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公开(公告)号：WO2017048096A1
公开(公告)日：2017-03-23
申请号：PCT/KR2016/010412
申请日：2016-09-19
Applicant: 한국화학연구원
IPC: H01M10/42 , H01M2/02 , H01M2/16 , H01M10/052 , H01M2/10 , H01M10/0567 , H01M4/62 , B01J20/22
CPC classification number: B01J20/22 , H01M2/02 , H01M2/10 , H01M2/16 , H01M4/62 , H01M10/052 , H01M10/0567 , H01M10/42
Abstract: 본 발명은 양극, 음극, 상기 양극과 음극 사이에 개재되는 분리막을 포함하는 전극조립체가 전해액과 함께 전지케이스의 내부에 내장되어 있는 이차전지로서, 상기 양극, 음극, 분리막, 전해액 및 전지 케이스 내부로 이루어진 군으로부터 선택되는 하나 이상의 부위에 수분 흡착제로, 흡착된 수분의 흡착 총량의 70% 이상의 탈착이 150℃ 이하에서 이루어져 재생이 가능한 제1 유무기 하이브리드 나노세공체(organic-inorganic hybrid nanoporous materials); 및 선택적으로 상대 습도 p/p 0 가 0.3 이하일 때, 수분 흡착능이 수분 탈착능보다 더 큰 제2 유무기 하이브리드 나노세공체(이 때 p 0 는 적용 온도에서의 포화 증기압, p는 흡착 시의 증기압을 나타냄)를 포함하는 것이 특징인 이차전지를 제공한다.
Abstract translation: 本发明是一种二次电池，其中包括阳极，阴极和设置在阳极和阴极之间的分离膜和电解质的电极组件一起包含在电池壳体内，二次电池包括作为水吸附剂， 在从由阳极，阴极，分离膜，电解质和电池壳体内部选择的组中的至少一个区域中：第一有机 - 无机杂化纳米多孔材料，其允许至少70％的总量 在150℃以下脱附的吸附水分量可再生; 以及任选的第二有机 - 无机混合纳米多孔材料，当相对湿度（p / p0）为0.3或更低时（p0表示在施加温度下的饱和蒸气压，p表示蒸气）时，其表现出比湿气解吸能力更大的吸湿能力 吸附时的压力）。
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公开(公告)号：KR102226797B1
公开(公告)日：2021-03-10
申请号：KR1020190019849
申请日：2019-02-20
Applicant: 한국화학연구원
Abstract: 본발명의목적은고온에서의질소산화물저감능력이우수한 CO-SCR 촉매를제공하는데목적이있다. 또한, 귀금속계활성상을사용하지않고도질소산화물저감능력이뛰어나비용절감의효과가있는 CO-SCR 촉매를제공하는데그 목적이있다. 본발명에따른고온에서의질소산화물저감성능이향상된 deNOx 촉매는배기가스내 일산화탄소(CO)를환원제로하여질소산화물(NOx)을환원시키는촉매로서, 바륨(Ba)이담지된지지체를포함하는것을특징으로한다.
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公开(公告)号：KR1020170124866A
公开(公告)日：2017-11-13
申请号：KR1020160054831
申请日：2016-05-03
Applicant: 한국화학연구원
IPC: B01J31/16 , C07D307/32 , C07D307/44
CPC classification number: B01J27/20 , B01J31/26 , B01J35/002 , B01J35/1023 , B01J35/1028 , B01J35/1047 , B01J37/036 , B01J37/06 , B01J31/1691 , C07D307/32 , C07D307/44
Abstract: 본발명은 MOF-808계열의 X-선회절패턴을갖는유기금속골격체로이루어진, 이동수소화반응용촉매에관한것이다. 높은결정성다공질 MOF-808계열의유기금속골격체는고온및 저온에서 EL의이동수소화반응에서우수한성능을발휘한다.
