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11.发明公开섬유상 나노탄소를 담체로 이용한 저온연료전지용 촉매,상기 촉매를 이용한 저온연료전지용 전극, 및 상기 촉매를이용한 저온연료전지 有权使用碳纳米纤维作为支撑的低温燃料电池，使用催化剂的低温燃料电池和使用催化剂的低温燃料电池的催化剂
公开(公告)号：KR1020090033288A
公开(公告)日：2009-04-02
申请号：KR1020070098491
申请日：2007-09-29
Applicant: (주)썬텔
CPC classification number: Y02P70/56 , H01M4/921 , H01M4/8647 , H01M4/926 , H01M8/1011 , H01M2008/1095 , Y02E60/521 , Y02E60/522
Abstract: A catalyst for a low temperature fuel cell is provided to maximize the efficiency while increasing the surface area of the dipped platinum catalyst, and to reduce noble metals. A catalyst for a low temperature fuel cell comprises a support and a catalyst. The support is fiber-like nano carbon of highly effective surface area, having the specific surface area measured with a nitrogen BET method of 100 m^2/g or more. The fiber-like nano carbon of highly effective surface area comprises the steps of: (i) manufacturing a transition metal alloy catalyst containing (a) iron single catalyst through oxidation reaction and reduction reaction and (b) at least one metal elected from the group consisting of nickel, cobalt, copper, and molybdenum; (ii) adding hydrogen gas to the catalyst, and performing reduction reaction to produce minute metals on the surface of the catalyst; and (iii) adding C1-4 saturated and unsaturated gas or the mixed gas consisting of carbon monoxide and hydrogen gas and heat-treating them.
Abstract translation: 提供了用于低温燃料电池的催化剂，以在提高浸渍的铂催化剂的表面积的同时使效率最大化并且还原贵金属。 用于低温燃料电池的催化剂包括载体和催化剂。 载体是具有高效表面积的纤维状纳米碳，其比表面积用氮BET法测定为100m 2 / g以上。 具有高效表面积的纤维状纳米碳包括以下步骤：（i）通过氧化反应和还原反应制备含有（a）铁单催化剂的过渡金属合金催化剂和（b）至少一种选自该组的金属 由镍，钴，铜和钼组成; （ii）向催化剂中加入氢气，进行还原反应，在催化剂表面产生微量金属; 和（iii）加入C1-4饱和和不饱和气体或由一氧化碳和氢气组成的混合气体并进行热处理。
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公开(公告)号：KR101315486B1
公开(公告)日：2013-10-07
申请号：KR1020120034186
申请日：2012-04-03
Applicant: (주)썬텔
CPC classification number: D01F9/12 , C01B32/15 , C01B32/162 , C01B32/18 , C01B2202/22
Abstract: PURPOSE: A high electrical conductive carbon nanofiber and a manufacturing method thereof are provided to increase an electrical conductivity and a contact area with an activated charcoal, and thus an electrode internal resistance and an electrical conductivity increase as well as a capacity increases. CONSTITUTION: A manufacturing method of high electrical conductive carbon nanofiber comprises following steps. A Cu/Ni catalyst is manufactured (S100). Carbon nanofiber is manufactured by using the Cu/Ni catalyst (S200). The carbon nanofiber is acid-processed (S300). The acid-processed carbon nanofiber is thermally decomposed and carbon coated (S400). The carbon coated carbon nanofiber is graphitize-processed (S500). [Reference numerals] (S100) Manufacture Cu/Ni catalyst; (S200) Manufacture carbon nanofiber; (S300) Acid-process carbon nanofiber; (S400) Thermally decompose and coat carbon; (S500) Graphitize-process
Abstract translation: 目的：提供高导电性碳纳米纤维及其制造方法，以增加导电性和与活性炭的接触面积，因此电极内阻和电导率增加以及容量增加。 构成：高导电性碳纳米纤维的制造方法包括以下步骤。 制造Cu / Ni催化剂（S100）。 使用Cu / Ni催化剂（S200）制造碳纳米纤维。 碳纳米纤维经酸处理（S300）。 将酸加工的碳纳米纤维热分解并进行碳涂布（S400）。 碳涂覆的碳纳米纤维经石墨化处理（S500）。 （附图标记）（S100）制造Cu / Ni催化剂; （S200）生产碳纳米纤维; （S300）酸工艺碳纳米纤维; （S400）热分解涂层碳; （S500）石墨化工艺
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公开(公告)号：KR101113008B1
公开(公告)日：2012-03-13
申请号：KR1020080075862
申请日：2008-08-04
Applicant: 금호석유화학 주식회사 , (주)썬텔
Abstract: 본 발명은 ⅰ) 실리콘 분말 또는 실리콘과 전이 금속, 2족, 13족, 14족, 15족 원소에서 선택된 1종 이상의 금속 합금 혼합 분말로 구성된 실리콘계 담지체 분말을 탄소공급원 존재하에 600～1100℃에서 담지체 기재 표면을 비결정성 열분해 탄소로 5～200 ㎚ 두께 및 담지체 중량 대비 3～50 중량% 표면 코팅시키는 단계; ⅱ) 열분해 탄소로 표면 코팅된 실리콘계 담지체 표면에 전이금속 촉매를 분산시키고 탄소공급원 존재 하에서 400～800℃에서 탄소나노섬유를 기상 성장시키는 단계로 제조된 최대 입경 45 ㎛ 이하인 리튬 이차전지용 실리콘계 음극 활물질 복합재를 제공한다.
