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公开(公告)号：KR1020030014988A
公开(公告)日：2003-02-20
申请号：KR1020010049024
申请日：2001-08-14
Applicant: 한국전자통신연구원
IPC: H01M12/08
CPC classification number: H01G9/016 , H01G9/02 , H01G9/038 , H01G9/155 , H01G11/06 , H01G11/50 , H01M4/381 , H01M4/602 , H01M10/4264 , H01M14/00 , H01M16/00 , H01M2300/0025 , Y02E60/13
Abstract: PURPOSE: Provided is a 3-electrode type hybrid power element having a lithium secondary battery and a supercapacitor in one cell, which has excellent performance than general lithium secondary batteries and is economical and practical and can be used for mobile communication. CONSTITUTION: The hybrid power element has the 3-electrode form by connecting a cathode(B) of the lithium secondary battery and one electrode(B) of the supercapacitor, as a common electrode, to a cathode and connecting a lithium metal anode(A) of the lithium secondary battery and the other electrode(C) of the supercapacitor to an anode. And the hybrid power element is produced by a process comprising the steps of: preparing a conductive polymer electrode(B) used as the common electrode by coating an electrode active material on both sides of a charge assembly and preparing a conductive polymer electrode(C) used as the electrode of the supercapacitor by coating an electrode active material on one side of a charge assembly; laminating the lithium metal electrode(A), a separator, the conductive polymer electrode(B), a separator, and the conductive polymer electrode(C); adding an electrolyte to the resultant; packing by using a material capable of vacuum heat packing.
Abstract translation: 目的：提供一种在一个电池中具有锂二次电池和超级电容器的3电极型混合动力元件，其具有比一般锂二次电池优异的性能，并且经济实用并且可用于移动通信。 构成：混合动力元件具有通过将锂二次电池的阴极（B）和作为公共电极的超级电容器的一个电极（B）连接到阴极并连接锂金属阳极（A ）和超级电容器的另一个电极（C）连接到阳极。 混合动力元件是通过以下工序来制造的，该方法包括以下步骤：制备用作公共电极的导电聚合物电极（B），通过在电荷组件的两侧涂覆电极活性材料并制备导电聚合物电极（C） 通过在电荷组件的一侧上涂覆电极活性材料而用作超级电容器的电极; 层叠锂金属电极（A），隔膜，导电性聚合物电极（B），隔膜和导电性聚合物电极（C）; 向所得物中加入电解质; 通过使用能够进行真空热包装的材料进行包装。
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公开(公告)号：KR100371137B1
公开(公告)日：2003-02-07
申请号：KR1019990058382
申请日：1999-12-16
Applicant: 한국전자통신연구원
IPC: C08J5/18
CPC classification number: H01B1/128 , C08J5/18 , C08J2300/12
Abstract: A method of manufacturing a conducting polymer film including dissolving a lithium salt in an organic solvent; after the lithium salt is completely dissolved in the organic solvent, dissolving a conducting polymer in the organic solvent by adding the conducting polymer little by little in many separate doses into the organic solvent until obtaining a deep blue colored solution; and leaving the deep blue colored solution as it stands over seven days and coating it on a flat surface; and evaporating the solvent from the coated solution. It is possible to work the conducting polymer film in a very thin membrane and to control the thickness as required, since the polymer film can be formed directly from a solution. Furthermore, it is also possible to control the conductivity of the polymer film by varying the type of salts as used and the concentration thereof, and thus its applicability is very diverse as the purpose of using them, for example in electronic/electric components.
