Abstract:
니켈이트리아안정화지르코니아복합체(Ni/YSZ)에귀금속(M)이도핑된것이되, 니켈이트리아안정화지르코니아(YSZ)의표면의니켈사이트(Ni sites)에귀금속(M)과니켈의합금(M-Ni alloy)이형성된건식개질촉매및 이를귀금속/글루코스를이용하여제조하는방법, 상기촉매를이용하여건식개질을수행하는방법이제공된다. 이에따르면, Ni/YSZ 촉매와대비하여훨씬높은건식개질활성을보여줄수 있다. 또한, 열화가억제또는방지되어장기성능도향상할수 있다. 또한, 상기제조방법은 Ni/YSZ 표면의 Ni 사이트에서의귀금속-Ni의합금화를수행하는데유용하고, 또한제조공정을단순화할수 있어대량생산에적합하다.
Abstract:
본 발명은 니켈-알루미늄 합금 분말 제조에 있어서, 공정이 간단하고 경제적인 동시에 반응기 부식 문제를 해결할 수 있는 니켈-알루미늄 합금 분말 저온 제조 방법에 관한 것으로, 본 발명에서는 니켈 분말 및 알루미늄 분말을 반응기 내에서 혼합하여 혼합 분말을 제조하고, 상기 반응기 내에 염화알루미늄을 첨가하는 단계(S1); 상기 반응기 내부를 진공 상태로 형성시킨 후, 상기 반응기를 실링하는 단계(S2); 및 상기 실링된 반응기 내의 혼합 분말을 저온 열처리하여, 니켈-알루미늄 합금 분말을 제조하는 단계(S3);를 포함하는 니켈-알루미늄 합금 분말 저온 제조 방법이 제공된다.
Abstract:
The present invention relates to a pre-treatment method of a porous nickel-based catalyst for a fuel cell, and more specifically, in order to increase activity of reforming reaction to supply hydrogen which is a raw material of a fuel electrode of a fuel cell, a porous nickel-based catalyst is pre-treated under SPOX or POX conditions, whereby the porous nickel-based catalyst have high activity in the reforming reaction. In addition, by structure co-catalyst coating on the porous nickel-based catalyst before pre-treating the porous nickel-based catalyst, it prevents activity of the porous nickel-based catalyst from decreasing to hydrocarbon reforming reaction as time goes on.
Abstract:
The present invention provides: a hydrogen production device which uses ammonia borane pellets as fuel for producing hydrogen, successively produces hydrogen without using a separate catalyst by promoting the anhydrization of the ammonia borane pellets using a heated organic solvent, is capable of self sustainable operation, and is capable of minimizing impurities; and a hydrogen producing method using the same.
Abstract:
PURPOSE: An apparatus for supplying reformed gas to a solid oxide fuel cell and a method thereof are provided to be able to rapidly and easily change the reformed gas, especially methane composition supplied to a solid oxide fuel cell, and to be able to stably control the temperature of a stack. CONSTITUTION: An apparatus for supplying reformed gas to a solid oxide fuel cell (300) comprises a backup reformer (230), a main reformer (250) connected to the backup reformer, a valve (100) branching a part of the gas supplied to the main reformer from the backup reformer to supply to the cathode of the solid oxide fuel cell. A method of supplying the reformed gas to the solid oxide fuel cell is to branch a part of the gas supplied to the main reformer from the backup reformer and to supply to the cathode of the solid oxide fuel cell. [Reference numerals] (AA) Anode gas flow; (BB) Cathode gas flow; (CC) Gas discharged from a catalyst combustor; (DD) Cooling water
Abstract:
자열 개질 반응이 일어나는 자열 개질 반응기, 상기 자열 개질 반응기와 대향하여 위치하고 수성화 반응이 일어나는 수성화 반응기, 상기 자열 개질 반응기와 상기 수성화 반응기 사이에 위치하는 내부 열교환기를 포함하는 연료 처리 장치로서, 상기 자열 개질 반응기의 반응물은 상기 내부 열교환기를 거쳐서 상기 자열 개질 반응기로 공급되고, 상기 자열 개질 반응기의 생성물은 상기 내부 열교환기를 거쳐서 상기 반응물과 열교환한 후 상기 수성화 반응기의 반응물로서 공급되는 자열 개질 반응기와 수성화 반응기가 통합된 연료 처리 장치 및 연료 처리 방법이 제공된다.
Abstract:
PURPOSE: An apparatus and method for treating fuel is provided to maintain high hydrogen yield and low carbon monoxide yield and to maintain sufficient temperature difference between an auto-thermal reforming reaction and hydrogenation reaction. CONSTITUTION: An apparatus(100) for treating fuel comprises an auto-thermal reformation reactor(10) which conducts an auto-thermal reforming reaction; a hydrogenation reactor(30) which is located opposite the auto-thermal reformation reactor; and an internal heat exchanger(20) between the auto-thermal reformation reactor and the hydrogenation reactor. The result of the auto-thermal reformer is supplied to the hydrogenation reactor through the internal heat exchanger, as a reactant after heat exchanging. [Reference numerals] (AA) Reactant(Ethanol + Water + Air)
Abstract:
니켈이트리아안정화지르코니아복합체(Ni/YSZ)에귀금속(M)이도핑된것이되, 니켈이트리아안정화지르코니아(YSZ)의표면의니켈사이트(Ni sites)에귀금속(M)과니켈의합금(M-Ni alloy)이형성된건식개질촉매및 이를귀금속/글루코스를이용하여제조하는방법, 상기촉매를이용하여건식개질을수행하는방법이제공된다. 이에따르면, Ni/YSZ 촉매와대비하여훨씬높은건식개질활성을보여줄수 있다. 또한, 열화가억제또는방지되어장기성능도향상할수 있다. 또한, 상기제조방법은 Ni/YSZ 표면의 Ni 사이트에서의귀금속-Ni의합금화를수행하는데유용하고, 또한제조공정을단순화할수 있어대량생산에적합하다.
Abstract:
PURPOSE: A carbon monoxide poisoning relieving method of a fuel cell is provided to be able to easily relieve the carbon monoxide poisoning phenomenon of a cathode catalyst generated when a high temperature polymer electrolyte membrane fuel cell uses hydrocarbon gas as fuel. CONSTITUTION: A carbon monoxide poisoning relieving method of a polymer electrolyte membrane fuel cell comprises a step of supplying steam to the cathode of a polymer electrolyte membrane fuel cell. The working temperature of the polymer electrolyte membrane fuel cell is 120-200deg.C. At the working temperature of the polymer electrolyte membrane fuel cell, steam is provided to the cathode of the polymer electrolyte membrane fuel cell. A modified gas supply apparatus supplying modified gas to the polymer electrolyte membrane fuel cell supplies modified gas to the cathode of the polymer electrolyte membrane fuel cell with maintaining steam in the modified gas or adding steam.
Abstract:
The present invention relates to a method for promoting a dehydrogenation reaction of ammonia borane pellets including a solid catalyst, wherein the method comprises: a mixture preparing step of mixing ammonia brane and a solid catalyst to prepare a mixture; a pellet preparing step of pelletizing the mixture to prepare ammonia brane pellets; a supplying step of supplying the prepared ammonia brane pellets to a reactor; and a hydrogen preparing step of applying heat to the reactor, to which the ammonia brane pellets are supplied, to promote a dehydrogenation reaction, thereby promoting the hydrogen generation rate and enabling continuous generation of hydrogen.