公开(公告)号：US5658669A

公开(公告)日：1997-08-19

申请号：US435496

申请日：1995-05-05

Applicant: Olaf Althoff ,  Uwe Falk ,  Ude Scheunemann ,  Werner Prass ,  Werner Hickel

Inventor： Olaf Althoff ,  Uwe Falk ,  Ude Scheunemann ,  Werner Prass ,  Werner Hickel

IPC: B01D53/22 ,  B01D69/12 ,  B01D71/32 ,  B01D71/36 ,  B01D71/38 ,  B05D1/20 ,  B32B5/18 ,  B32B27/00 ,  B32B27/08 ,  B32B27/16 ,  B32B27/30

CPC classification number: B01D69/122 ,  B01D53/228 ,  B01D71/34 ,  B01D71/76 ,  B01D61/362 ,  B01D71/32 ,  B01D71/38 ,  B01D71/40 ,  Y10T428/3154 ,  Y10T428/31544

Abstract: A composite membrane comprises a porous carrier membrane (A) and a fluorine-containing permselective layer (C) which is a copolymer and has a thickness of 10 to 500 nm. The copolymer of layer (C) comprisesa) 10 to 80 mol % of monomer units of a vinyl ester of the formula (I) ##STR1## in which R.sup.1, R.sup.2 and R.sup.3 are hydrogen, alkyl radicals, cycloalkyl radicals or aryl radicals, and these radicals together have at least 5 and not more than 30 carbon atoms,b1) 5 to 50 mol % of monomer units of a vinyl alcohol of the formula (II) ##STR2## in which R.sup.4 is the hydroxyl group and up to 10% of the groups R.sup.4 can be replaced by radicals of the formula OCOR.sup.5, in which R.sup.5 is methyl, ethyl or propyl, orb2) 5 to 50 mol % of monomer units of the formula (III) ##STR3## in which R.sup.6 is a straight-chain or branched alkylene radical having 1 to 6 carbon atoms, andc) at least 10 mol % of a fluoroolefin, the chains containing hydroxyl groups being crosslinked with one another, in particular by multifunctional isocyanates. The membrane can be employed, inter alia, for gas separation and pervaporation.

Abstract translation: 复合膜包括多孔载体膜（A）和作为共聚物的厚度为10〜500nm的含氟选择渗透层（C）。 层（C）的共聚物包含a）10至80mol％的式（I）的乙烯基酯单体单元（1），其中R 1，R 2和R 3是氢，烷基，环烷基或 芳基，这些基团一起具有至少5个且不多于30个碳原子，b1）5-50mol％的式（II）的乙烯醇的单体单元，其中R 4是 羟基和至多10％的基团R 4可以被式OCOR 5的基团取代，其中R 5是甲基，乙基或丙基，或者b2）5至50摩尔％的式（III）单体单元

公开(公告)号：US5432286A

公开(公告)日：1995-07-11

申请号：US133502

申请日：1993-10-07

Applicant: Ivan Cabrera ,  Uwe Falk ,  Werner Hickel ,  Donald Lupo ,  Ude Scheunemann ,  Peter Boldt ,  Martin Blenkle

Inventor： Ivan Cabrera ,  Uwe Falk ,  Werner Hickel ,  Donald Lupo ,  Ude Scheunemann ,  Peter Boldt ,  Martin Blenkle

IPC: B05D1/20 ,  C07D495/04 ,  G02F1/35 ,  G02F1/355 ,  G02F1/361 ,  G02F1/365 ,  G02F1/37 ,  C07D493/04

CPC classification number: C07D495/04 ,  B05D1/202 ,  B82Y20/00 ,  B82Y30/00 ,  B82Y40/00 ,  G02F1/3614 ,  G02F1/3618

Abstract: Substituted thieno[3,2-b]thiophenes, processes for their preparation and their useCompounds of the formula I ##STR1## in which R is a C.sub.1 - to C.sub.22 -alkyl radical,A.sup.1 and A.sup.2 are hydrogen or methyl orA.sup.1 is hydrogen and A.sup.2 is the nitro group, andB is the cyano group, the nitro group or an electron-attracting organic group having a double bond which is in conjugation with the thieno[3,2-b]thiophene ring system,have a high dipole moment and a high polarizability and are suitable for purposes of nonlinear optics. If R in the formula I is a C.sub.12 - to C.sub.22 -alkyl radical, monomolecular layers can be applied to a substrate by the Langmuir-Blodgett method. The resulting layer elements are suitable, inter alia, as waveguides.