Abstract translation: 一种制造导电聚合物膜的方法，包括将锂盐溶解在有机溶剂中; 在锂盐完全溶解在有机溶剂中后，通过将导电聚合物以许多不同的剂量一点一点地加入有机溶剂中，将导电聚合物溶解在有机溶剂中，直到获得深蓝色溶液; 并在七天内留下深蓝色的溶液并将其涂覆在平坦的表面上; 并从涂布的溶液中蒸发溶剂。 因为聚合物膜可以直接由溶液形成，所以可以将导电聚合物膜加工成非常薄的膜并根据需要控制厚度。 此外，还可以通过改变所使用的盐的类型及其浓度来控制聚合物膜的导电率，因此其应用性因使用它们的目的而非常多样化，例如在电子/电气部件中。
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公开(公告)号：KR1020020088245A
公开(公告)日：2002-11-27
申请号：KR1020010027458
申请日：2001-05-19
Applicant: 한국전자통신연구원
IPC: C01G31/02
CPC classification number: H01M10/052 , H01M4/136
Abstract: PURPOSE: A preparation method of VOPO4.2H2O used as a cathode material for lithium secondary batteries by ultrasonication is provided, which offers much shortened reaction time and fined particles compared with conventional method. CONSTITUTION: The preparation method of VOPO4.2H2O comprises the steps of: mixing V2O5, H3PO4 and H2O in a molar ratio of 1 : 40-50 : 500-610; ultrasonicating the mixture in a strength of 70-100W/cm¬2 for 10-15min; washing and decompression filtering; drying at room temperature. The resultant VOPO4.2H2O has 1-3micrometer size, 3.6V voltage and 135mAh/g discharge capacity. Also, the composition for a cathode material for lithium secondary batteries is prepared by mixing VOPO4.2H2O, acetylene black and polyethylene tetrachloride in a weight ratio of 60-80 : 15-25 : 5-15.
Abstract translation: 目的：提供一种通过超声波处理用作锂二次电池阴极材料的VOPO4.2H2O的制备方法，与常规方法相比，反应时间和微细颗粒缩短。 构成：VOPO4.2H2O的制备方法包括以1:40-50：500-610的摩尔比混合V2O5，H3PO4和H2O的步骤; 将混合物以70-100W / cm 2的强度超声10-15分钟; 洗涤和减压过滤; 在室温下干燥。 所得的VOPO4.2H2O具有1-3微米尺寸，3.6V电压和135mAh / g放电容量。 而且，用于锂二次电池用阴极材料的组合物是通过混合VOPO4.2H2O，乙炔黑和聚四氯乙烯，其重量比为60-80:15-25:5-15。
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公开(公告)号：KR1020020048624A
公开(公告)日：2002-06-24
申请号：KR1020000077836
申请日：2000-12-18
Applicant: 한국전자통신연구원
IPC: H01G9/22
Abstract: PURPOSE: A super capacitor for oxidation/restoration and a method of fabricating the capacitor are provided to remarkably reduce interfacial resistance and to simplify a capacitor fabrication process. CONSTITUTION: An electric active material(302) containing polyaniline doped with lithium is fabricated. The electrode active material is attached to a charge collecting layer(402) to fabricate an electrode plate. A polymer separator(501) is placed between two electrode plates and attached to the electrode plates. The electrode active material is directly coated on the charge collecting layer and dried to form the electrode plate. The polymer separator is formed of a mixture of acetone and PVDF dissolved in the acetone.
Abstract translation: 目的：提供用于氧化/还原的超级电容器和制造电容器的方法，以显着降低界面电阻并简化电容器制造工艺。 构成：制造含有掺杂有锂的聚苯胺的电活性材料（302）。 电极活性物质附着到电荷收集层（402）以制造电极板。 聚合物分离器（501）放置在两个电极板之间并附着到电极板上。 将电极活性物质直接涂覆在电荷收集层上并干燥以形成电极板。 聚合物分离器由溶解在丙酮中的丙酮和PVDF的混合物形成。
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公开(公告)号：KR1020020043945A
公开(公告)日：2002-06-12
申请号：KR1020000073385
申请日：2000-12-05
Applicant: 한국전자통신연구원
IPC: H01M10/0565 , B82Y30/00
CPC classification number: H01M10/052 , H01M10/0525 , H01M10/056 , H01M10/0565
Abstract: PURPOSE: Provided are a polyelectrolyte filled with titania having size of nanometer, having high ion conductivity and low interfacial resistance, and a method for producing the same. CONSTITUTION: The polyelectrolyte is produced by the steps of (i) dissolving a copolymer of vinylidene fluoride and hexafluoropropylene, and titania particles of nanometer size in solvent, so as to form a polymer film; and (ii) impregnating the polymer film with electrolyte solution. The solvent is acetone or tetrahydrofuran. The electrolyte solution is a mixture of lithium salt and an organic solvent. The lithium salt is at least one selected from the group consisting of LiClO4, LiBF4, LiAsF6, LiCF3SO3 and LiN(CF3SO2)2. The organic solvent is selected from the group consisting of ethylene carbonate, propylene carbonate, dimethyl carbonate, diethyl carbonate, ethylmethyl carbonate, and mixture thereof.
