公开(公告)号：KR100064386B1

公开(公告)日：1993-08-13

申请号：KR1019900001964

申请日：1990-02-17

Applicant: 한국과학기술연구원

Inventor： 김정엽 ,  이희우 ,  민경선

IPC: C08F2/00 ,  C08G73/06

公开(公告)号：KR1019930003715B1

公开(公告)日：1993-05-08

申请号：KR1019900001964

申请日：1990-02-17

Applicant: 한국과학기술연구원

Inventor： 김정엽 ,  이희우 ,  민경선

IPC: C08F2/00 ,  C08G73/06

CPC classification number: C08G61/123

Abstract: 5-Ring heterocyclic electric conductive polymer of formula (II) is prepared by electro chemical polymerizing the 5-ring heterocyclic monomer of formula (I) in the presence of tetrabutyl ammoniumalkyl sulfate electrolyte and organic solvent. The obtd. electric conductive polymer has more than 100 s/cm of the electric conductivity. In the formulas, M is nitrogen or sulfur; R is C4-22 aliphatic alkyl; if M is N, R is H, and if M is S, sustd. hydrogen in M is isolated and R is H or C4-22 aliphatic alkyl. Pref. the 5-ring heterocyclic monomer is pyrrole, thiophene or thiophen deriv. on the 3-position substd. with C4-22 aliphatic gp..

Abstract translation: 在四丁基烷基硫酸铵电解质和有机溶剂的存在下，通过电化学聚合式（I）的5-环杂环单体制备式（II）的5-环杂环导电聚合物。 有限公司 导电聚合物具有超过100s / cm的电导率。 在式中，M为氮或硫; R为C 2-4-22脂族烷基; 如果M是N，R是H，如果M是S，则维持。 分离M中的氢，R是H或C 2-4-22脂族烷基。 县。 5-环杂环单体是吡咯，噻吩或噻吩衍生物。 在3位置。 与C4-22脂肪gp ..