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公开(公告)号：KR1020130001465A
公开(公告)日：2013-01-04
申请号：KR1020110062228
申请日：2011-06-27
Applicant: 한국에너지기술연구원
CPC classification number: Y02A50/2342 , Y02C10/04 , Y02C10/06 , B01D53/14 , B01D53/62 , B01D53/96 , B01J20/22
Abstract: PURPOSE: A continuous carbon dioxide collecting method for minimizing regeneration energy is provided to supply a carbon dioxide absorbent with a composition which minimizes salt generation. CONSTITUTION: A method for removing carbon dioxide includes: a step for bringing gas containing carbon dioxide into contact with a carbon dioxide absorbent in which a sterically hindered cyclic amine is added into alkali carbonate(S110); a step for absorbing carbon dioxide from the gas(S120); a step for separating salts from the absorbent(S130); and a step for regenerating the absorbent(S140). The salt separating process uses a decanter. The absorbent includes 20 wt% or less of the alkali carbonate and 10 wt% or less of the sterically hindered cyclic amine. The alkali carbonate is at least one selected from a group including potassium carbonate(K_2CO_3), sodium carbonate(Na_2CO_3), sodium hydroxide(NaOH), potassium hydroxide(KOH), potassium bicarbonate(KHCO_3), and sodium bicarbonate(NaHCO_3). [Reference numerals] (S110) Gas contacting step; (S120) Carbon dioxide absorbing step; (S130) Salt separating step; (S140) Absorbent regenerating step
Abstract translation: 目的：提供用于使再生能量最小化的连续二氧化碳收集方法，以使二氧化碳吸收剂具有最小化盐产生的组合物。 构成：除去二氧化碳的方法包括：使含二氧化碳的气体与其中将空间位阻环胺加入碱金属碳酸盐的二氧化碳吸收剂接触的步骤（S110）; 从气体吸收二氧化碳的步骤（S120）; 从吸收剂中分离盐的步骤（S130）; 和再生吸收剂的步骤（S140）。 盐分离过程使用滗析器。 吸收剂包含20重量％以下的碱金属碳酸盐和10重量％以下的空间位阻环状胺。 碱金属碳酸盐是选自碳酸钾（K 2 CO 3），碳酸钠（Na 2 CO 3），氢氧化钠（NaOH），氢氧化钾（KOH），碳酸氢钾（KHCO 3）和碳酸氢钠（NaHCO 3）的组中的至少一种。 （S110）气体接触步骤; （S120）二氧化碳吸收步骤; （S130）盐分离步骤; （S140）吸收剂再生步骤
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公开(公告)号：KR1020120097366A
公开(公告)日：2012-09-03
申请号：KR1020120092691
申请日：2012-08-24
Applicant: 한국에너지기술연구원
IPC: C07D233/58 , B01D53/14 , B01D53/62
CPC classification number: Y02C10/04 , Y02C10/06 , Y02P20/152 , C07D233/58 , B01D53/14 , B01D53/62
Abstract: PURPOSE: A method for preparing phenolate ionic liquid used as a carbon dioxide absorbent is provided to improve carbon dioxide absorbing ability and speed and to lower production cost. CONSTITUTION: A method for preparing phenolate ionic liquid is prepared by synthesizing an imidazolium cation and a phenolate anion. The imidazolium cation is (bmim)(1-butyl-3-methylimidazolium), (emim)(1-ethyl-3-methyimidazolium), or (hmim)(1-hexyl-3-methyimidazolium). A method for preparing the phenolate ionic liquid comprises: a step of mixing (imidazolium cation)Cl and Na-phenolate with methanol and stirring; and a step of removing NaCl and unreacted materials. [Reference numerals] (AA) Process of drying [imidazolium-based cation]Cl and Na-phenolate which are starting substances; (BB) Process of mixing and stirring methanol into each of two starting substances; (CC) Process of mixing and synthesizing two starting substances; (DD) Process of removing impurities; (EE) Solvent removing step; (FF) Washing step; (GG) Filtering step; (HH) Column filtering step
