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公开(公告)号：KR1020110054992A
公开(公告)日：2011-05-25
申请号：KR1020090111836
申请日：2009-11-19
Applicant: 한국에너지기술연구원
CPC classification number: B01J20/041 , B01D53/02 , B01J20/3078 , B01J20/32
Abstract: PURPOSE: An oxygen selective absorber and a method for preparing the same are provided to uniformly form a protective film on the surface of barium-contained compound using magnesium oxide. CONSTITUTION: Magnesium alkoxide is dissolved in alcohol in order to obtain magnesium oxide precursor solution. A barium-contained compound is dispersed in the magnesium oxide precursor solution in order to solate the dispersion solution. Distilled water is added to the solated dispersion solution in order to be gelated. The gelated dispersion solution is undergone a drying process and a sintering process.
Abstract translation: 目的：提供氧选择性吸收剂及其制备方法，以使用氧化镁在含钡化合物的表面上均匀形成保护膜。 构成：将醇盐溶解在醇中以获得氧化镁前体溶液。 将含钡化合物分散在氧化镁前体溶液中以溶剂化分散液。 将蒸馏水加入到溶剂型分散液中，使其凝胶化。 凝胶化分散液经过干燥过程和烧结过程。
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公开(公告)号：KR1020010095500A
公开(公告)日：2001-11-07
申请号：KR1020000018618
申请日：2000-04-10
Applicant: 한국에너지기술연구원
IPC: C07D307/32
CPC classification number: C07D315/00
Abstract: PURPOSE: A method for producing gamma butyrolactone using a maleic hydride is provided, thereby producing the novel catalyst which has high activity and selectivity can be used as a raw material in producing pyrrolidone. CONSTITUTION: The gamma butyrolactone is produced by mixing maleic anhydride(MAN) and tetrahydrofuran(THF); inserting the mixture into a reactor; reacting the mixture; separating products and catalysts to produce gamma butyrolactone(GBL), in which the catalyst consists of 40 to 70 wt.% of silica, 15 to 40 wt.% of nickel, 1 to 4 wt.% of palladium and 2 to 8 wt.% of molybdenum, wherein the silica has 50 m2/g or more of specific surface area; the reaction temperature is 100 to 275 deg. C; the reaction pressure is 50 to 150 kg/cm2; and the reactor is high pressure batch or continuous reactor.
Abstract translation: 目的：提供使用马来酸酐制造γ-丁内酯的方法，由此生产具有高活性和选择性的新型催化剂，可用作生产吡咯烷酮的原料。 构成：通过混合马来酸酐（MAN）和四氢呋喃（THF）产生γ-丁内酯; 将混合物插入反应器; 使混合物反应; 分离产物和催化剂以产生γ-丁内酯（GBL），其中催化剂由40至70重量％的二氧化硅，15至40重量％的镍，1至4重量％的钯和2至8重量％的钯组成。 ％的钼，其中二氧化硅具有50m 2 / g以上的比表面积; 反应温度为100-275℃。 C; 反应压力为50〜150kg / cm2; 并且反应器是高压分批或连续反应器。
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公开(公告)号：KR1019990081068A
公开(公告)日：1999-11-15
申请号：KR1019980014769
申请日：1998-04-24
Applicant: 한국에너지기술연구원
IPC: B01D15/00
Abstract: 휘발성석유화합물의 정제시설과 저장시설과 취급시설에서 배출되는 탄화수소류의 총 체적비가 약 15 - 53%인 오염공기를 실리카겔과 활성탄이 충진된 흡착식포집탑에 공급하여서 탄화수소류는 흡착 제거하고 일반적인 배출허용치 0.15 - 10g/m
3 를 만족하는 청정공기만을 대기로 배출하여서 대기환경오염을 방지하며, 흡착식포집탑에 흡착된 탄화수소류를 재생하여 얻어진 탄화수소류를 2탑식 흡착회수장치로 처리하여서 탄화수소류는 응측회수하여 자원 손실을 방지할 수 있는 휘발성 석유화합물의 흡착식포집장치와 2탑식 흡착회수장치 및 그 운전방법.-
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公开(公告)号：KR1020210041187A
公开(公告)日：2021-04-15
申请号：KR1020190123549
申请日：2019-10-07
Applicant: 한국에너지기술연구원
Abstract: 본발명은멤브레인공정및 증류공정을포함하는하이브리드가스분리공정에관한것으로, 본발명의일 측면은, 기체혼합물을멤브레인공정을통해 1차분리하는단계; 및상기 1차분리하는단계를통해얻은 1차기체분리물들을증류공정을통해 2차분리하는단계;를포함하고, 상기 1차기체분리물들중 일부는, 상기증류공정을위한증류장치의상단부에주입하고, 나머지는하단부에주입하는것인, 하이브리드가스분리공정을제공한다.
