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11.
公开(公告)号:KR101469261B1
公开(公告)日:2014-12-08
申请号:KR1020110138668
申请日:2011-12-20
Applicant: 제일모직주식회사
IPC: C08F220/10 , C08L33/04 , C08F2/38 , C08J5/00
CPC classification number: C08F22/10 , C08F220/18 , C08L33/10 , C08F220/14 , C08F2220/1883
Abstract: 본발명은 (A) 굴절률이 1.580~1.700 인방향족 (메타)아크릴레이트; 및 (B) 단관능성불포화단량체를포함하는단량체로부터유도된단위를함유하는열가소성 (메타)아크릴레이트공중합체에관한것이다.
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公开(公告)号:KR101315098B1
公开(公告)日:2013-10-07
申请号:KR1020100095918
申请日:2010-10-01
Applicant: 제일모직주식회사
Abstract: 본 발명은 (A) 초고분자량 분지형 아크릴계 공중합체 수지 1 내지 100 중량부; (B) 아크릴계 수지 0 내지 99 중량부; 및 (A)+(B)로 이루어지는 기초수지 100 중량부에 대하여 (C) 아크릴계 충격보강제 0 내지 40 중량부를 포함하고, 상기 초고분자량 분지형 아크릴계 공중합체 수지 (A)가 (a1) 단관능성 아크릴 단량체 50 내지 99.899 중량%, (a2) 하기 화학식 1의 구조로 표시되는 유연구조(Flexible segment)를 가지는 (메타)아크릴계 단량체 0.1 내지 40 중량% 및 (a3) 분지구조 형성 단량체 0.001 내지 10 중량%를 포함하는 단량체 혼합물의 중합체 또는 이들 중합체의 혼합물인 것을 특징으로 하는 투명 열가소성 수지 조성물을 제공한다. 본 발명에 따른 투명 열가소성 수지 조성물은 우수한 투명성, 내스크래치성 및 충격강도 외에 우수한 유동성을 보일 수 있다.
상기 식에서, m은 3~18의 정수이며, X 및 Y는, 각각 독립적으로, 메틸기 또는 탄화수소기이다.-
公开(公告)号:KR1020120031532A
公开(公告)日:2012-04-04
申请号:KR1020100072920
申请日:2010-07-28
Applicant: 제일모직주식회사
CPC classification number: C08F230/02 , C08F220/14 , C08F220/18 , C08L33/04 , C08L33/062 , C08L33/12 , C08L33/14 , C08L43/02 , C08L51/00
Abstract: PURPOSE: A transparent thermoplastic resin composition is provided to have excellent flame retardancy, thermal resistance, physical properties and flowability, while maintaining inherent excellent transparency and scratch resistance characteristics. CONSTITUTION: A transparent thermoplastic resin composition comprises a phosphorous-based acrylic copolymer resin as a base resin. The copolymer resin comprises one or more of the acrylic monomers in chemical formula 1, and one or more of the phosphorus acrylic monomers in chemical formula 2. In the chemical formulas, R1 is -H or -CH3, R2 is -(CH2)n-CH3, n is an integer from 0-18, R3 is the functional group of chemical formula 2-a, t is an integer from 0-10, R4 and R5 are -O-(CH2)m-CH3, at least one of R4 and/or R5 is -O-CH3, and m is an integer from 0-5.
Abstract translation: 目的:提供透明的热塑性树脂组合物以具有优异的阻燃性,耐热性,物理性能和流动性,同时保持固有的优异的透明性和耐划伤性。 构成:透明热塑性树脂组合物包括作为基础树脂的磷基丙烯酸共聚物树脂。 共聚物树脂包含化学式1中的一种或多种丙烯酸单体和化学式2中的一种或多种磷丙烯酸类单体。在化学式中,R 1为-H或-CH 3,R 2为 - (CH 2)n -CH 3,n是0-18的整数,R3是化学式2-a的官能团,t是0-10的整数,R4和R5是-O-(CH2)m-CH3,至少一个 的R 4和/或R 5为-O-CH 3,m为0-5的整数。
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公开(公告)号:KR1020140074087A
公开(公告)日:2014-06-17
申请号:KR1020120142297
申请日:2012-12-07
Applicant: 제일모직주식회사
Abstract: The present invention relates to a thermoplastic resin comprising: a polycarbonate resin; and a resin including a phosphorous heterocyclic group. An embodiment of the present invention comprises: (A) a polycarbonate resin; and (B) a (meth)acrylic copolymer including a phosphorous heterocyclic group. The (meth)acrylic copolymer (B) comprises: (b1) a phosphorous (meth)acrylic monomer including a phosphorous heterocyclic group; (b2) a (meth)acrylic monomer containing a biphenyl group having a refractive index of 1.580 to 1.700; and (b3) a unit derived from a monomer including an unsaturated monomer. The thermoplastic resin has excellent flame retardancy and transparency and has heat resistance, scratch resistance, and eco-friendliness.
