公开(公告)号：KR1020120004853A

公开(公告)日：2012-01-13

申请号：KR1020100065551

申请日：2010-07-07

Applicant: 국방과학연구소

Inventor： 박병열 ,  류문삼 ,  김창기

IPC: C09J5/00 ,  B32B37/00 ,  B32B37/14 ,  C09J163/00

CPC classification number: B32B7/10 ,  B32B25/10 ,  B32B25/14 ,  B32B27/12 ,  B32B27/38 ,  B32B2037/0092 ,  B32B2038/0076 ,  B32B2260/021 ,  B32B2260/042 ,  B32B2262/106 ,  B32B2270/00 ,  B32B2307/306 ,  B32B2307/50 ,  B32B2319/00 ,  B32B2363/00

Abstract: PURPOSE: A method for improving adhesion between a rubber and an epoxy resin-containing composite is provided to be hardened at the same time at high temperature through an epoxy chemical reaction between the composite and latent epoxy resin in the rubber without separate adhesive layer, thereby improving adhesion between the rubber and the composite. CONSTITUTION: A method for improving adhesion between a rubber and an epoxy resin-containing composite comprises a step of laminating the mixture of the rubber and the epoxy resin-containing composite and hardening the same at the same time. The rubber is mixed by 3.0-5.0wt% epoxy resin on the basis of total weight of the rubber and the epoxy resin. The rubber is an ethylene propylene diene rubber or ethylene propylene. The epoxy resin is aromatic amine hardening agent epoxy resin. The composite comprises a carbon fiber.

Abstract translation: 目的：提高橡胶与含环氧树脂的复合体之间的粘合力的方法，通过橡胶中的复合和潜在环氧树脂之间的环氧化学反应在高温下同时硬化，而不需要单独的粘合剂层，由此 改善橡胶和复合材料之间的粘合性。 构成：改善橡胶与含环氧树脂的复合材料之间的粘合力的方法包括将橡胶和含环氧树脂的复合材料的混合物层压并同时硬化的步骤。 基于橡胶和环氧树脂的总重量，橡胶以3.0-5.0重量％的环氧树脂混合。 橡胶是乙烯丙烯二烯橡胶或乙烯丙烯。 环氧树脂是芳香族胺硬化剂环氧树脂。 复合材料包括碳纤维。

公开(公告)号：KR1020080019396A

公开(公告)日：2008-03-04

申请号：KR1020060081681

申请日：2006-08-28

Applicant: 국방과학연구소

Inventor： 윤진산 ,  정성훈 ,  심재훈 ,  김응수 ,  류문삼

IPC: C04B33/04 ,  C04B24/16 ,  B82Y30/00

Abstract: A clay compound modified with a tetra sulfide group, a rubber/clay nanocomposite containing the same, and methods for preparing them are provided to show excellent mechanical properties including tensile strength, elongation at break, tear strength and heat stability while maintaining flexibility. A clay compound is modified with a tetra sulfide group and particularly, is prepared by a method comprising the steps of: admixing a silane compound containing a tetra sulfide group to a water-soluble solvent and hydrating the admixture with an appropriate acid; and admixing clay to the resulting hydrated silane compound solution, followed by stirring. A rubber/clay nanocomposite contains the clay compound modified with the tetra sulfide group, and particularly, is prepared by a method comprising the steps of: mixing the clay compound modified with the tetra sulfide group, a rubber and a cross-linking agent, followed by stirring; and drying the resulting solution, and then heating the solution under a pressure to be cured. Further, the rubber is a silicon rubber which is poly dimethyl siloxane.

Abstract translation: 提供用四硫化物基团改性的粘土化合物，含有它们的橡胶/粘土纳米复合材料及其制备方法，以显示出优异的机械性能，包括拉伸强度，断裂伸长率，撕裂强度和热稳定性，同时保持柔韧性。 粘土化合物用四硫化物基团改性，特别是通过包括以下步骤的方法制备：将含有四硫化物基团的硅烷化合物与水溶性溶剂混合并将该混合物与合适的酸水合; 并将粘土与所得水合硅烷化合物溶液混合，然后搅拌。 橡胶/粘土纳米复合材料包含用四硫化物基团改性的粘土化合物，特别是通过包括以下步骤的方法制备：将经四硫化物改性的粘土化合物，橡胶和交联剂混合，然后 通过搅拌; 并干燥所得溶液，然后在待固化的压力下加热溶液。 此外，橡胶是聚二甲基硅氧烷的硅橡胶。