Abstract translation: 目的：提供一种填充有纳米尺寸，具有高离子传导性和低界面电阻的二氧化钛的聚电解质及其制造方法。 构成：通过以下步骤制备聚电解质：（i）将偏二氟乙烯和六氟丙烯的共聚物和纳米尺寸的二氧化钛颗粒溶解在溶剂中，以形成聚合物膜; 和（ii）用电解质溶液浸渍聚合物膜。 溶剂是丙酮或四氢呋喃。 电解质溶液是锂盐和有机溶剂的混合物。 锂盐是选自LiClO 4，LiBF 4，LiAsF 6，LiCF 3 SO 3和LiN（CF 3 SO 2）2中的至少一种。 有机溶剂选自碳酸亚乙酯，碳酸亚丙酯，碳酸二甲酯，碳酸二乙酯，碳酸甲乙酯及其混合物。
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Patent Agency Ranking16.发明公开
公开(公告)号：KR1020020025305A
公开(公告)日：2002-04-04
申请号：KR1020000056989
申请日：2000-09-28
Applicant: 한국전자통신연구원
IPC: H01G4/018
Abstract: PURPOSE: A method for forming polyaniline powder having lithium salt doped, and a method for preparing electrode active material and a super capacitor using it are provided to form polyaniline conductive polymer powder having lithium salt doped and prepare electrode active material and a super capacitor using the polyaniline conductive polymer powder. CONSTITUTION: First, non-conductive polyaniline powder is prepared. Then, lithium salt solution is prepared. Next, the non-conductive polyaniline powder and the lithium salt solution are mixed, whereby lithium salt is doped into the non-conductive polyaniline powder. Then, the polyaniline powder having lithium salt doped is separated from the lithium salt solution.
Abstract translation: 目的：提供一种用于形成掺杂锂盐的聚苯胺粉末的方法，以及使用该方法制备电极活性材料和超级电容器的方法，以形成掺有锂盐并制备电极活性材料的聚苯胺导电聚合物粉末和使用 聚苯胺导电聚合物粉末。 规定：首先，制备非导电聚苯胺粉末。 然后，制备锂盐溶液。 接着，将非导电性聚苯胺粉末和锂盐溶液混合，由此将锂盐掺杂到非导电性聚苯胺粉末中。 然后，将具有锂盐的聚苯胺粉末与锂盐溶液分离。
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17.发明公开캡슐화된 전해액을 포함하는 건고분자 전해질막 및 그형성 방법과 그를 이용한 리튬고분자 전지 제조 방법 失效含聚氨酯电解液的干燥聚合物电解质膜及其制备方法及使用该膜的锂聚合物电池的制备方法
公开(公告)号：KR1020020025302A
公开(公告)日：2002-04-04
申请号：KR1020000056984
申请日：2000-09-28
Applicant: 한국전자통신연구원
IPC: H01M10/05
CPC classification number: H01M10/052 , H01M10/0565
Abstract: PURPOSE: A dry polymer electrolyte membrane containing the capsulated electrolyte solution, its preparation method and a method for preparing a lithium polymer battery using the membrane are provided, to improve the ion conductivity and the mechanical properties of a polymer electrolyte by breaking a microcapsule physically to disperse the electrolyte solution inside the microcapsule into the dry polymer membrane. CONSTITUTION: The dry polymer electrolyte membrane(1A) comprises a supporter polymer; and an electrolyte storing means which is mixed with the supporter polymer and where an electrolyte solution is filled. Preferably the storing means is a capsule, and the electrolyte solution is an electrolyte solution containing a lithium salt. The preparation method of the electrolyte membrane comprises the steps of preparing the electrolyte storing means filled with an electrolyte solution; mixing an organic solvent with a supporter polymer to form the polymer slurry; distributing the storing means inside the polymer slurry; spreading the polymer slurry to form a storing means-dispersed polymer electrolyte; and volatilizing the organic solvent in the polymer electrolyte to prepare a dry polymer electrolyte membrane(1A).
