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公开(公告)号：KR1020100132275A
公开(公告)日：2010-12-17
申请号：KR1020090051012
申请日：2009-06-09
Applicant: 성균관대학교산학협력단
Inventor： 한귀영
IPC: C01B3/58
CPC classification number: C01B3/26 , B01D53/047 , B01D2253/102 , B01D2256/16 , C01B3/508 , C01B2203/1041 , C01B2203/1628
Abstract: PURPOSE: A high purity hydrogen producing apparatus using the catalytic decomposition of petroleum waste gas, and a method thereof are provided to use the petroleum waste gas as a reaction raw material. CONSTITUTION: A high purity hydrogen producing apparatus using the catalytic decomposition of petroleum waste gas comprises a fluid bed reactor(10), and a pressure swing absorption top(60). The fluid bed reactor successively decomposes the petroleum waste gas into hydrogen and carbon. The fluid bed reactor includes a discharging pipe for discharging the carbon.
Abstract translation: 目的：提供使用石油废气的催化分解的高纯度氢制造装置及其方法，以石油废气为反应原料。 构成：使用石油废气的催化分解的高纯度氢气生产装置包括流化床反应器（10）和压力摆动吸收顶部（60）。 流化床反应器依次将石油废气分解成氢气和碳。 流化床反应器包括用于排出碳的排出管。
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公开(公告)号：KR1020170089253A
公开(公告)日：2017-08-03
申请号：KR1020160009428
申请日：2016-01-26
Applicant: 성균관대학교산학협력단
Abstract: 분해가스오일(pyrolysis gas oil, PGO)을반응기내 카본블랙촉매상에서열분해반응시켜수소및 메탄가스를생성하는공정을제공한다.
Abstract translation: 热解瓦斯油（PGO）在反应器中的炭黑催化剂上经受热分解反应以产生氢气和甲烷气体。
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公开(公告)号：KR101761829B1
公开(公告)日：2017-07-26
申请号：KR1020150063829
申请日：2015-05-07
Applicant: 성균관대학교산학협력단
IPC: C10K1/00
Abstract: 합성가스및 일산화탄소의제조방법에관한것이다.
Abstract translation: 合成气和生产一氧化碳的方法。
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公开(公告)号：KR101465208B1
公开(公告)日：2014-11-26
申请号：KR1020130103287
申请日：2013-08-29
Applicant: 성균관대학교산학협력단
Abstract: 본원은, 합성가스 및 수소의 제조 방법을 제공한다.
Abstract translation: 本发明提供一种合成气体和氢气的制造方法。 制造合成气体和氢气的方法包括以下步骤：将甲烷气体提供到具有多孔陶瓷载体的反应器中，所述多孔陶瓷载体涂覆有合成的金属氧化物以制造合成气体; 并停止供应甲烷气体并向反应器中提供蒸气以制造氢气。 合成气体和氢气可以在低温下制造，二氧化碳不会排出。
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公开(公告)号：KR101419856B1
公开(公告)日：2014-07-17
申请号：KR1020140037924
申请日：2014-03-31
Applicant: 성균관대학교산학협력단
Abstract: 본원은 카본 블랙을 이용한 탄화수소의 촉매분해반응에 의한 이산화탄소 배출 없이 수소를 연속적으로 생산하는 방법 및 장치에 있어서, 탄화수소의 촉매분해반응 결과로 생성된 카본 블랙을 특정 크기로 물리적 분쇄하여 촉매로서 재사용하는 것을 특징으로 하는 방법 및 장치에 관한 것이다.
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Patent Agency Ranking
公开(公告)号：KR101302192B1
公开(公告)日：2013-08-30
申请号：KR1020110016887
申请日：2011-02-25
Applicant: 성균관대학교산학협력단
Abstract: 본원은 온실 가스인 이산화탄소를 배출하지 않고 낮은 온도에서 반응을 수행하기 위하여, 세리아(CeO
2 ) 또는 세리아를 함유하는 산화물 촉매가 코팅된 다공질 지지체를 이용하여 메탄의 직접분해로 합성가스를 생성하고, 상기 합성가스의 생성 반응 중 환원된 세리아에 수증기를 공급하여 수소를 수득하는 방법 및 장치를 제공한다.-
公开(公告)号：KR1020130027219A
公开(公告)日：2013-03-15
申请号：KR1020110090676
申请日：2011-09-07
Applicant: 성균관대학교산학협력단
CPC classification number: Y02P20/52 , C01B3/40 , B01J35/1076 , C01B2203/0838 , C01B2203/1017 , C01B2203/1058 , C01B2203/1076 , C01B2203/1241
Abstract: PURPOSE: A synthetic gas and hydrogen manufacturing method and a manufacturing apparatus are provided to improve the reaction rate of the synthetic gas and hydrogen manufacturing reaction as by preventing the emission of carbon dioxide which is greenhouse gas, and by including a multi-pored metal supporting body in a reactor. CONSTITUTION: A synthetic gas and hydrogen manufacturing method includes following steps: a step which heats a reactor loaded with a multi-pored metal support coated with CeO2/ZrO2 which is a metal oxide; a step which produces synthetic gas by supplying methane gas into the reactor; and a step which produces hydrogen by supplying vapor into the reactor after stopping the supply of the methane gas. A metal of the multi-pored metal support is selected from nickel(Ni), copper(Cu), or combination thereof. The difference between the surface temperature of the multi-pored metal support and the inner temperature is less than 50 deg. C. The size of pores in the multi-pored metal support is ranged from 100 micrometers to 3 millimeters. [Reference numerals] (AA) Porous metal support(Ni foam); (B1) Diameter:30mm, thickness:7mm; (B2) Pore size:1mm-2mm; (CC) Soaking the porous metal support with distilled water; (DD) Uniformly dispersing CeO_2/ZrO_2 into the porous metal support using Mesh; (EE) Soaking the dispersed CeO_2/ZrO_2 with distilled water; (FF) Drying with a Heating gun; (GG) CeO_2/ZrO_2/Ni foam(porous metal support); (HH) Repeating