Abstract translation: 本发明涉及热塑性树脂,其包含:聚碳酸酯树脂; 以及包含磷杂环基的树脂。 本发明的实施方案包括:(A)聚碳酸酯树脂; 和(B)包含磷杂环基的(甲基)丙烯酸共聚物。 (甲基)丙烯酸共聚物(B)包括:(b1)包含磷杂环基的磷(甲基)丙烯酸单体; (b2)含有折射率为1.580〜1.700的联苯基的(甲基)丙烯酸系单体; 和(b3)衍生自包含不饱和单体的单体的单元。 热塑性树脂具有优异的阻燃性和透明性,并且具有耐热性,耐刮擦性和环保性。
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公开(公告)号:KR101374360B1
公开(公告)日:2014-03-18
申请号:KR1020100127795
申请日:2010-12-14
Applicant: 제일모직주식회사
CPC classification number: C08L69/00 , C08J5/00 , C08J2369/00 , C08L33/14 , C08L2201/02 , C08F220/14 , C08F2220/1825 , C08F230/02 , C08L33/08
Abstract: 본 발명은 특정 (메타)아크릴계 난연 공중합체를 포함시켜, 난연성과 내스크래치성을 높이고 환경 친화적인 난연 내스크래치성 폴리카보네이트 수지 조성물에 관한 것이다.
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公开(公告)号:KR101293787B1
公开(公告)日:2013-08-06
申请号:KR1020100072920
申请日:2010-07-28
Applicant: 제일모직주식회사
CPC classification number: C08F230/02 , C08F220/14 , C08F220/18 , C08L33/04 , C08L33/062 , C08L33/12 , C08L33/14 , C08L43/02 , C08L51/00
Abstract: 내열성이 우수한 하기 화학식 2의 인계 (메타)아크릴계 모노머를 단위체로 포함하여 이루어지는 인계 아크릴 공중합체를 포함하는 수지 조성물이 제공된다. 본 발명의 수지 조성물은 기존의 우수한 투명성, 내스크래치성과 함께 우수한난연성, 내열성,기계적 물성 및 유동 특성을 보인다.
[화학식 2]
상기 식에서 R
1 은 -H 또는 -CH
3 이고,
R
3 는 이며, t는 0~10 사이의 정수이고,
R
4 및 R
5 는 -O-(CH
2 )
m -CH
3 (단, m은 0~5 사이의 정수)이되, R
4 및 R
5 중 적어도 어느 하나는 -O-CH
3 이다.-
公开(公告)号:KR1020130070413A
公开(公告)日:2013-06-27
申请号:KR1020110137733
申请日:2011-12-19
Applicant: 제일모직주식회사
IPC: C08F220/10 , C08F230/02 , C08L33/04 , C08L69/00
CPC classification number: C08F220/18 , C08F220/14 , C08F230/02 , C08L33/08 , C08L33/18 , C08L69/00 , C08L2201/02 , C08F212/08 , C08F220/44
Abstract: PURPOSE: A environment-friendly flame-retarding acrylic copolymer is provided to have high refractive index and an excellent flame resistant, to minimize the problem of transparency and reduced coloring property when the copolymer is used being mixed with highly refractive resin, and to have an excellent scratch resistance. CONSTITUTION: A environment-friendly flame-retarding acrylic copolymer contains (A) (meth)acrylic monomer; (B) one or more of vinyl monomer aromatic selected from an aromatic vinyl monomer and an unsaturated nitrile monomer; and (C) a unit induced from the (meth)acrylic monomer in phosphoric marked with a chemical formula 1. In a chemical formula 1, R1 is hydrogen or a methyl group and n is a whole number ranged 0-10. R2 and R3 are independently -O(CH2)qX and q is a whole number ranged 0-3. X is selected from a methyl group, a cyclohexyl grou, a phenyl group, a methylphenyl group, a methyl-ethyl-phenyl group, a propylphenyl group, a methoxyphenyl group, a cyclohexylphenyl group, a chlorophenyl group, a bronmophenyl group, a phenyl-phenyl group, and a benzylphenyl group.
Abstract translation: 目的:提供环境友好的阻燃丙烯酸共聚物以具有高折射率和优异的阻燃性,以使当共聚物与高折射率树脂混合时使透明度和着色性能降低,并且具有 优异的耐刮擦性。 构成:环保型阻燃丙烯酸共聚物含有(A)(甲基)丙烯酸单体; (B)一种或多种选自芳族乙烯基单体和不饱和腈单体的乙烯基单体芳族化合物; 和(C)由化学式1标记的磷酸酯中的(甲基)丙烯酸单体引发的单元。在化学式1中,R 1是氢或甲基,n是整数0-10。 R2和R3独立地是-O(CH2)qX,q是0-3的整数。 X选自甲基,环己基烷基,苯基,甲基苯基,甲基 - 乙基 - 苯基,丙基苯基,甲氧基苯基,环己基苯基,氯苯基,支链苯基,苯基 苯基和苄基苯基。
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公开(公告)号:KR101268881B1
公开(公告)日:2013-05-29
申请号:KR1020100095952
申请日:2010-10-01
Applicant: 제일모직주식회사
Abstract: 본발명의폴리카보네이트계수지조성물은폴리카보네이트수지에초고분자량분지구조아크릴계공중합체를도입하여충격강도및 내스크래치성이우수한열가소성수지조성물이다. 본발명의폴리카보네이트계수지조성물은우수한내스크래치성및 충격강도외에별도의상용화제없이상용성이개선되어우수한투명성및 외관을보이면서우수한유동성을보이는것을특징으로한다.
