531/24
Abstract: The present invention provides a method of producing oligomers of olefins, comprising reacting olefins with a catalyst under oligomerization conditions. The catalyst can be the product of the combination of a chromium compound and a pyridyl phosphino compound. In particular embodiments, the catalyst compound can be used to trimerize or tetramerize ethylene to 1 -hexene, 1 -octene, or mixtures of 1 -hexene and 1 - octene.
Abstract translation: 本发明提供一种生产烯烃低聚物的方法，包括在低聚条件下使烯烃与催化剂反应。 催化剂可以是铬化合物和吡啶基膦基化合物的组合的产物。 在具体实施方案中，催化剂化合物可用于将乙烯三聚或四聚为1-己烯，1-辛烯或1-己烯和1-辛烯的混合物。
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公开(公告)号：WO2006096881A1
公开(公告)日：2006-09-14
申请号：PCT/US2006/008926
申请日：2006-03-09
Applicant: EXXONMOBIL CHEMICAL PATENTS INC. , ACKERMAN, Lily, J. , BEI, Xiaohong , BOUSSIE, Thomas, R. , DIAMOND, Gary, M. , HALL, Keith, A. , LAPOINTE, Anne, M. , LONGMIRE, James, M. , MURPHY, Vincent, J. , SUN, Pu , VERDUGO, Dawn , SCHOFER, Susan , DIAS, Eric , MCCONVILLE, David, H. , LI, Robert, T. , WALZER, John , RIX, Francis , KUCHTA, Matthew
Inventor： ACKERMAN, Lily, J. , BEI, Xiaohong , BOUSSIE, Thomas, R. , DIAMOND, Gary, M. , HALL, Keith, A. , LAPOINTE, Anne, M. , LONGMIRE, James, M. , MURPHY, Vincent, J. , SUN, Pu , VERDUGO, Dawn , SCHOFER, Susan , DIAS, Eric , MCCONVILLE, David, H. , LI, Robert, T. , WALZER, John , RIX, Francis , KUCHTA, Matthew
CPC classification number: C07C2/32 , C07C2531/22 , C08F10/00 , C08F110/02 , C08F2500/02 , C08F4/69103 , C08F4/69146 , C08F4/69275 , C07C11/02 , C07C11/107
Abstract: The present invention provides a method of producing oligomers of olefins, comprising reacting olefins with a catalyst under oligomerization conditions. The catalyst can be the product of the combination of a chromium compound and a pyridyl amine or a heteroaryl-amine compound. In particular embodiments, the catalyst compound can be used to trimerize or tetramerize ethylene to 1-hexene, 1-octene, or mixtures of 1-hexene and 1-octene.
Abstract translation: 本发明提供一种生产烯烃低聚物的方法，包括在低聚条件下使烯烃与催化剂反应。 催化剂可以是铬化合物和吡啶基胺或杂芳基 - 胺化合物的组合的产物。 在具体实施方案中，催化剂化合物可用于将乙烯三聚或四聚为1-己烯，1-辛烯或1-己烯和1-辛烯的混合物。
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10.发明申请PHENOL-HETEROCYCLIC LIGANDS, METAL COMPLEXES, AND THEIR USES AS CATALYSTS 审中-公开苯酚 - 杂环配体，金属络合物及其作为催化剂的用途
公开(公告)号：WO2006066126A3
公开(公告)日：2006-08-24
申请号：PCT/US2005045766
申请日：2005-12-16
Applicant: SYMYX TECHNOLOGIES INC , LECLERC MARGARETE K , BEI XIAHONG , LONGMIRE JAMES , DIAMOND GARY M , SHOEMAKER JAMES A W , LAPOINTE ANNE M , ACKERMAN LILY
Inventor： LECLERC MARGARETE K , BEI XIAHONG , LONGMIRE JAMES , DIAMOND GARY M , SHOEMAKER JAMES A W , LAPOINTE ANNE M , ACKERMAN LILY
IPC: C07F7/00 , C07D231/12 , C07D231/56 , C07D233/54 , C07D235/06 , C07D271/06 , C07D277/20 , C07F7/28 , C08F4/76 , C08F10/00 , C08F12/00
CPC classification number: C07D271/06 , C07D277/22 , C07F7/00 , C07F7/006 , C08F4/65908 , C08F4/65912 , C08F10/00 , C08F12/08 , C08F110/06 , C08F110/14 , C08F210/16 , C08F4/659 , C08F2500/03 , C08F210/14 , C08F4/64048 , C08F2500/06
Abstract: Ligands, compositions, and metal-ligand complexes that incorporate phenol-heterocyclic compounds are disclosed that are useful in the catalysis of transformations such as the polymerization of monomers into polymers. The catalysts have high performance characteristics, including high comonomer incorporation into ethylene/olefin copolymers, where such olefins are for example, 1-octene, propylene or styrene. The catalysts particularly polymerize styrene to form polystyrene.
Abstract translation: 公开了掺入苯酚 - 杂环化合物的配体，组合物和金属 - 配体络合物，其可用于转化的催化作用，例如将单体聚合成聚合物。 该催化剂具有高性能特征，包括高共聚单体结合到乙烯/烯烃共聚物中，其中这种烯烃例如是1-辛烯，丙烯或苯乙烯。 催化剂特别使苯乙烯聚合形成聚苯乙烯。
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