Abstract translation: 目的：提供合成气和氢制造方法和制造装置，以通过防止作为温室气体的二氧化碳的排放来提高合成气体和氢气制造反应的反应速率，并且通过包括多孔金属支撑 身体在反应堆。 构成：合成气和氢制造方法包括以下步骤：加热装载有作为金属氧化物的CeO 2 / ZrO 2的多孔金属载体的反应器的步骤; 通过将甲烷气体供应到反应器中而产生合成气体的步骤; 以及在停止供应甲烷气体之后通过向反应器中供应蒸汽来产生氢气的步骤。 多孔金属载体的金属选自镍（Ni），铜（Cu）或其组合。 多孔金属载体的表面温度与内部温度之间的差值小于50度。 多孔金属载体中的孔的大小范围为100微米至3毫米。 （标号）（AA）多孔金属载体（Ni泡沫）; （B1）直径：30mm，厚度：7mm; （B2）孔径：1mm-2mm; （CC）用蒸馏水浸泡多孔金属载体; （DD）使用Mesh将CeO_2 / ZrO_2均匀分散在多孔金属载体中; （EE）用蒸馏水浸泡分散的CeO_2 / ZrO_2; （FF）用加热枪干燥; （GG）CeO_2 / ZrO_2 / Ni泡沫（多孔金属载体）; （HH）重复
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19.发明公开지르코니아 나노튜브 및 그의 제조 방법, 및 상기 지르코니아 나노튜브를 이용하여 열화학적 물 분해를 통한 수소의 제조 방법 无效ZIRCONIA NANOTUBE，其制备方法和使用该化合物的热化学水分解氢气的制备方法
公开(公告)号：KR1020130001042A
公开(公告)日：2013-01-03
申请号：KR1020110061916
申请日：2011-06-24
Applicant: 성균관대학교산학협력단
CPC classification number: Y02E60/36 , C01G25/02 , B01J21/066 , B01J23/755 , C01B3/042 , C01P2004/13
Abstract: PURPOSE: A zirconia nanotube, a manufacturing method thereof, and a manufacturing method of hydrogen through thermochemical water splitting are provided to form zirconia nanotubes through an anodization process in a short period of time. CONSTITUTION: A manufacturing method of a zirconia nanotube comprises the following step: forming zirconia nanotubes through anodization within a halogen-containing electrolyte. The zirconia nanotube is formed into a powdered form. The concentration of the halogen-containing electrolyte is 0.05-0.5 M. The applied electric potential in the anodization is 2-100 V. The anodization is performed for 0.001-120 minutes. The length of the zirconia nanotube is in micrometer units. A manufacturing method of the hydrogen through thermochemical hydrolysis comprises the following step: producing hydrogen by hydrolysis through a thermochemical cycle.
Abstract translation: 目的：提供氧化锆纳米管及其制造方法以及通过热化学水分解的氢气的制造方法，以通过阳极氧化处理在短时间内形成氧化锆纳米管。 构成：氧化锆纳米管的制造方法包括以下步骤：通过在含卤素电解质中的阳极氧化形成氧化锆纳米管。 氧化锆纳米管形成粉末状。 含卤素电解质的浓度为0.05-0.5M。阳极氧化时施加的电位为2-100V。阳极氧化进行0.001-120分钟。 氧化锆纳米管的长度为微米单位。 通过热化学水解的氢气的制造方法包括以下步骤：通过热化学循环的水解产生氢。
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公开(公告)号：KR1020120095606A
公开(公告)日：2012-08-29
申请号：KR1020110015029
申请日：2011-02-21
Applicant: 성균관대학교산학협력단
CPC classification number: C09C1/48 , B01J8/1818 , C01B3/26
Abstract: PURPOSE: A method for manufacturing hydrogen and carbon black from waste lubricating oil is provided to prevent environmental pollution by preventing the generation of byproducts such as carbon dioxide during a waste lubricating oil decomposing process. CONSTITUTION: A method for manufacturing hydrogen and carbon black from waste lubricating oil includes the following: waste lubricating oil is vaporized; the vaporized lubricating oil and inert gas are supplied into a fluidized bed reactor(10) with a carbon black catalyst; the vaporized waste lubricating oil is catalytic decomposed; carbon black is obtained and is discharged through a discharging pipe equipped at the fluidized bed reactor; a gas mixture containing hydrogen, non-reacted waste lubricating oil, and entrained carbon is collected with a cyclone(50) equipped at the outlet of the fluidized bed reactor; the entrained carbon is separated from the collected gas mixture; the mixture of the hydrogen and the non-reacted waste lubricating oil is transferred to a pressure converting absorbing column(60); and hydrogen is separated from the mixture.
Abstract translation: 目的：提供从废润滑油制造氢和炭黑的方法，以防止在废润滑油分解过程中产生二氧化碳等副产物而导致环境污染。 构成：从废润滑油制造氢和炭黑的方法包括：废润滑油蒸发; 汽化的润滑油和惰性气体用炭黑催化剂供入流化床反应器（10）中; 蒸发的废润滑油被催化分解; 得到炭黑，并通过设置在流化床反应器的排出管排出; 含有氢气，未反应的废润滑油和夹带的碳的气体混合物用设置在流化床反应器出口处的旋风分离器（50）收集; 夹带的碳与收集的气体混合物分离; 将氢和未反应的废润滑油的混合物转移到压力转化吸收塔（60）中; 并从混合物中分离氢。
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