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公开(公告)号：KR1020100073672A
公开(公告)日：2010-07-01
申请号：KR1020080132400
申请日：2008-12-23
Applicant: 제일모직주식회사
IPC: C08L69/00 , C08K3/10 , C08L101/00
CPC classification number: C08G59/688 , C08G59/62 , C08K3/32 , C08K3/38 , C08K5/09 , C08L25/02 , C08L69/00 , C08L2666/04
Abstract: PURPOSE: A branched polycarbonate resin composition is provided to be applied to various molded products including auto parts, a computer housing, and other office supplies due to excellent impact strength, heat resistance, mechanical strength, and workability. CONSTITUTION: A branched polycarbonate resin composition comprises: 80-99 weight% of a polycarbonate resin; 0.5-20 weight% of a polymer having a reactive group and carbon-carbon double bond; and 0.0001-0.8 weight% of an ionic compound including an ion which is selected from an alkali metal ion and an organic cation. The average molecular weight of the polycarbonate resin is 10,000-200,000 g/mol.
Abstract translation: 目的：提供一种支化聚碳酸酯树脂组合物，其由于优异的冲击强度，耐热性，机械强度和可加工性而适用于包括汽车部件，计算机外壳和其它办公用品在内的各种模塑产品。 构成：支化聚碳酸酯树脂组合物包含：80-99重量％的聚碳酸酯树脂; 0.5-20重量％的具有反应性基团和碳 - 碳双键的聚合物; 和0.0001-0.8重量％的包含选自碱金属离子和有机阳离子的离子的离子化合物。 聚碳酸酯树脂的平均分子量为10,000-200,000g / mol。
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公开(公告)号：KR101469268B1
公开(公告)日：2014-12-05
申请号：KR1020110145267
申请日：2011-12-28
Applicant: 제일모직주식회사
IPC: C08F236/10 , C08F2/60 , C08F4/48 , C08L53/02
Abstract: 본발명의공액디엔으로부터열가소성수지를연속적으로제조하는방법은공액디엔계단량체와방향족비닐계단량체를유기금속계촉매및 제1 용매존재하에서제1 반응기에서 1차중합하여고무용액을제조하며; 상기고무용액에방향족비닐계단량체및 이와공중합가능한단량체를투입하여제2 용매존재하에서제2 반응기에서 2차중합하는단계를포함하고, 상기제1용매와제2용매는동일하며, 각단계별이종(異種)의중합개시제를사용하여단계적으로중합하는것을특징으로한다. 상기방법은스팀과물을사용한탈거공정및 수세, 응집공정후 제품제조를위한베일형성과정이없기때문에에너지및 CO가절감되어친환경적이며, 이로부터제조된열가소성수지는저광택성을갖는다.
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公开(公告)号：KR100862243B1
公开(公告)日：2008-10-09
申请号：KR1020070137410
申请日：2007-12-26
Applicant: 제일모직주식회사
Abstract: A method for preparing a branched polycarbonate resin is provided to allow effective control of the molecular structure, molecular weight and terminal hydroxyl group content of a branched polycarbonate resin, and to inhibit gelling. A method for preparing a branched polycarbonate resin comprises the steps of: carrying out transesterification of an aromatic dihydroxyl compound and diallyl carbonate to form a linear polycarbonate prepolymer; removing the excessive amount of diallyl carbonate and reaction byproducts from the linear polycarbonate prepolymer; and introducing a branching agent to the linear polycarbonate prepolymer from which diallyl carbonate and byproducts are removed and carrying out a reaction.
Abstract translation: 提供一种制备支化聚碳酸酯树脂的方法，以有效控制支化聚碳酸酯树脂的分子结构，分子量和末端羟基含量，并抑制胶凝。 制备支化聚碳酸酯树脂的方法包括以下步骤：进行芳族二羟基化合物和碳酸二烯丙酯的酯交换以形成线性聚碳酸酯预聚物; 从线性聚碳酸酯预聚物中除去过量的碳酸二烯丙酯和反应副产物; 并将支化剂引入到直链聚碳酸酯预聚物中，从其中除去二烯丙基碳酸酯和副产物并进行反应。
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