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公开(公告)号:KR1020120049963A
公开(公告)日:2012-05-18
申请号:KR1020100109988
申请日:2010-11-05
Applicant: 제일모직주식회사
CPC classification number: C08L69/00 , C08F220/14 , C08K5/521 , C08L33/06 , C08L33/10 , C08L43/02 , C08L51/04 , C08F2220/301 , C08F230/02 , C08F2220/1841
Abstract: PURPOSE: A polycarbonate resin composition having specific flame-retardant (meth)acrylic copolymer is provided to enhance mechanical property which includes flame-retardant. CONSTITUTION: A polycarbonate resin composition having specific flame-retardant (meth)acrylic copolymer comprises polycarbonate resin, (meth)acryl group flame resisting copolymers, and (meth)acrylic copolymer having a refractive index of 1.495-1.590. The (meth)acryl group flame resisting copolymers comprises phosphorous-based acrylic monomer which is represented by chemical formula 1, aromatic family or cycloaliphatic (meth)acrylate which is represented by following chemical formula 2 or 3, and reactive unsaturated monomers. The (meth)acryl group flame resisting copolymers has an average molecular weight of 5,000-150,000 g/mol.
Abstract translation: 目的:提供具有特定阻燃(甲基)丙烯酸共聚物的聚碳酸酯树脂组合物,以增强包括阻燃性的机械性能。 构成:具有特定阻燃(甲基)丙烯酸共聚物的聚碳酸酯树脂组合物包含聚碳酸酯树脂,(甲基)丙烯酸类阻燃共聚物和折射率为1.495-1.590的(甲基)丙烯酸共聚物。 (甲基)丙烯酰基的阻燃共聚物包括由化学式1表示的磷基丙烯酸类单体,由以下化学式2或3表示的芳香族或脂环族(甲基)丙烯酸酯和反应性不饱和单体。 (甲基)丙烯酰基的阻燃性共聚物的平均分子量为5,000〜150,000g / mol。
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公开(公告)号:KR1020120048384A
公开(公告)日:2012-05-15
申请号:KR1020100109991
申请日:2010-11-05
Applicant: 제일모직주식회사
CPC classification number: C09K21/14 , C08F220/14 , C08F2220/301 , C08F230/02 , C08F2220/185 , C08F2220/1841
Abstract: PURPOSE: An environmentally-friendly flame resistant acrylic copolymer including specific phosphorous-based acrylic monomer and a manufacturing method thereof are provided to minimize degradation of transparency and coloring property. CONSTITUTION: An environmentally-friendly flame resistant acrylic copolymer including specific phosphorous-based acrylic monomer has refractive index of 1.490-1.590. The phosphorous-based acrylic monomer is represented by chemical formula 1. In the chemical formula 1, R1 indicates -H or -(CH2)n-CH3, n indicates integers between 0-5, R3 indicates -(CH2)t-P(O)R4R5. Here, t indicates integers between 1-10, R4 and R5 respectively indicate -O(CH2)qX. Q indicates integers between 0-3, Q indicates a fixed number of 0-3. X can be selected from methyl, cyclohexyl, phenyl, methyl phenyl group, (methylethyl)phenyl, propyl phenyl radical, methoxy phenyl radical, cyclohexyl phenyl radical, chlorophenyl, bromo phenyl radical, phenyl phenyl group, and benzyl phenyl radical.
Abstract translation: 目的:提供一种包含特定的磷基丙烯酸类单体的环保型阻燃丙烯酸共聚物及其制造方法,以使透明性和着色性降低。 构成:包含特定磷基丙烯酸单体的环保型阻燃丙烯酸共聚物的折射率为1.490-1.590。 在化学式1中,R1表示-H或 - (CH2)n-CH3,n表示0-5之间的整数,R3表示 - (CH2)tP(O) R4R5。 这里,t表示1-10之间的整数,R4和R5分别表示-O(CH2)qX。 Q表示0-3之间的整数,Q表示0-3的固定数。 X可选自甲基,环己基,苯基,甲基苯基,(甲基乙基)苯基,丙基苯基,甲氧基苯基,环己基苯基,氯苯基,溴苯基,苯基苯基和苄基苯基。
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