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Patent Agency Ranking
公开(公告)号：KR1020160082441A
公开(公告)日：2016-07-08
申请号：KR1020140193210
申请日：2014-12-30
Applicant: 한국에너지기술연구원
CPC classification number: B01J20/041 , B01J20/3078 , B01J2220/4806 , B01J2220/50
Abstract: 본발명에따른산소선택성흡착제는마그네슘산화물로코팅된스트론튬산화물을함유하며, 하기관계식 1을만족하는산소흡착이이루어져, 300℃이하의중온에서도대량의산소흡·탈착이이루어지는특징을갖는다. (관계식 1) 1.5 A≤ A ≤ 5 A관계식 1에서, Aref는스트론튬산화물을기준산소흡착제로, 산소분위기에서 1℃/분의속도로 400℃에서 100℃로감온할때, 기준산소흡착제의단위질량당흡착된산소의몰수이며, A는마그네슘산화물로코팅된스트론튬산화물을산소흡착제로, 동일조건에서, 산소흡착제의단위질량당흡착된산소의몰수이다
Abstract translation: 根据本发明，氧选择性吸附剂包括用氧化镁涂覆的氧化锶，并且当氧化物被吸收时，在等于或小于300℃的温度下吸收大量的氧并解吸，满足 以下关系式1，1.5 Aref <= A <= 5 Aref，其中Aref是基于氧化锶的氧吸附剂和当单一质量的现有参考氧吸收剂的氧气的摩尔数，当温度从400° 以1℃/分钟的速度C至100℃; 并且A是在与Aref相同的条件下计算的氧化镁涂覆的氧化锶和每单位质量的现有氧吸收剂的氧摩尔数。
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公开(公告)号：KR101499694B1
公开(公告)日：2015-03-11
申请号：KR1020130075908
申请日：2013-06-28
Applicant: 한국에너지기술연구원
CPC classification number: B01J20/043 , B01D53/02 , B01D2251/402 , B01D2251/406 , B01D2251/408 , B01D2253/112 , B01D2256/12 , B01D2257/104 , B01J20/28016 , C01B13/0281 , C01F11/18 , C01F11/186 , C01P2002/50 , C01P2002/72 , C01P2002/85 , C01P2004/03 , C01P2004/61
Abstract: 본 발명은 종래의 산소 선택성 흡착제보다 동일 조업 온도에서도 저진공에서 산소를 탈착시킬 수 있도록, 산소흡착활성원소인 바륨에 Sr 등 이종의 금속을 첨가함으로써 전이 산소 분압을 증가시키고, 높은 열적 안정성 및 우수한 산소 흡착능을 나타내는 Ba
x Sr
(1-x) Mg
y (CO
3 )
(1+y) 입자 또는 Ba
x Sr
(1-x) CO
3 입자를 포함하는 산소 선택성 흡착제 및 이의 제조방법에 관한 것이다.-
公开(公告)号：KR101352832B1
公开(公告)日：2014-01-20
申请号：KR1020110071104
申请日：2011-07-18
Applicant: 한국에너지기술연구원
IPC: C01B15/013 , B01D3/36
Abstract: 본 발명은, 물을 함유하는 과산화수소에서 공비제를 이용하여 물을 제거함으로서 고농도의 과산화수소를 제조하기 위한 공비제를 이용한 과산화수소 농축 방법에 관한 것이다. 본 발명에 따른 공비제를 이용한 과산화수소 농축 방법은, 재비기, 칼럼 및 응축기로 이루어지는 계통 내에 진공을 생성하는 단계; 상기 재비기에 내장되고 물을 함유하는 과산화수소에 열을 가하여 기화시키는 단계; 비점의 차이에 의해 상기 칼럼의 하단에 과산화수소가 응축되고 상기 칼럼의 상단에 물이 응축된 상태에서 상기 물에 공비제를 혼합하여 상기 물과 공비제의 혼합물을 증발시키는 단계; 및 상기 물과 공비제의 혼합물을 상기 응축기에서 응축하여 공비제를 회수하는 단계;를 포함하고, 상기 진공은 상기 물과 공비제의 혼합에 의한 온도에서 공비점에 도달할 수 있는 압력으로 설정된다.
