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公开(公告)号：KR100024634B1
公开(公告)日：1987-12-08
申请号：KR1019850001210
申请日：1985-02-27
Applicant: 한국과학기술연구원
IPC: C09J103/06
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公开(公告)号：KR1020040014687A
公开(公告)日：2004-02-18
申请号：KR1020020047298
申请日：2002-08-10
CPC classification number: B82Y30/00 , C08K3/08 , C08K3/22 , C08K2003/0806 , C08K2003/0831 , C08K2201/011
Abstract: PURPOSE: Provided are nano-sized metals or metal salts thereof stabilized by semi-telechelic or telechelic polymers obtained by living anionic polymerization, which has excellent stability in air and forms a nano-structure by simply mixing with a block copolymer. CONSTITUTION: The nano-sized metal particles or metal salts thereof present in a polymer matrix having a functional group at the end of the polymer chain and a molecular weight of 1000-10000, is stable in air, and is represented by the formula selected from the group consisting of the following formulae 1-5, wherein each of R1 and R2 is H, methyl or t-butyl; each of X1 and X2 is independently a carboxyl, hydroxyl, sulfonate, anhydride or thiol group; n is an integer of 10-5000; each of R3 and R4 is H or methyl; each of X2 and X3 is independently a hydroxyl, carboxyl, sulfonate, thiol, amine, tertiary amine or anhydride group; m is an integer of 20-10000; X4 is a hydroxyl, amine or tertiary amine group; Y2 is a hydroxyl, carboxyl, sulfonate, thiol, amine, tertiary amine or anhydride group; A1 is a styrene monomer; B1 is a methyl methacrylate, vinylpyridine or diene monomer; and each of o and p is an integer of 10-5000.
Abstract translation: 目的：提供通过活性阴离子聚合获得的半遥爪或遥爪聚合物稳定的纳米尺寸金属或其金属盐，其通过简单地与嵌段共聚物混合在空气中具有优异的稳定性并形成纳米结构。 构成：存在于在聚合物链末端具有官能团且分子量为1000-10000的聚合物基质中的纳米尺寸金属颗粒或其金属盐在空气中稳定，并且由选自 由下式1-5组成的组，其中R 1和R 2各自为H，甲基或叔丁基; X1和X2各自独立地是羧基，羟基，磺酸酯，酸酐或硫醇基; n为10-5000的整数; R 3和R 4各自为H或甲基; X2和X3各自独立地是羟基，羧基，磺酸酯，硫醇，胺，叔胺或酸酐基团; m为20-10000的整数; X4是羟基，胺或叔胺基团; Y2是羟基，羧基，磺酸酯，硫醇，胺，叔胺或酸酐基团; A1是苯乙烯单体; B1是甲基丙烯酸甲酯，乙烯基吡啶或二烯单体; o和p各自为10-5000的整数。
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公开(公告)号：KR1020010094269A
公开(公告)日：2001-10-31
申请号：KR1020000017831
申请日：2000-04-06
Applicant: 한국과학기술연구원
IPC: C08F112/08
Abstract: PURPOSE: A method for preparing a polystyrene grafted copolymer having a functional group is provided, to allow various functional groups to be introduced into the side chain of a syndiotactic polystyrene, thereby preparing the polymer with improved strength and processability. CONSTITUTION: The method comprises the steps of: protecting a functional group of a benzophenol derivative with a silane protecting group and methylating it to obtain a diphenylethylene derivative; reacting the diphenylethylene derivative with an alkyl alkali metal initiator quantitatively, and polymerizing the obtained one with styrene and/or a diene-based monomer in a non-polar solvent or a non-polar/polar solvent mixture, to obtain a styrene and/or diene living polymer having a functional group; reacting the living polymer with 4-chloromethylstyrene to obtain a styrene and/or diene-chained a styrene macromonomer having a functional group; and copolymerizing the macromonomer and styrene monomer by using a titanocene catalyst system, to obtain a polystyrene grafted copolymer. The macromonomer is represented by the formula 5 or 6. In the formula 5, R is a normal butyl group or a secondary butyl group; R1 is H, -CH3, -OCH3, -N(CH3)2, -OSi(t-C4H9)(CH3)2, -N(Si(CH3)3)2 or -C(CH3); X1 and X2 are independent each other, are H, -OCH3, -N(CH3)2, -OSi(t-C4H9)(CH3)2 or -N(Si(CH3)3)2, and are not H simultaneously; and n is a degree of polymerization and is an integer of 5-100. In the formula 6, R is a normal butyl group or a secondary butyl group; R1 is H or -CH3; X1 and X2 are independent each other, are H, -OCH3, -N(CH3)2, -OSi(t-C4H9)(CH3)2 or -N(Si(CH3)3)2, and are not H simultaneously; and m and n are a degree of polymerization and are an integer of 5-100.