실리콘, 분말, 전이 금속, 담지체, 탄소공급원, 열분해 탄소, 음극 활물질-
公开(公告)号：KR101077218B1
公开(公告)日：2011-10-27
申请号：KR1020090018343
申请日：2009-03-04
Applicant: (주)썬텔
Abstract: 본발명은에스펙트비가 30 이상이어서유효비표면적이매우넓고전극제조시전기전도도가높고연료및 공기확산그리고공기극에서발생하는물의배출이용이한플레이트리트탄소나노섬유및 그제조방법에관한것으로서, 본발명에따른플레이트리트구조탄소나노섬유제조방법은, a) 전이금속질화물수용액을환원하여아탄산전이금속미립자를제조하고, 이를건조및 산화처리하여탄소나노섬유합성촉매를제조하는단계; b) 상기탄소나노섬유합성촉매를회전식반응로에장착하고, 상기회전식반응로를회전시키면서탄소원을도입하여열분해반응에의한탄소나노섬유를합성하는단계;를포함하는것을특징으로한다.
Abstract translation: 本发明具有高的纵横比为30以上，然后在燃料和空气扩散的制造非常大的有效的电极表面积时的导电性和播放从空气电极处理碳纳米纤维利用水的排放和用于制造本方法 根据本发明的碳纳米纤维的制造方法的处理游戏结构，一）通过减少过渡金属氮化物，包含：水性溶液哦产酸的过渡金属和细小颗粒，将其干燥，并进行氧化处理用于制造碳纳米纤维合成催化剂; 其特征在于它包括一个; b）还包括：安装在旋转反应的碳纳米纤维合成催化剂，同时旋转旋转到反应合成通过引入碳源通过热分解反应所得到的碳纳米纤维。
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Patent Agency Ranking
公开(公告)号：KR1020100099819A
公开(公告)日：2010-09-15
申请号：KR1020090018343
申请日：2009-03-04
Applicant: (주)썬텔
CPC classification number: C01B32/382 , B82B1/008 , B82B3/0038 , B82Y30/00 , B82Y40/00 , C01B32/15 , D01F9/12
Abstract: PURPOSE: A platelet carbon nanofiber and a manufacturing method thereof are provided to secure the high conductivity when manufacturing an electrode, and to easily disperse fuel and air. CONSTITUTION: A platelet carbon nanofiber has the expect rate(fiber length/fiber diameter rate) of 30~50, and the interplanar distance of a carbon basal plane less than 0.34 nanometers. A manufacturing method of the platelet carbon nanofiber comprises the following steps: reducing a transition metal nitride aqueous solution to form a carbon transition metal corpuscle; drying and oxidizing the outcome to form a carbon nano fiber synthetic catalyst; settling the catalyst to a rotational reactor, and rotating the reactor while applying a carbon source to synthesize the carbon nanofiber.
Abstract translation: 目的：提供一种血小板碳纳米纤维及其制造方法，以在制造电极时确保高导电性，并且容易地分散燃料和空气。 构成：片状碳纳米纤维的预期速率（纤维长度/纤维直径率）为30〜50，碳基平面的面间距离小于0.34纳米。 所述血小板碳纳米纤维的制造方法包括以下步骤：还原过渡金属氮化物水溶液以形成碳过渡金属微粒; 干燥和氧化结果形成碳纳米纤维合成催化剂; 将催化剂沉降到旋转反应器，并在施加碳源以合成碳纳米纤维的同时旋转反应器。
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公开(公告)号：KR1020100009359A
公开(公告)日：2010-01-27
申请号：KR1020080070209
申请日：2008-07-18
Applicant: (주)썬텔
CPC classification number: H01M4/921 , B01J37/16 , H01M4/9041 , H01M4/9075 , H01M8/1004 , Y02E60/521
Abstract: PURPOSE: A catalyst for fuel cell is provided to have core-shell form and enhance the activity of fuel cell. CONSTITUTION: A catalyst for fuel cell comprises: carbon carrier, transition metal cocatalyst contained in the carbon carrier, and platinum main catalyst formed on the surface of cocatalyst. The cocatalyst is selected from Ru, Pd, Au, Ag, Ir, Os, V, Cr, Mn, Fe, Co, Ni, Cu, Ru, Ir, W, and Mo. A method for preparing the catalyst for fuel cell comprises: a step of dipping a copolymer in a carbon carrier to prepare a cocatalyst support; a step of adding platonic compound solution to the cocatalyst support; and a step of adding reductant to the solution.