Abstract translation: 目的：提供一种制备用作二氧化碳吸收剂的酚盐离子液体的方法，以提高二氧化碳吸收能力和速度，降低生产成本。 构成：通过合成咪唑鎓阳离子和酚盐阴离子制备酚盐离子液体的制备方法。 咪唑阳离子是（bmim）（1-丁基-3-甲基咪唑鎓），（emim）（1-乙基-3-甲基咪唑鎓）或（hmim）（1-己基-3-甲基咪唑鎓）。 一种制备酚盐离子液体的方法包括：将（咪唑鎓阳离子）Cl和苯酚钠与甲醇混合并搅拌的步骤; 以及除去NaCl和未反应物质的步骤。 （AA）作为原料的干燥[咪唑鎓系阳离子] Cl和苯酚钠的工序; （BB）将甲醇混合并搅拌成两种起始物质的方法; （CC）混合合成两种起始物质的方法; （DD）除杂过程; （EE）溶剂去除步骤; （FF）洗涤步骤; （GG）过滤步骤; （HH）列过滤步骤
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公开(公告)号：KR100771230B1
公开(公告)日：2007-10-29
申请号：KR1020060088761
申请日：2006-09-13
Applicant: 한국에너지기술연구원
CPC classification number: Y02C10/08
Abstract: A ceramic fiber supporter and a method for preparing the same are provided to improve the efficiency in separation of carbon dioxide during a decarbonating process before combustion. A carbon dioxide adsorbent and a catalyst are immersed in a sheet type of ceramic fiber supporter. The ceramic fiber supporter includes an inorganic binder, an organic binder, and pulp. The carbon dioxide adsorbent is one or more selected from calcium carbonate, potassium carbonate, sodium carbonate, magnesium carbonate, silicate iridium, and iridium carbonate. The catalyst is one or more selected from nickel, rhodium, and platinum. The inorganic binder is one or more selected from silica sol, bentonite, clay, mica, kaolin and montmorillonite. The organic binder is one or more selected from polyvinyl alcohol, gelatin and methylcellulose.
Abstract translation: 提供了陶瓷纤维支撑体及其制备方法，以提高燃烧前的脱碳过程中二氧化碳的分离效率。 将二氧化碳吸附剂和催化剂浸渍在片状陶瓷纤维载体中。 陶瓷纤维支撑体包括无机粘合剂，有机粘合剂和纸浆。 二氧化碳吸附剂是选自碳酸钙，碳酸钾，碳酸钠，碳酸镁，硅酸铱和碳酸铱中的一种或多种。 催化剂是选自镍，铑和铂中的一种或多种。 无机粘合剂是选自硅溶胶，膨润土，粘土，云母，高岭土和蒙脱石中的一种或多种。 有机粘合剂是选自聚乙烯醇，明胶和甲基纤维素中的一种或多种。
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公开(公告)号：KR1020060016412A
公开(公告)日：2006-02-22
申请号：KR1020040064835
申请日：2004-08-17
Applicant: 한국에너지기술연구원
CPC classification number: C01B3/36 , C01B3/38 , C01B3/50 , C01B2203/0425
Abstract: 본 발명은 화석연료를 이용하여 메탄을 생산한 후, 수증기개질반응을 통한 수소를 생산하는 과정 중 생성된 이산화탄소를 분리하는 공정을 포함하는 연소전 탈탄소화방법에 관한 것으로, 3개의 반응기 RA, RB, RC로 구성되어 물(H
2 O)과 메탄(CH
4 )이 유입되어 이산화탄소(CO
2 )와 수소(H
2 )를 배출하는 과정에서 이산화탄소를 제거하는 연소전 탈탄소화방법에 있어서, (스텝1) RA는 혼성반응과정, RB는 온도조절과정, RC는 탈착과정; (스텝2) RA는 탈착과정, RB는 혼성반응과정, RC는 온도조절과정; 및 (스텝3) RA는 온도조절과정, RB는 탈착과정, RC는 혼성반응과정;을 포함하는 공정사이클로 구성되고, 상기의 혼성반응과정은 메탄과 물을 이용한 수증기개질반응과 흡착제를 이용하여 상기 수증기개질반응에서 생성된 이산화탄소를 흡착하는 흡착반응이 동시에 수행되도록 온도를 유지하는 과정이며, 상기 온도조절과정은 흡착제에 흡착된 이산화탄소를 탈착시키고 혼성반응으로 넘어가기 위하여 온도를 낮추는 과정이고, 상기 탈착과정은, 흡착제에 흡착된 이산화탄소를 탈착하기 위하여 온도를 탈착온도까지 높이는 과정인 것을 특징으로 하는 연소전 탈탄소화 방법이다.