Abstract translation: 取代的噻吩并[3,2-b]噻吩，其制备方法及用途其中R为C 1至C 22 - 烷基的式I的化合物，A 1和A 2为氢或甲基或A 1为 氢和A2是硝基，B是氰基，硝基或具有与噻吩并[3,2-b]噻吩环体系共轭的双键的吸电子有机基团具有高的 偶极矩和高极化性，适用于非线性光学。 如果式I中的R是C 12 -C 22烷基，则可以通过Langmuir-Blodgett法将单分子层施加到基底上。 所得到的层元件尤其适用于波导。

公开(公告)号：US5429842A

公开(公告)日：1995-07-04

申请号：US108119

申请日：1993-08-17

Applicant: Gunther Appel ,  Jacqueline Bauer ,  Werner Hickel ,  Donald Lupo ,  Werner Prass ,  Ude Scheunemann

Inventor： Gunther Appel ,  Jacqueline Bauer ,  Werner Hickel ,  Donald Lupo ,  Werner Prass ,  Ude Scheunemann

IPC: B05C3/09 ,  B05C3/132 ,  B05D1/20 ,  B05C3/02

CPC classification number: B82Y30/00 ,  B05D1/206 ,  B82Y40/00

Abstract: In order to continuously produce an ultrathin, ordered layer of amphiphilic molecules on the surface of a polar liquid a directed flow of the polar liquid is produced in a duct which contains the amphiphilic molecules in dissolved or undissolved form on the surface in spread form. In the duct, a duct section having a relatively high flow rate on the surface and comprising a ramp which is arranged at the bottom of the duct and washed over by the polar liquid is provided. This is followed by a duct section having a relatively low flow rate on the surface, in which the flow is dammed up at an obstacle at a liquid level constant with time, so that an ultrathin, ordered layer of amphiphilic molecules is continuously formed in these duct sections at the polar liquid/air interface by compression of the flow. The washed over ramp is movable.

Abstract translation: 为了在极性液体的表面上连续生产超薄有序的两亲分子层，极性液体的定向流在包含以扩散形式的表面上溶解或未溶解的形式的两亲分子的管道中产生。 在管道中，具有在表面上具有相对较高流速的管道部分，并且包括布置在管道底部并被极性液体洗涤的斜面。 其后是在表面上具有相对较低流速的管道部分，其中流动在障碍物处以随时间恒定的液面被阻塞，使得在这些中连续形成两极分子的超薄有序层 通过压缩流体在极性液体/空气界面处的管道部分。 洗过的坡道是可移动的。

公开(公告)号：US5120809A

公开(公告)日：1992-06-09

申请号：US453669

申请日：1989-12-20

Applicant: Donald Lupo ,  Werner Prass ,  Ude Scheunemann

Inventor： Donald Lupo ,  Werner Prass ,  Ude Scheunemann

IPC: B05D1/20 ,  B32B27/30 ,  C07C233/05 ,  C07C233/80 ,  C08F20/34 ,  C08F20/36 ,  C08F20/52 ,  C08F20/60 ,  C08J5/18

CPC classification number: B05D1/202 ,  B82Y30/00 ,  B82Y40/00 ,  C07C233/05 ,  C08F20/36 ,  C08F20/60