Abstract translation: 目的：提供一种制备具有官能团的聚苯乙烯接枝共聚物的方法，以允许将各种官能团引入间同立构聚苯乙烯的侧链中，从而制备具有改进的强度和加工性的聚合物。 方案：该方法包括以下步骤：用硅烷保护基保护苯并酚衍生物的官能团并进行甲基化，得到二苯基乙烯衍生物; 将二苯基乙烯衍生物与烷基碱金属引发剂定量反应，并将所得二苯乙烯衍生物与非极性溶剂或非极性/极性溶剂混合物中的苯乙烯和/或二烯类单体进行聚合，得到苯乙烯和/或 具有官能团的二烯生物聚合物; 使活性聚合物与4-氯甲基苯乙烯反应，得到具有官能团的苯乙烯和/或二烯链接的苯乙烯大分子单体; 并通过使用二茂钛催化剂体系共聚大分子单体和苯乙烯单体，得到聚苯乙烯接枝共聚物。 大分子单体由式5或式6表示。在式5中，R为正丁基或仲丁基; R 1是H，-CH 3，-OCH 3，-N（CH 3）2，-OSi（t-C 4 H 9）（CH 3）2，-N（Si（CH 3）3）2或-C（CH 3） X1和X2彼此独立，分别为H，-OCH3，-N（CH3）2，-OSi（t-C4H9）（CH3）2或-N（Si（CH3） n为聚合度，为5〜100的整数。 在式6中，R是正丁基或仲丁基; R1是H或-CH3; X1和X2彼此独立，分别为H，-OCH3，-N（CH3）2，-OSi（t-C4H9）（CH3）2或-N（Si（CH3） m和n为聚合度，为5〜100的整数。
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公开(公告)号：KR100135914B1
公开(公告)日：1998-04-25
申请号：KR1019940035326
申请日：1994-12-20
Applicant: 한국과학기술연구원
Abstract: 본 발명은 이소택틱 인텍스가 96% 이상인 폴리프로필렌 수지에 가공조제와 기핵제를 동시에 배합한 폴리프로필렌 수지를 시트 또는 필름상으로 용융압축하고 냉각 드럼 또는 냉각 수조에서 급랭한 후 얻어진 미배향 시트 또는 필름을 종방향으로 2단계 연신방법을 통해 5.80-8.00배 연신하고 이어서 횡방향으로 7.50-10.0배 연신하는 것으로 이루어진 축차 이축연신 폴리프로필렌 필름의 연속 제조방법을 제시한다. 본 발명에 따라 제조된 폴리프로필렌 필름은 종방향 인장 강도가 20㎏/㎜2 이상이며, 특수 테이프용, 전선 초벌 감기용, 골프채 및 자전거 삼각대 제조용 필름 등으로 이용될 수 있다.
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Patent Agency Ranking
公开(公告)号：KR1019960021485A
公开(公告)日：1996-07-18
申请号：KR1019940035326
申请日：1994-12-20
Applicant: 한국과학기술연구원
Abstract: 본 발명은 이소택틱 인덱스가 96% 이상인 폴리프로필렌 수지에 가공조제와 기핵제를 동시에 배합한 폴리프로필렌 수지를 시트 또는 필름상으로 용융압축하고 냉각 드럼 또는 냉각 수조에서 급랭한 후 얻어진 미배향 시트 또는 필름을 중방향으로 2단계 연신방법을 통해 5.80~8.00배 연신하고 이어서 횡방향으로 7.50~10.0배 연신하는 것으로 이루어진 축차 이축연신 폴리프로필렌 필름의 연속 제조방법을 제시한다. 본 발명에 따라 제조된 폴리프로필렌 필름은 종방향 인장 강도가 20kg/mm
2 이상이며, 특수 테이프용, 전선 초벌 감지용, 골프채 및 자전거 삼각대 제조용 필름 등으로 이용될 수 있다.-
公开(公告)号：KR1019950010228B1
公开(公告)日：1995-09-12
申请号：KR1019920020030
申请日：1992-10-29
Applicant: 한국과학기술연구원
Abstract: The fluoroalkyl contg. monomer is prepd. by reacting fluoroalkyl carboxylic acid or fluoroalkyl carboxyl halide or fluoroalkyl sulfonic acid or fluoroalkyl sulfonyl halide, with the acrylic monomer comprising hydroxyl gp. and amine gp., or the styrenic monomer comprising hydroxyl gp. or amine gp., or the vinylether type monomer. The polymer usful for preparing a contact lens having good oxygen permeability is prepd. by (co)polymerising 5-100 wt.% of the obtd. fluoroalkyl contg. monomer, 0-60 wt.% of silicone contg. monomer, 0-60 wt.% of vinyl based monomer, 0-10 wt.% of crosslinking monomer, and/or 0-5 wt.% of hydrophilic monomer.
