Abstract:
PURPOSE: A tandem structure dye-sensitized solar cell and a manufacturing method thereof are provided to reduce production costs by forming a photo-electrode and a counter electrode at one substrate. CONSTITUTION: A lower side dye sense solar cell(300) is composed of a photo-electrode(110), a counter electrode(120), an insulating layer(130), and a nano-oxide layer(140). The counter electrode is separately formed with the photo-electrode. The insulating layer is formed into the structure of covering the upper side and side of the counter electrode. An upper side sense solar cell(400) is composed of a photo-electrode(210), a counter electrode(220), a porosity insulating layer(230), a nano-oxide layer(240). The lower side dye sense solar cell and the upper side sense solar cell are as the structure of each other facing with a sealing material(700).
Abstract:
PURPOSE: Provided are a dye-sensitized solar cell provided with a silane coupling co-absorbent capable of preventing a back electron transfer reaction and improving aggregation of the dye by having corrosion resistance for an electrolyte and effectively absorbing onto the surface of titanium dioxide, and a manufacturing method thereof. CONSTITUTION: A dye-sensitized solar cell is provided with a sillane coupling co-absorbent wherein the co-absorbent includes at least one functional group selected from a group consisting of a triethoxysilyl, a triethoxy vinyl and a trietoxy group.
Abstract:
PURPOSE: Triphenylamine salicylic acid is provided to improve photoelectric conversion efficiency by using the triphenylamine salicylic acid as a ligand for a photoelectrochemical solar cell. CONSTITUTION: Triphenylamine salicylic acid is represented by chemical formula 1. A manufacturing method of the triphenylamine salicylic acid comprises a step of reacting triphenylamine-4-boronic acid and 5-bromo salicylic acid under the presence of platinum acetate. A photoelectrochemical solar cell using a ligand-metal charge transition comprises an anode in which a nanooxide layer with a ligand attached to the surface thereof is formed. The ligand is the triphenylamine salicylic acid represented by the chemical formula 1.
Abstract:
PURPOSE: A nanogel-type electrolyte is provided to improve long term stability and photoelectric conversion efficiency and to reduce concentration of a used ionic liquid. CONSTITUTION: A nanogel-type electrolyte comprises a nanoparticle with a chemically bonded imidazolium salt indicated in chemical formula 1, and an ionic liquid electrolyte. A manufacturing method of the nanoparticle with the chemically bonded imidazolium salt comprises: a step of manufacturing a nanoparticle which is surface-treated with 3-glycidyloxypropyltrimethoxysilane by reacting the nanoparticle and 3-(trimethoxysilyl)propyl methacrylate; a step of reacting the surface-treated nanoparticle and imidazole; and a step of reacting the result with methyl iodide.
Abstract:
Disclosed are a dye-sensitized solar cell with a co-adsorbent whose chemical bond is enhanced and a manufacturing method thereof. The method for manufacturing the dye-sensitized solar cell with the co-adsorbent whose chemical bond is enhanced according to the present invention comprises: S1, a step of forming a photoelectrode by absorbing a dye and the co-adsorbent with dipole moment on a porous layer including oxide semiconductor particles formed on one side of a substrate; S2, a step of forming a relative electrode composed of a metallic material at an upper part of the substrate having a conductive oxide layer composed of the oxide semiconductor particles; and S3, a step of preparing a dye-sensitized solar cell module by arranging the photoelectrode spaced apart from the relative electrode while facing each other, injecting the electrolyte and sealing it. By this means, the present invention may have more intensified corrosion resistance against the electrolyte, may prevent back electron transfer reaction by being effectively absorbed on the titanium oxide surface, and may improve dye aggregation.
Abstract:
The present invention relates to a cylinder type dye-sensitized solar cell containing phase transition materials and a module thereof. The cylinder type dye-sensitized solar cell containing phase transition materials comprises an inner center material of the bar shape and an outer transparent tube having the curved surface in the shape of surrounding the inner center material, wherein a hollow is formed in the inner center material so that phase conversion materials can be embedded, a metal thin film electrode arranged in the external surface of the inner center material, a transparent electrode located in the internal surface of the outer transparent tube by being separated to be opposite to the metal thin film electrode, and an electrolyte layer interposed between the metal thin film electrode and the transparent electrode, thereby improving light collection efficiency of sunlight as well as improving the long term stability and preventing the temperature rise that may cause the declination of optical conversion efficiency by preventing the internal temperature from being raised at the temperature that the photoelectric efficiency of the dye-sensitized solar cell becomes maximum.