Abstract: Amphiphilic monomers with mixed-chain structures of the formula ##STR1## in which Y denotes --O-- or --NH--X denotes a group of the formula --(CH.sub.2).sub.n -- or --(CH.sub.2 --O--CH.sub.2).sub.n --l denotes an integer from 0 to 10,n denotes an integer from 1 to 10,R.sup.1 denotes hydrogen, methyl, chlorine, cyano, fluorine or bromine,R.sup.2 denotes C.sub.1 -C.sub.24 -alkyl or C.sub.1 -C.sub.24 -fluoroalkyl andR.sup.3 denotes C.sub.8 -C.sub.24 -alkyl or C.sub.8 -C.sub.24 -fluoralkyl, with the proviso that the groups R.sup.2 and R.sup.3 contain a different number of carbon atoms. The monomers are polymerized on their own or together with other comonomers. The polymers obtained are suitable for the preparation of ultra-thin layers on a suitable layer support.

Abstract translation: 其中Y表示-O-或-NH- X的式“IMAGE”的具有混合链结构的两亲单体表示式 - （CH 2）n - 或 - （CH 2 -O-CH 2）n - 表示 0至10的整数，n表示1至10的整数，R1表示氢，甲基，氯，氰基，氟或溴，R2表示C1-C24 - 烷基或C1-C24-氟烷基，R3表示C8-C24- 烷基或C 8 -C 24 - 氟烷基，条件是基团R 2和R 3含有不同数目的碳原子。 单体自身或与其它共聚单体一起聚合。 所获得的聚合物适用于在合适的层载体上制备超薄层。

公开(公告)号：US4960635A

公开(公告)日：1990-10-02

申请号：US244930

申请日：1988-09-15

Applicant: Christian Erdelen ,  Helmut Ringsdorf ,  Werner Prass ,  Ude Scheunemann

Inventor： Christian Erdelen ,  Helmut Ringsdorf ,  Werner Prass ,  Ude Scheunemann

IPC: C08F20/22 ,  B05D1/20 ,  C08F20/00 ,  C08F20/52 ,  C08F20/54 ,  C08J5/16 ,  C08J5/18 ,  C08L33/16 ,  C10M107/38 ,  C10N50/08

CPC classification number: B05D1/202 ,  B82Y30/00 ,  B82Y40/00 ,  C08L33/16 ,  Y10T428/261 ,  Y10T428/3154

Abstract: The film consists of one or more Langmuir-Blodgett layers, the layer containing an organic polymer having long-chain fluoroalkyl side groups or consisting of this compound. The film is distinguished by a multilayer structure having few defects and is, for example, suitable for optical purposes and for surface treatment. The order of the molecules in the multilayer can be improved by annealing and by heating the film through the phase transition and cooling again.

Abstract translation: 该膜由一个或多个Langmuir-Blodgett层组成，该层包含具有长链氟烷基侧基或由该化合物组成的有机聚合物。 该薄膜通过具有很少缺陷的多层结构来区分，并且例如适用于光学目的和表面处理。 可以通过退火和通过相转变加热膜并再次冷却来改善多层中的分子的顺序。

公开(公告)号：US5517350A

公开(公告)日：1996-05-14

申请号：US366022

申请日：1994-12-29

Applicant: Ivan Cabrera ,  Uwe Falk ,  Werner Hickel ,  Donald Lupo ,  Andreas Mayer ,  Georg Pawlowski ,  Ude Scheunemann

Inventor： Ivan Cabrera ,  Uwe Falk ,  Werner Hickel ,  Donald Lupo ,  Andreas Mayer ,  Georg Pawlowski ,  Ude Scheunemann

IPC: B32B7/02 ,  C08J5/18 ,  C08L101/00 ,  G02F1/35 ,  G02F1/355 ,  G02F1/361

CPC classification number: G02F1/3618 ,  B82Y20/00 ,  G02F1/3616

Abstract: An optical component comprises an electromagnetic radiation-transparent polymeric medium having a second-order susceptibility of at least 10.sup.-9 electrostatic units where this polymeric medium comprises compounds having polar-aligned noncentrosymmetric molecular dipoles which have as structural element an electron acceptor which is bound to an electron donor via a conjugated .pi.-electron system, which makes possible an oscillation of the molecular dipole between a ground state having a first dipole moment and an electronically excited state having a second dipole moment different from the first, and the nonionic polymeric medium comprises an alternating arrangement of at least one Langmuir-Blodgett film each of at least two different nonionic polymers having nonlinear optical properties. Besides high mechanical and chemical stability the optical component of the invention has excellent nonlinear optical properties, for example frequency-doubling.