Abstract translation: 目的：提供燃料电池用催化剂，具有核壳形式，增强燃料电池的活性。 构成：用于燃料电池的催化剂包括：碳载体中包含的碳载体，过渡金属助催化剂和形成在助催化剂表面上的铂主催化剂。 助催化剂选自Ru，Pd，Au，Ag，Ir，Os，V，Cr，Mn，Fe，Co，Ni，Cu，Ru，Ir，W和Mo。 ：将共聚物浸渍在碳载体中以制备助催化剂载体的步骤; 将铂族复合溶液加入助催化剂载体的步骤; 以及向溶液中加入还原剂的步骤。
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17.发明授权섬유상 나노탄소를 담체로 이용한 저온연료전지용 촉매,상기 촉매를 이용한 저온연료전지용 전극, 및 상기 촉매를이용한 저온연료전지 有权使用碳纳米纤维作为载体的低温燃料电池催化剂，使用该催化剂的低温燃料电池用电极和使用该催化剂的低温燃料电池
公开(公告)号：KR100921889B1
公开(公告)日：2009-10-13
申请号：KR1020070098491
申请日：2007-09-29
Applicant: (주)썬텔
CPC classification number: Y02P70/56
Abstract: 본 발명은 나노 로드를 기본 단위구조로 가지는 질소 BET법으로 측정한 비표면적이 100m
2 /g 이상인 고유효 표면적의 섬유상 나노탄소의 담체; 및 촉매로 이루어진 저온연료전지용 촉매, 상기 촉매를 포함하는 저온연료전지용 전극, 및 상기 촉매를 포함하는 저온연료전지를 제공한다.
본 발명의 저온연료전지는 나노 로드를 단위 구조로 가지는 섬유상 나노탄소를 담체로 사용함으로써, 백금 촉매를 담지시킬 수 있는 유효표면적을 증대시켜 담지된 백금촉매의 이용률이 상승된다. 이와 같이 제조된 촉매를 저온연료전지의 연료전지용 전극으로 사용함으로써 귀금속 백금 촉매의 사용량을 20% 이상 감소시켜도 상용촉매의 활성에 상당하거나 능가하는 높은 발전효율의 발현이 가능하므로, 촉매 제조 코스트 저하에 크게 기여할 수 있다.
나노로드, 섬유상 나노탄소, 연료전지, 백금촉매, 촉매담체-
公开(公告)号：KR100915968B1
公开(公告)日：2009-09-10
申请号：KR1020070009142
申请日：2007-01-29
Applicant: (주)썬텔
CPC classification number: Y02E60/13
Abstract: 본 발명은 탄소재료-탄소나노섬유 복합 소재를 전극 재료로 사용한 전기이중층 캐패시터에 관한 것으로서, 탄소재료의 표면에 탄소나노섬유를 성장시킨 탄소재료-탄소나노섬유 복합 소재를 전극 재료로 사용함으로써 종래 소재와 유사한 체적 용량 및 전극밀도를 유지하면서 전극의 부피팽창율을 대폭 감소시킨 전기이중층 캐패시터를 제공한다.
복합소재, 탄소나노섬유, 가스화, 전극팽창율, 전극밀도-
公开(公告)号：KR1020080071038A
公开(公告)日：2008-08-01
申请号：KR1020070009142
申请日：2007-01-29
Applicant: (주)썬텔
Abstract: An electric double-layer capacitor using a carbon-based material-carbon nano fiber composite as an electrode is provided to increase a capacity per a volume by restricting a volume expansion rate of the electrode while maintaining a similar capacity and electrode density in charging or discharging. An electric double-layer capacitor uses the carbon-based material-carbon nano fiber composite having changed specific surface area, and diameter and volume of a pore by improving a surface of a carbon nano fiber by growing the carbon nano fiber on a surface of a carbon material. The carbon material has a micro pore of 80% or more having a specific surface area of 100 to 1000 m^2/g and a diameter of 2 nm.
Abstract translation: 提供一种使用碳基材料 - 碳纳米纤维复合材料作为电极的电双层电容器，通过限制电极的体积膨胀率，同时保持充电或放电中的类似容量和电极密度来增加每个体积的容量 。 电双层电容器使用通过在碳纳米纤维的表面上生长碳纳米纤维来改善碳纳米纤维的表面而改变比表面积的碳基材料 - 碳纳米纤维复合材料，以及孔的直径和体积 碳材料。 碳材料具有80％以上的微孔，比表面积为100〜1000m 2 / g，直径为2nm。
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