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19.发明授权
公开(公告)号：KR100836709B1
公开(公告)日：2008-06-10
申请号：KR1020070011196
申请日：2007-02-02
Applicant: 한국에너지기술연구원
CPC classification number: Y02A50/2342 , C01B32/50 , B01D53/1406 , B01D53/1425 , C01C1/10
Abstract: A method and an apparatus for producing carbon dioxide with a high purity by continuously recovering carbon dioxide contained in a mixed gas without loss of ammonia by using ammonia water as an absorbing solution are provided. An apparatus for producing carbon dioxide with a high purity continuously from a mixed gas containing carbon dioxide comprises: a first absorption tower(1) for selectively absorbing carbon dioxide from flue gas using ammonia water; a stripper(3) for stripping carbon dioxide from ammonia water containing carbon dioxide; a first circulation pump(9) for recirculating ammonia water from the stripper; a third absorption tower(6) for absorbing ammonia gas using water when the ammonia gas is contained in the stripped carbon dioxide in a very small amount; a second absorption tower(5) for removing an ammonia that is contained in a flue gas (14) from a top part of the first absorption tower in a very small amount using water, and sending ammonia-containing water to the third absorption tower; a first heat exchanger(2) for performing a heat exchanging operation between carbon dioxide-containing ammonia water from the first absorption tower and recirculated ammonia water from the stripper; a concentration tower(7) for recirculating a very small amount of ammonia-containing water to the second absorption tower while recirculating the concentrated ammonia water to the stripper by concentrating a portion of ammonia water from a bottom part of the stripper; a first reboiler(4) and a second reboiler(8) mounted on bottom parts of the stripper and the concentration tower; a second circulation pump(11) for recirculating a very small amount of ammonia-containing water discharged from the concentration tower to the second absorption tower; and a second heat exchanger(10) for performing a heat exchanging operation between water discharged from the concentration tower and carbon dioxide-containing ammonia water discharged from the first heat exchanger.
Abstract translation: 提供了一种通过使用氨水作为吸收溶液连续地回收混合气体中所含的二氧化碳而不损失氨的高纯度二氧化碳的方法和装置。 一种从含有二氧化碳的混合气体连续生产高纯度二氧化碳的设备包括：使用氨水从烟道气中选择性吸收二氧化碳的第一吸收塔（1） 用于从含有二氧化碳的氨水中汽提二氧化碳的汽提塔（3） 用于从汽提塔再循环氨水的第一循环泵（9） 第三吸收塔（6），其在非常少量的汽提二氧化碳中含有氨气时，使用水吸收氨气; 第二吸收塔（5），用于使用水从少量的第一吸收塔的顶部除去包含在烟道气（14）中的氨，并向第三吸收塔输送含氨水; 用于在来自第一吸收塔的含二氧化碳的氨水和来自汽提塔的再循环氨水之间进行热交换操作的第一热交换器（2） 浓缩塔（7），用于将非常少量的含氨水再循环到第二吸收塔，同时通过从汽提塔的底部浓缩一部分氨水将浓缩的氨水再循环到汽提塔; 第一再沸器（4）和第二再沸器（8），其安装在汽提塔和集中塔的底部; 第二循环泵（11），用于将从浓缩塔排出的非常少量的含氨水再循环到第二吸收塔; 以及用于在从浓缩塔排出的水和从第一热交换器排出的含二氧化碳的氨水之间进行热交换操作的第二热交换器（10）。
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公开(公告)号：KR100836707B1
公开(公告)日：2008-06-10
申请号：KR1020070040366
申请日：2007-04-25
Applicant: 한국에너지기술연구원 , 에스케이이노베이션 주식회사
CPC classification number: C07C7/12 , B01D3/143 , B01D53/04 , B01D2253/108 , B01D2256/24 , B01D2257/7022 , B01D2259/40086 , B01D2259/403 , C07C7/005 , C07C7/04 , C07C7/13 , C07C11/08
Abstract: A method for separating butene-1 from a mixture gas comprising a C4 olefin and a paraffin, and its apparatus are provided to reduce the loss of butene-1 in case of the removing isobutane and to lower the concentration of n-butane. A method for separating butene-1 from a mixture gas comprising C4 olefins and paraffins comprises the steps of: introducing a mixture gas comprising C4 olefins and paraffins into an adsorption tower to adsorb olefins to separate paraffins; introducing the some part of the obtained C4 olefins of high purity to wash out the adsorbed paraffins of small quantity for improving the purity of olefins; introducing a desorber to desorb C4 olefins; and distilling C4 olefins to obtain butene-1, wherein the absorption, washing and desorption are carried out continuously and repeatedly at three adsorption towers and the three adsorption towers carry out the different processes at the identical point.
Abstract translation: 提供了从包含C4烯烃和石蜡的混合气体中分离丁烯-1的方法及其装置，以减少在除去异丁烷的情况下的丁烯-1的损失并降低正丁烷的浓度。 从包含C4烯烃和石蜡的混合气体中分离丁烯-1的方法包括以下步骤：将包含C4烯烃和链烷烃的混合气体引入吸附塔中以吸附烯烃以分离石蜡; 引入部分得到的高纯度C4烯烃洗出少量的吸附石蜡，以提高烯烃的纯度; 引入解吸器解吸C4烯烃; 并蒸馏出C4烯烃，得到丁烯-1，其中吸附，洗涤和解吸在三个吸附塔连续反复进行，三个吸附塔在同一点进行不同的过程。
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