흡착제, 이산화탄소, 탈탄소-
公开(公告)号：KR100527420B1
公开(公告)日：2005-11-09
申请号：KR1020030045260
申请日：2003-07-04
Applicant: 한국에너지기술연구원
IPC: B01D53/02
CPC classification number: Y02C10/08
Abstract: 본 발명은 CO
2 를 선택적으로 흡수하는 전달반응기와, CO
2 를 잡고있는 고체입자가 CO
2 를 놓아주면서 원래의 상태로 재생되는 재생반응기로 구성된 CO
2 분리회수장치에 관한 것으로, 외부로부터 공급된 CO
2 함유가스(11)가 건식고체흡수제와 접촉하여 CO
2 를 회수하는 회수반응기(1); 상기 회수반응기(1)와 연결되어 기체는 배출시키고 CO
2 를 함유하고 있는 고체만 분리하는 사이클론1(3a); 상기 사이클론1(3a)과 연결된 루프실(5)을 포함하는 고체이송파이프(7)를 통해 CO
2 를 함유하고 있는 고체를 공급받아 유동화가스(8)를 이용하여 CO
2 와 건식고체흡수제로 분리하고, 분리된 건식고체흡수제를 이송수단을 통해 다시 회수반응기(1)로 보내는 재생용 유동층반응기(2); 및 상기 재생용 유동층반응기(2)에서 분리된 CO
2 를 외부로 저장 또는 이용할 수 있도록 하는 CO
2 분리회수장치이다.-
Patent Agency Ranking
公开(公告)号：KR1020040069044A
公开(公告)日：2004-08-04
申请号：KR1020030005465
申请日：2003-01-28
Applicant: 한국에너지기술연구원
IPC: B22F9/30
Abstract: PURPOSE: A method for preparing barium titanate powder is provided to prepare barium titanate powder having high purity, small particle size and uniform particle size distribution from primary barium titanate powder prepared using starting materials of titanium contained hydroxide and barium contained hydroxide obtained by sulfuric acid process. CONSTITUTION: The method comprises a process of dehydration reacting a mixed solution of barium obtained from sulfuric acid process and titanium contained hydroxide at a temperature of 100 to 400 deg.C under a reaction pressure of atmospheric pressure to 20 kg/cm¬2; and a process of calcining the pH adjusted primary barium titanate powder after adjusting pH of the first barium titanate from 9 to 13 by washing primary barium titanate powder prepared by the dehydration reaction using acid solution or purified water, and wherein the calcination is performed in the temperature range of 800 to 1300 deg.C.
Abstract translation: 目的：提供一种制备钛酸钡粉末的方法，以制备使用由含钛的氢氧化物和含硫酸钡的硫酸制得的含氢氧化物制备的原始钛酸钡粉末，其纯度高，粒度小，粒度分布均匀的钛酸钡粉末 。 方案：该方法包括在大气压至20kg / cm 2的反应压力下，将从硫酸法得到的钡的混合溶液与含钛的氢氧化物在100〜400℃的温度下脱水反应的方法; 以及通过使用酸溶液或纯化水洗涤通过脱水反应制备的一次钛酸钡粉末，将第一钛酸钡的pH调节为9〜13后，对pH调整了的初级钛酸钡粉末进行煅烧，其中，在 温度范围800〜1300℃。
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公开(公告)号：KR100376203B1
公开(公告)日：2003-03-15
申请号：KR1020000081696
申请日：2000-12-26
Applicant: 한국에너지기술연구원
IPC: C08B16/00
CPC classification number: Y02P20/544
Abstract: PURPOSE: Provided are a method and a device which substantially increase a reaction rate of hydrolysis using a supercritical water and improve the yield of hydrolysis. CONSTITUTION: The method comprises the steps of (i) heating and pressurizing a raw water containing a small amount of sulfuric acid or sulfate in a heating part(4), (ii) providing the raw water to reactor(8) together with cellulose slurry provided by the slurry pump(10) to effect a hydrolysis, (ii) terminating a reaction by firstly cooling the reactants discharged from the reactor(8) with cooling water provided from cooling water tank(12), (iii) completely terminating a reaction by secondarily cooling the reactants by heat exchanger(13), (iv) passing the reaction product to filter unit(14) to filter an unreacted cellulose, while the filtrate being obtained from a product collecting tank.