Abstract translation: 本发明涉及一种具有的MOF-808系列，移动加氢催化剂的X射线衍射图案的有机金属骨架构成的主体。 高度结晶的有机MOF-808有机金属骨架在高温和低温下EL的移动氢化中表现出优异的性能。
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公开(公告)号：KR1020170034103A
公开(公告)日：2017-03-28
申请号：KR1020150132364
申请日：2015-09-18
Applicant: 한국화학연구원
IPC: H01M10/42 , H01M2/02 , H01M2/16 , H01M10/052 , H01M2/10 , H01M10/0567 , H01M4/62 , B01J20/22
CPC classification number: B01J20/22 , H01M2/02 , H01M2/10 , H01M2/16 , H01M4/62 , H01M10/052 , H01M10/0567 , H01M10/42
Abstract: 본발명은양극, 음극, 상기양극과음극사이에개재되는분리막을포함하는전극조립체가전해액과함께전지케이스의내부에내장되어있는이차전지로서, 상기양극, 음극, 분리막, 전해액및 전지케이스내부로이루어진군으로부터선택되는하나이상의부위에수분흡착제로, 흡착된수분의흡착총량의 80% 이상의탈착이 150℃이하에서이루어져재생이가능한제1 유무기하이브리드나노세공체(organic-inorganic hybrid nanoporous materials); 및선택적으로상대습도 p/p가 0.3 이하일때, 수분흡착능이수분탈착능보다더 큰제2 유무기하이브리드나노세공체(이때 p는적용온도에서의포화증기압, p는흡착시의증기압을나타냄)를포함하는것이특징인이차전지를제공한다.
Abstract translation: 本发明是一种正电极，负电极，即与包含在正电极和负电极为正电极，负电极，隔膜，电解质和电池壳体之间的隔膜的电解质嵌入在电池壳的内部中的电极组件一起可再充电电池 在至少一个部位的吸湿剂选自选择吸收混合纳米多孔材料（有机 - 无机杂化纳米多孔材料）的第一有机 - 无机在于以下150℃80％或吸附水的总量的多个可释放的再现; 和，任选地，P /相对湿度。当p是0.3或更小，吸水能力是更keunje第二有机 - 无机杂化纳米多孔体比的水分解吸性能包括（eseoui其中p是温度的蒸气压，p表示在吸附时的蒸气压） 其特征在于提供二次电池。
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公开(公告)号：KR1020160145241A
公开(公告)日：2016-12-20
申请号：KR1020150081326
申请日：2015-06-09
Applicant: 한국화학연구원
IPC: B01D53/14 , C23C16/455
CPC classification number: Y02C10/06
Abstract: 본발명은 1 사이클이상의원자층증착법(atomic layer deposition)에의해, 알칼리금속염을포함하는이산화탄소건식흡수제입자의표면상에알루미늄산화물층을형성시킨것이특징인이산화탄소건식흡수제; 및이의활용에관한것이다. 본발명에따른이산화탄소건식흡수제는 300℃이상의중·고온영역에서이산화탄소건식흡수제입자내 함유되어있는알칼리금속염간의반응이억제되어이산화탄소건식흡수제입자간 응집, 즉뭉침현상이방지또는감소되면서이산화탄소건식흡수제입자의물리적인변형은억제되고이산화탄소흡수능은발휘할수 있다.
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Patent Agency Ranking
公开(公告)号：KR101648341B1
公开(公告)日：2016-08-16
申请号：KR1020140052790
申请日：2014-04-30
Applicant: 한국화학연구원
Abstract: 본발명은, Ni 전구체화합물, Cu 전구체화합물및 SiO로부터졸겔법에의해 NiO-CuO/SiO나노복합체촉매를제조하고, 제조된촉매의존재하에글리세롤의수소첨가분해반응에의해프로필렌글리콜을제조하는반응을제공한다. 본발명에따른촉매를사용하면, 10 이하의낮은수소/글리세롤비율에서도높은글리세롤전환율및 높은프로필렌글리콜선택성을달성할수 있을뿐만아니라장시간동안프로필렌글리콜을고수율로생산할수 있다.