Abstract translation: 光学部件包括具有至少10-9个静电单元的二阶易感性的电磁辐射透明聚合物介质，其中该聚合物介质包含具有极性取向的非中心对称分子偶极子的化合物，其具有作为结构元件的电子受体，其结合到 通过共轭π电子系统的电子给体，其使得可能在具有第一偶极矩的基态和具有不同于第一偶极矩的第二偶极矩的电子激发态之间的分子偶极子的振荡，并且非离子聚合物介质包括 具有至少两种具有非线性光学性质的至少两种不同的非离子聚合物的至少一种Langmuir-Blodgett膜的交替排列。 除了高机械和化学稳定性外，本发明的光学部件具有优异的非线性光学性质，例如倍频。

公开(公告)号：US5358746A

公开(公告)日：1994-10-25

申请号：US127987

申请日：1993-09-27

Applicant: Martin Bruck ,  Tilo Vaahs ,  Marcellus Peuckert ,  Ude Scheunemann ,  Thomas Stehlin ,  Jurgen Theis

Inventor： Martin Bruck ,  Tilo Vaahs ,  Marcellus Peuckert ,  Ude Scheunemann ,  Thomas Stehlin ,  Jurgen Theis

IPC: C04B35/589 ,  C03C13/04 ,  C04B35/584 ,  C04B41/50 ,  C04B41/87 ,  D01F9/10 ,  D06M11/00 ,  D06M11/60 ,  D06M101/00 ,  G02B1/00 ,  B05D3/02

CPC classification number: C04B41/009 ,  C03C13/041 ,  C04B41/5035 ,  C04B41/87 ,  G02B1/00

Abstract: A process for the preparation of optical materials from silicon nitride by pyrolysis of polymeric silazanes, by pressing the pulverulent polymeric silazanes to give moldings before the pyrolysis or first dissolving the polymeric silazanes in an organic solvent, drawing fibers from this solution and pyrolyzing these fibers after evaporation of the solvent, or by melting polymeric silazanes, casting, injection-molding or extruding this melt to give moldings and subsequently pyrolyzing the moldings. An oxidic coating is produced on the silicon nitride molding in an oxygen-containing atmosphere during or after the pyrolysis. The pyrolysis can be carried out at 800.degree.-1000.degree. C. in an atmosphere containing ammonia or an ammonia/inert gas mixture.

Abstract translation: 通过热分解聚硅氮烷，通过挤压粉状聚合硅氮烷以在热解或首先将聚合硅氮烷溶解在有机溶剂中之前得到成型物，从该溶液中拉伸纤维并在这种溶液中热解这些纤维之后，将这些纤维热解后，从氮化硅制备光学材料的方法 蒸发溶剂，或通过熔融聚合硅氮烷，铸造，注射成型或挤出该熔体以得到模制品，随后热解模制品。 在热分解期间或之后，在含氧气氛中的氮化硅模制品上产生氧化涂层。 热解可以在含有氨或氨/惰性气体混合物的气氛中在800°-1000℃进行。

公开(公告)号：US5258262A

公开(公告)日：1993-11-02

申请号：US730835

申请日：1991-09-13

Applicant: Christian Erdelen ,  Helmut Ringsdorf ,  Werner Prass ,  Ude Scheunemann

Inventor： Christian Erdelen ,  Helmut Ringsdorf ,  Werner Prass ,  Ude Scheunemann

IPC: B05D1/20 ,  B05D3/06 ,  C08F12/00 ,  C08F16/02 ,  C08F16/16 ,  C08F20/32 ,  C08F20/52 ,  C08F212/08 ,  C08F216/04 ,  C08F216/16 ,  C08F220/32 ,  C08F220/58 ,  C08J5/18 ,  C08J7/00 ,  G03F7/038 ,  G03C1/76 ,  G03C1/492 ,  G03F7/095 ,  G03F7/16

