Abstract:
The invention relates to a method for producing aldehyde functional compounds by a cross-metathesis reaction of an olefinic compound having at least one hydroxy group and at least one C—C double bond with at least one at least monounsaturated fatty acid or at least one at least monounsaturated fatty acid derivative, in the presence of a metathesis catalyst at a maximum temperature of 180° C. and in the presence of at least one reagent that acts as a protective group-forming compound in relation to the aldehyde group of the aldehyde functional compounds.
Abstract:
A molding compound, containing at least 30% by weight of a copolyamide, which is derived from the following monomers: a) 50 to 95 mole percent of the combination of a diamine, selected from the group consisting of 1,9-nonane diamine, 1,10-decane diamine, 1,11-undecane diamine and 1,12-dodecane diamine, and terephthalic acid, and b) 5 to 50 mole percent of the combination of a diamine, selected from the group consisting of 2,2,4-trimethylhexamethylene diamine, 2,4,4-trimethylhexamethylene diamine, and mixtures thereof, and terephthalic acid. The copolyamide is crystalline and has low water absorption.
Abstract:
The invention relates to a plant for carrying out chemical reactions, having a reactor (1), the reaction space of which contains hydrogen peroxide (H2O2) and titanium silicalite (TS-1). The object of the invention is to improve such a plant such that continuous separation and recycling of the active catalyst to the reaction space is possible with a long filter service life. This is achieved in that the reaction space contains a solid silicon source, in that the plant comprises a water takeoff line (3) which is set up for drawing off water in addition to components which are dissolved and/or dispersed therein from the reaction space, in that the water takeoff line (3) leads to a filter (4) which separates off the components which are dissolved and/or dispersed in the water, and in that the plant has a return line (5) which is set up for recirculating to the reaction space components which are separated off by means of the filter (4).
Abstract translation:本发明涉及一种用于进行化学反应的设备,其具有反应器(1),其反应空间含有过氧化氢(H 2 O 2)和钛硅沸石(TS-1)。 本发明的目的是改进这种设备,使得活性催化剂在反应空间的连续分离和循环是可能的,并具有长的过滤器使用寿命。 这是通过反应空间包含固体硅源实现的,因为该设备包括除了从反应空间溶解和/或分散在其中的组分除去水以外的水引出线(3) 因为水引出线(3)通过一个过滤器(4),该过滤器(4)将溶解和/或分散在水中的组分分离出来,并且该设备具有一个回流管线(5) 再循环到通过过滤器(4)分离的反应空间部件。
Abstract:
The present invention is directed to a process for preparing amides. In particular, the process is directed to a process performable on the industrial scale, in which a ketoxime can be converted to a cyclic or acyclic amide by means of a Beckmann rearrangement using 2,4,6-trichloro-1,3,5-triazine as a catalyst in a nonpolar organic solvent.
Abstract:
A process for preparing cyclododecene by selective gas-phase hydrogenation of at least one starting material selected from cyclododecatriene, cyclododecadiene and mixtures thereof, wherein the starting material present in the gas phase is hydrogenated in the presence of a catalyst in a fixed-bed reactor and the Bodenstein number for the process is greater than 100.
Abstract:
The present invention concerns a process for separation of a monomer including at least one double bond, hereafter referred to as “monomer,” in particular (meth)acrylic acid, from a composition Z including this monomer and at least one impurity different to the monomer, including the steps of bringing into contact of the composition Z with an additive by forming a separation phase. The additive has a melting point of at most about 150° C. and a vapour pressure at a temperature of 20° C. of at most about 1 mbar. The monomer is then separated from the separation phase. A device for producing a monomer, the use of additives in the separation of a monomer from a monomer-comprising composition, the monomer obtainable by the process according to the invention, chemical products comprising the monomer as well as the use of the monomer in or for production of chemical products.
Abstract:
The invention concerns a process for purification of an acidic monomer having a double bond, as well as a device for synthesis of an acidic monomer having a double bond, a process for producing an acidic monomer having a double bond, an acid monomer having a double bond and obtainable by this process, fibres, formed bodies, films, foams, superabsorbent polymers and other special polymers based on or containing this acidic monomer, the use of this acidic monomer in or for producing fibres, formed bodies, films, foams, superabsorbent polymers or other special polymers.
Abstract:
A system for operating a door lock (14) and a latching device (16), which can be arrested in a positive-locking manner, of a sliding door (10), said latching device preventing the sliding door (10) in its open position from sliding back. The operation of the door lock (14) and latching device (16) takes place mechanically via connecting elements, and the logical closing functions, are integrated in the door lock (14) which is situated remote from the door handles. In order to avoid very long connecting elements with cumulative tolerances, the connecting elements (22, 24) between the door handles and the door lock (14) have driver elements (40, 42) which act via a driven element (32, 44) on a connecting element (28) connected to the latching device (16).
Abstract:
A test probe for collecting test permeate samples from a multiple, reverse-osmosis membrane module, wherein the membrane module has a straight permeate-collection passageway and a plurality of individual, spaced-apart, permeate passageways which permit permeate, from each of a plurality of membranes, to flow into the permeate-collection passageway, and which probe comprises a first outer and a second inner tube concentrically positioned and spaced apart, whereby, on insertion of the test probe into the permeate-collection passageway, the test probe comprises a downstream permeate flow passageway and an upstream permeate flow passageway and a test permeate flow passageway, the test probe having a spacer element at the test end with a radial passageway, and resilient O-rings above and below the spacer element, and a coiled spring to bias the O-rings between an unbiased, nonsealing position and a biased, sealing position, whereby the O-rings extend radially outwardly, to form a seal above and below a test permeate passageway, and permit flow of the permeate from the individual passageways into the test permeate flow passageway, while not disrupting the flow of the upstream and downstream permeate.
Abstract:
Cyclododecanone (CDON) is prepared by epoxidizing cyclododecene (CDEN) to epoxycyclododecane (CDAN epoxide), and rearranging the CDAN epoxide to CDON to obtain a mixture comprising said CDON and CDEN, wherein CDEN is separated from the CDON-containing mixture and sent to the epoxidation to CDAN epoxide in step a.