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17.发明公开
公开(公告)号：KR1020160068552A
公开(公告)日：2016-06-15
申请号：KR1020140174430
申请日：2014-12-05
Applicant: 한국화학연구원
CPC classification number: B01D53/22 , B01D53/228 , B01D67/0079 , B01D69/02 , B01D69/148 , B01D2053/221 , B01D2256/10 , B01D2256/12 , B01D2256/16 , B01D2256/22 , B01D2256/245 , B01D2257/102 , B01D2257/104 , B01D2257/108 , B01D2257/2047 , B01D2257/30 , B01D2257/504 , B01J20/226 , B01J20/262 , B01J20/28033 , Y02C10/10 , B01D69/00 , B01D71/00
Abstract: 본발명은하이브리드나노세공체를포함하는기체분리또는농축용고분자분리막, 이의용도및 이의제조방법에관한것으로, 더욱상세하게는하이브리드나노세공체를포함하는기체분리또는농축용고분자분리막으로서상기하이브리드나노세공체의윈도우(window)의크기가 4 내지 15 Å이거나상기하이브리드나노세공체의흡착능력이상이하도록조절되어기체투과선택성이개선된고분자분리막, 이의용도및 이의제조방법에관한것이다.
Abstract translation: 本发明涉及一种用于浓缩或分离含有杂化纳米多孔材料的气体的聚合物分离膜及其制备方法及其制备方法。 更具体地说，本发明涉及一种用于分离或浓缩气体并含有杂化纳米多孔材料的聚合物分离膜，其中杂化纳米多孔材料的尺寸为4〜15，混合纳米多孔材料的吸附能力为 调整为不同，从而具有改善的气体选择性。 本发明还涉及其用途及其制备方法。
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公开(公告)号：KR1020090011999A
公开(公告)日：2009-02-02
申请号：KR1020070077335
申请日：2007-08-01
Applicant: 한국화학연구원
CPC classification number: Y02A50/235
Abstract: An adsorber containing porosity organic/inorganic hybrid is provided to remove impurities of organic/inorganic mixture nanoporous materials and to increase surface area the organic/inorganic mixture nanoporous materials by processing it using ammonium chloride or potassium fluoride. An adsorber containing porosity organic/inorganic hybrid comprises steps of: mixing metal precursor, organic compound acting on ligand, acid and solvent and manufacturing a reactant mixed solution; irradiating microwave to the reactant mixed solution over 100°C; processing the porosity organic/inorganic hybrid using an inorganic salt or solvent. The acid is inorganic acid except for hydrofluoric acid.
Abstract translation: 提供含有孔隙有机/无机杂化物的吸附剂，以除去有机/无机混合物纳米多孔材料的杂质，并通过使用氯化铵或氟化钾处理有机/无机混合物纳米多孔材料来增加表面积。 含有孔隙性有机/无机杂化物的吸附剂包括以下步骤：混合金属前体，作用于配体，酸和溶剂的有机化合物，制备反应物混合溶液; 在100℃下向反应混合溶液中照射微波; 使用无机盐或溶剂处理孔隙有机/无机混合物。 酸是除氢氟酸以外的无机酸。
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19.发明公开
公开(公告)号：KR1020080114380A
公开(公告)日：2008-12-31
申请号：KR1020070063881
申请日：2007-06-27
Applicant: 한국화학연구원
Abstract: A manufacturing method of porosity organic and inorganic hybrid is provided to manufacture and refine porosity organic and inorganic hybrid by an eco-friendly method using a new manufacturing process which does not use a hydrofluoric acid at all. A manufacturing method of porosity organic and inorganic hybrid comprises steps of: 1) manufacturing the reactant mixed solution by mixing a metal precursor, an organic compound acting on a ligand, an acid and a solvent; 2) heating the reactant mixed solution over 100‹C by electric heating or irradiating a microwave; 3) refining the porosity organic and inorganic hybrid by processing obtained the porosity organic and inorganic hybrid in the step 2) as inorganic salts.