Abstract translation: 氟代烷基 单体制备 通过使氟代烷基羧酸或氟代烷基羧基卤化物或氟代烷基磺酸或氟代烷基磺酰卤与包含羟基gp的丙烯酸单体反应。 和胺gp，或包含羟基gp的苯乙烯单体。 或胺gp，或乙烯基醚型单体。 制备用于制备具有良好透氧性的隐形眼镜的聚合物是制备的。 通过（共）聚合5-100重量％的obtd。 氟代烷基 单体，0-60重量％的硅氧烷 单体，0-60重量％的乙烯基单体，0-10重量％的交联单体和/或0-5重量％的亲水单体。
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公开(公告)号：KR1019950001643B1
公开(公告)日：1995-02-27
申请号：KR1019910013644
申请日：1991-08-07
Applicant: 한국과학기술연구원
IPC: C08L81/04
CPC classification number: C08L81/02 , C08L67/04 , C08L77/12 , C08L81/06 , C08L77/00 , C08L2666/18 , C08L81/00
Abstract: The molding compsn. for the liquid crystal composite in situ composite comprises 60-80 wt.% of polyphenylene sulfide; 5-10 wt.% of thermotropic liquid crystal polymer; and 15-30 wt.% of polysulfone. The molding product is prepared by injection molding the obtd. compsn., and then the composite fiber is prepared from the obtd. compsn. Pref. the obtd. compsn. can be melt-extruded at 285-290 deg.C or melt-injection molded at 320-350 deg.C. Pref. the thermotropic liquid crystal polymer is condensed to comprise 70 wt.% of 2,6-hydroxy naphthoic acid and 30 wt.% of hydroxy benzoic acid.
Abstract translation: 成型产品。 对于液晶复合材料原位复合材料包含60-80重量％的聚苯硫醚; 5-10重量％的热致液晶聚合物; 和15-30重量％的聚砜。 成型产品通过注射成型制备。 然后从复合纤维制备复合纤维。 compsn。 县。 有限公司 compsn。 可以在285-290℃熔融挤出或在320-350℃熔融注塑成型。 县。 将热致液晶聚合物冷凝成包含70重量％的2,6-羟基萘甲酸和30重量％的羟基苯甲酸。
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公开(公告)号：KR1019890001067B1
公开(公告)日：1989-04-22
申请号：KR1019850007216
申请日：1985-09-30
Applicant: 한국과학기술연구원
IPC: C08G71/04
Abstract: The urethane coating agent is prepd. by (a) reacting aliphatic diisocyanate with polyol and bisphenol A 10-50% (to total solids) and MDA 0.5-1% (to total solids) in lower b.p. solvent, (b) neutralizing with acid and (c) distg. off solvent. Thus, e.g. vacuum dry polypropyleneglycole (mw ca 2000) and polyethertriol (mw ca 3000) for 30 min at 100 deg.C, put dried polyols, bisphenol A, 1,6-hexanediol, MDA, methylethylketone (MEK) and hexamethylenediisocyanate into reactor and react them for 4hr at 70 deg. C, neutralize with HCl and add water with stirring, and distg. off MEK to give coating agent.
Abstract translation: 制备聚氨酯涂料 通过（a）使脂族二异氰酸酯与多元醇和双酚A与总摩尔数相比为10-50％（总固体）和MDA为0.5-1％（总固体）的较低沸点。 溶剂，（b）用酸中和，（c）distg。 关闭溶剂。 因此，例如 在100℃下真空干燥聚丙二醇（mw ca 2000）和聚醚三醇（mw ca 3000）30分钟，将干燥的多元醇，双酚A，1,6-己二醇，MDA，甲基乙基酮（MEK）和六亚甲基二异氰酸酯加入反应器中， 在70度下4小时。 C，用HCl中和，搅拌加水， 关闭MEK给予涂层剂。
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