Abstract translation: 目的：提供一种含有封装的电解质溶液的干燥聚合物电解质膜及其制备方法和使用该膜制备锂聚合物电池的方法，通过将微胶囊物理地破坏而提高聚合物电解质的离子传导性和机械性能 将微胶囊内的电解质溶液分散到干燥的聚合物膜中。 构成：干燥聚合物电解质膜（1A）包含支持聚合物; 以及电解质储存装置，其与所述载体聚合物混合并且其中填充有电解质溶液。 优选地，存储装置是胶囊，电解质溶液是含有锂盐的电解液。 电解质膜的制备方法包括以下步骤：制备填充有电解质溶液的电解液储存装置; 将有机溶剂与载体聚合物混合以形成聚合物浆料; 将储存装置分配在聚合物浆料内; 铺展聚合物浆液形成储存装置分散的聚合物电解质; 并使聚合物电解质中的有机溶剂挥发，制备干式聚合物电解质膜（1A）。
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公开(公告)号：KR1019990051074A
公开(公告)日：1999-07-05
申请号：KR1019970070313
申请日：1997-12-19
Applicant: 한국전자통신연구원
IPC: H01M10/05
Abstract: 본 발명은 리튬 고분자 전지에 관한 것으로 특히 고분자 전극을 이용한 리튬 2차전지에 관한 것이다. 종래에는 전도성고분자 중 폴리아닐린이 전도도를 가지게 하기 위해 양성자 산으로 도핑을 하는 방법을 이용하였다. 상기의 양성자 산에 의해 도핑한 폴리아닐린을 양전극으로 사용하여 리튬 2차전지를 구성하면 도핑된 양성자들이 전지 반응에 참여하여 전지에 좋지 않은 영향을 주어 전지의 성능 저하를 가져왔다. 따라서 본 발명에서는 양성자 산에 의한 도핑을 하지 않고 전지구성 시 사용하는 염이 녹아있는 전해질로 도핑을 한 전도성고분자를 양전극으로 사용하여 리튬 2차전지를 구성하면, 상기의 단점을 개선 할 수 있어 전지의 성능이 개선되며, 무기물 전극을 사용하였을 때 보다 전지의 모양도 자유롭고 무게도 가벼운 전지의 제작이 가능할 것이다.
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公开(公告)号：KR1019990051072A
公开(公告)日：1999-07-05
申请号：KR1019970070311
申请日：1997-12-19
Applicant: 한국전자통신연구원
IPC: H01M2/02
Abstract: 본 발명은 리튬 고분자 전지에 있어서 양전극 물질과 음전극 물질 및 고분자 전해질을 기본 물질로하여 적층하거나 접는 방법을 이용하여 구성하는 전지의 제작에 있어서 양전극과 음전극의 탭을 손쉽게 부착하고 급속 충전 및 방전이 가능하게 하는 전극 탭 부착 방법에 관한 것이다. 종래의 리튬 고분자전지는 양전극 및 음전극의 한쪽 끝에 일자형으로 탭을 부착하기 때문에 공정이 복잡하고 탭의 형태도 전극 양쪽 종단에 고착되고 그 용착면적도 적어 기계적으로 약하며 전지의 급속 충방전에 약한 단점이 있다. 본 발명에서는 종래의 적층형 전지의 탭 공정 중 한쪽 끝에서 작은 면적만을 접촉 시켜 적층하는 기존의 탭 방법과는 달리 단위 전지와 단위 전지를 용량에 맞도록 먼저 적층한 후 전지의 탭 부착 위치인 금속 망 부분(집전체 부분)을 탭 금속으로 한바퀴 돌리고 접어 초음파 용착기를 사용하여 한번에 용착하여 탭을 만드는 방법을 제안한 것이며, 또한 이러한 방법은 접는 형태의 전지에서도 동일하게 적용할 수 있다. 이에따라 단위 셀과 단위 셀의 접촉 면적은 물론 전극과 탭의 접촉 면적을 넓게하므로 급속 충전 및 방전에도 효과적인 방법을 제안한 것이다.
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