Abstract translation: 提供孔隙有机和无机混合物的制造方法，通过使用不使用氢氟酸的新制造方法的环保方法来制造和精制孔隙有机和无机杂化物。 孔隙有机和无机杂化物的制造方法包括以下步骤：1）通过混合金属前体，作用于配体的有机化合物，酸和溶剂来制备反应混合溶液; 2）通过电加热或照射微波将反应物混合溶液加热至100℃以上; 3）通过加工精制孔隙有机和无机杂化物，得到在步骤2）中的无机杂化物作为无机盐。
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20.发明授权
公开(公告)号：KR100864313B1
公开(公告)日：2008-10-20
申请号：KR1020070049415
申请日：2007-05-21
Applicant: 한국화학연구원
CPC classification number: B01J31/1691 , B01J31/069 , B01J2531/18 , B01J2531/824
Abstract: A preparation method of surface functionalized porous organic-inorganic hybrid materials that can be used in adsorbents, gas storage bodies, sensors, membranes, functional thin films, catalysts, and catalyst carriers is provided, and a catalyst composition for an acid or base reaction, hydrogenation, dehydrogeneration, a carbon-carbon bonding reaction, or an oxidation reaction by using the surface functionalized porous organic-inorganic hybrid materials or porous organic-inorganic mesoporous materials is provided. A preparation method of surface modified porous organic-inorganic hybrid materials is characterized in that the surface modified porous organic-inorganic hybrid materials are prepared by bonding organic materials, polyoxometalates, ionic liquids, organometallic compounds, or mixtures thereof having functional groups selected from an amino group(-NH2), a thiol group(-SH) and a phosphoric group(-PO(OH)2) to porous organic-inorganic hybrid materials with coordinatively unsaturated metal sites or to coordinatively unsaturated metal sites of porous organic-inorganic mesoporous materials. The porous organic-inorganic hybrid materials are polymer compounds formed by bonding core metal ions to organic ligands and have molecular-sized or mamo-sized pore structures, and the porous organic-inorganic mesoporous materials have coordinatively unsaturated metal sites and pores with a pore size of 2 to 50 nm by substituting dissimilar metals. Core metal precursors of the porous organic-inorganic hybrid materials are one or more metals selected from Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Mn, Re, Fe, Ru, Os, Co, Rh, Ir, Ni, Pd, Pt, Cu, Ag, Au, Zn, Cd, Hg, Mg, Ca, Sr, Ba, Sc, Y, Al, Ga, In, Tl, Si, Ge, Sn, Pb, As, Sb and Bi, or compounds thereof.
Abstract translation: 提供了可用于吸附剂，储气体，传感器，膜，功能薄膜，催化剂和催化剂载体的表面官能化多孔有机 - 无机混合材料的制备方法，以及用于酸或碱反应的催化剂组合物， 提供氢化，脱氢生成，碳 - 碳键合反应或通过使用表面官能化的多孔有机 - 无机杂化材料或多孔有机 - 无机介孔材料的氧化反应。 表面改性多孔有机 - 无机杂化材料的制备方法的特征在于表面改性的多孔有机 - 无机杂化材料是通过键合具有选自以下的官能团的有机材料，多金属氧酸盐，离子液体，有机金属化合物或其混合物制备的： 基团（-NH 2），硫醇基（-SH）和磷酸基（-PO（OH）2）与具有配位不饱和金属位点的多孔有机 - 无机杂化材料或多孔有机 - 无机介孔材料的配位不饱和金属部位 。 多孔有机 - 无机杂化材料是通过将核心金属离子与有机配体键合而形成的聚合物化合物，并且具有分子尺寸或mamo尺寸的孔结构，并且多孔有机 - 无机介孔材料具有配位不饱和金属部位和孔径 通过取代异种金属2〜50nm。 多孔有机 - 无机杂化材料的核心金属前体是选自Ti，Zr，Hf，V，Nb，Ta，Cr，Mo，W，Mn，Re，Fe，Ru，Os，Co，Rh中的一种或多种金属， Ir，Ni，Pd，Pt，Cu，Ag，Au，Zn，Cd，Hg，Mg，Ca，Sr，Ba，Sc，Y，Al，Ga，In，Tl，Si，Ge，Sn，Pb， Sb和Bi，或其化合物。
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