CPC classification number: G03F7/038 ,  Y10S430/136 ,  Y10S430/143 ,  Y10T428/261 ,  Y10T428/3154

Abstract: Radiation-sensitive film composed of at least one monomolecular layer of fluorine-containing amphiphiles. If a vinyl monomer containing fluoroalkyl side groups is copolymerized with a vinyl monomer containing oxirane groups, an amphiphilic polymer is obtained. To prepare a sandwich, a polymer is dissolved in a volatile organic solvent which is immiscible with water, the solution is spread on the water/air boundary surface, the resultant layer is compressed after the solvent has evaporated and transferred to a solid layer support by the Langmuir-Blodgett technique. The oxirane rings are cleaved and the film crosslinked by the action of high-energy radiation on the film.

Abstract translation: PCT No.PCT / EP90 / 00069 Sec。 371日期1991年9月13日 102（e）1991年9月13日PCT PCT 1990年1月12日PCT公布。 公开号WO90 / 08346 日期：1990年7月26日。由至少一个含氟两亲物单分子层组成的辐射敏感膜。 如果含有氟烷基侧基的乙烯基单体与含有环氧乙烷基的乙烯基单体共聚，则得到两亲性聚合物。 为了制备三明治，将聚合物溶解在与水不混溶的挥发性有机溶剂中，将溶液铺展在水/空气边界表面上，在溶剂蒸发后将所得层压缩并转移到固体层载体上 Langmuir-Blodgett技术。 环氧乙烷环被切割，膜通过高能辐射的作用在膜上交联。

公开(公告)号：US5081212A

公开(公告)日：1992-01-14

申请号：US414535

申请日：1989-09-29

Applicant: Werner Prass ,  Ude Scheunemann

Inventor： Werner Prass ,  Ude Scheunemann

IPC: B05D1/20 ,  B32B27/00 ,  C08G18/32 ,  C08G18/38 ,  C08G18/73 ,  C08G18/76 ,  C08J5/18 ,  C08G18/10

CPC classification number: B05D1/202 ,  B82Y30/00 ,  B82Y40/00 ,  C08G18/324 ,  C08G18/325 ,  C08G18/3821 ,  C08G18/3825 ,  C08G18/73 ,  C08G18/7614 ,  Y10T428/31504

Abstract: A polyurea of the general formula ##STR1## where X and Y are. independently of one another, a divalent radical whose chain contains in each case at least two carbon atoms, and A and B are, independently of one another, H or (C.sub.1 -C.sub.26)alkyl, and n is an integer greater than 4, which polyurea contains at least one (C.sub.6 -C.sub.26) alkyl group per repeating unit, is prepared by reacting the diamine NHA-X-NHB with roughly the equimolar amount of a diisocyanate OCN-Y-NCO. The polyurea is suitable for preparing ordered monomolecular LB films on a base (film-substrate-system). For this purpose it is dissolved in a volatile organic solvent which is not miscible with water, the solution is spread at the water/air interface, and the layer formed is compressed after the solvent has evaporated and it is transferred to a solid layer base by the Langmuir-Blodgett technique.

Abstract translation: 其中X和Y是通式为“IMAGE”的聚脲。 彼此独立地是其链中含有至少两个碳原子的二价基团，A和B彼此独立地为H或（C 1 -C 26）烷基，n为大于4的整数，其中 聚脲含有每个重复单元至少一个（C 6 -C 26）烷基，通过使二胺NHA-X-NHB与大约等摩尔量的二异氰酸酯OCN-Y-NCO反应来制备。 聚脲适用于在基底（薄膜 - 基底 - 系统）上制备有序单分子LB薄膜。 为此，将其溶解在与水不混溶的挥发性有机溶剂中，溶液在水/空气界面处扩散，并且在溶剂蒸发后形成的层被压缩，并且通过 Langmuir-Blodgett技术。