Abstract translation: 目的：提供一种显着增加使用超临界水的水解反应速率并提高水解产率的方法和装置。 构成：该方法包括以下步骤：（i）在加热部分（4）中加热和加压含有少量硫酸或硫酸盐的原水，（ii）将原水与纤维素浆料 （10）提供以实现水解，（ii）通过首先用从冷却水罐（12）提供的冷却水冷却从反应器（8）排出的反应物，终止反应，（iii）完全终止反应 通过热交换器（13）二次冷却反应物，（iv）使反应产物通过过滤单元（14）以过滤未反应的纤维素，同时从产物收集罐获得滤液。
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公开(公告)号：KR1020020007504A
公开(公告)日：2002-01-29
申请号：KR1020000040581
申请日：2000-07-14
Applicant: 한국에너지기술연구원
IPC: C01F11/40
CPC classification number: Y02P20/544
Abstract: PURPOSE: A continuous preparation method of barium hexaferrite(BaO·6Fe2O3) powders by supercritical water crystallization is provided, which is characterized in that each step of hydrolysis, formation of critical nuclei, dehydration is performed in sequence. Accordingly the resultant barium hexaferrite powders are homogeneous and fine. CONSTITUTION: The preparation method is as follows: (i) hydrolyzing a mixed solution, being obtained from mixing a nitrate solution containing Fe and Ba and an alkali solution(KOH or NaOH) at a mixing point(MP1), at room temperature under 30-50MPa of pressure, which is represented by the formula, M(NO3)x(s) + xH2O(l) --> M(OH)x(l) + xHNO3(l) where M is metal, s is solid and l is liquid; (ii) forming critical nuclei by reacting a mixture, being obtained from mixing hydrolyzed raw materials (M(OH)x) and heated water at MP2, at 100-400deg.C for 3-10sec.; (iii) dehydrating a product in a reactor after heating hydrolyzed materials to 300-500deg.C of supercritical temperature for water rapidly at MP3 by using a hot water, where the size of formed particles is controlled by an angle of the reactor; (iv) recovering formed powder in a cyclone and washing.
Abstract translation: 目的：提出一种通过超临界水结晶连续制备六硼酸钡（BaO·6Fe2O3）粉末的方法，其特征在于每个步骤水解，形成临界核，脱水均按顺序进行。 因此，所得的六硼酸钡粉末是均匀的和细的。 制备方法：（i）水解混合溶液，将混合溶液（在混合点（MP1））下混合含有Fe和Ba的硝酸盐溶液和碱溶液（KOH或NaOH），在室温下混合30 -50MPa的压力，其由下式表示：M（NO 3）x（s）+ xH 2 O（1）→M（OH）x（1）+ xHNO 3（l）其中M是金属，s是固体， l是液体的 （ii）通过将水解原料（M（OH）x）和MP2的加热水混合得到的混合物在100-400℃下反应3-10秒，形成临界核。 （iii）通过使用热水在水中将水加热物料加热至300-500℃的超临界温度以迅速在MP3中，使反应器中的产物脱水，其中形成的颗粒的尺寸由反应器的角度控制; （iv）在旋风分离器中回收形成的粉末并洗涤。
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公开(公告)号：KR100121982B1
公开(公告)日：1997-11-10
申请号：KR1019940007564
申请日：1994-04-12
Applicant: 한국에너지기술연구원
IPC: C10L1/14 , C10M133/20 , C10M175/00
CPC classification number: F41B5/1426
Abstract: The present invention relates to a refining method for using waste lubricant as fuel by using a liquified ammonium solution. The ammomium solution is manufactured by pre-eliminating impurities (gypsum, etc) except nitrogen and phosphorous component from composite fertilizers not containing potassium by adding water.
Abstract translation: 本发明涉及使用液化铵溶液使用废润滑剂作为燃料的精炼方法。 淀粉溶液是通过加入水来除去不含钾的复合肥料除氮和磷成分以外的杂质（石膏等）制造的。
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公开(公告)号：KR1020140014740A
公开(公告)日：2014-02-06
申请号：KR1020120081513
申请日：2012-07-26
Applicant: 한국에너지기술연구원
IPC: C07D233/58 , B01D53/14 , B01D53/62
CPC classification number: B01D53/1475 , B01D53/1493 , B01D2252/30 , C07D233/61 , Y02C10/04 , Y02C10/06 , Y02P20/152
Abstract: Disclosed are an imidazolium-based ionic liquid functionalized with an amine and a method for a separation of carbon dioxide using the same. The imidazolium-based ionic liquid functionalized with the amine according to the present invention has a superior carbon dioxide absorption capacity. The absorbed carbon dioxide can be easily absorbed/desorbed by heating. The liquid of the present invention provides use convenience and can be effectively used in collecting CO2 since the liquid has a selectivity, a thermal stability, a repeatable usability, and a long lifespan.
Abstract translation: 公开了用胺官能化的咪唑鎓离子液体和使用其分离二氧化碳的方法。 用根据本发明的胺官能化的咪唑鎓离子液体具有优异的二氧化碳吸收能力。 吸收的二氧化碳可以通过加热容易地吸收/解吸。 本发明的液体提供使用的便利性，并且可以有效地用于收集二氧化碳，因为液体具有选择性，热稳定性，可重复的可用性和长的使用寿命。
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