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1.发明授权
公开(公告)号：KR100895413B1
公开(公告)日：2009-05-07
申请号：KR1020070063881
申请日：2007-06-27
Applicant: 한국화학연구원
Abstract: 본 발명은 다공성 유무기혼성체 (porous organic inorganic hybrid materials)의 신규 제조방법으로서, 수득되는 다공성 유무기혼성체를 무기염으로 처리하여 정제하는 단계를 포함하며, 특히, 불산을 사용하지 않는 것을 특징으로 하는 제조 방법, 상기 제조 방법에 의하여 제조된 다공성 유무기혼성체 및 이의 촉매적 용도에 관한 것으로서, 상기 다공성 유무기혼성체는 높은 표면적과 분자크기 또는 나노크기의 세공을 갖고 있어 흡착제, 기체 저장, 센서, 멤브레인, 기능성 박막, 촉매 및 촉매 담체 등에 사용될 수 있으며 세공크기보다 작은 게스트 분자를 포집하거나 세공크기를 이용하여 분자들을 분리하는데 사용될 수 있다.
유무기혼성체, 수열합성, 나노입자, 세공물질, 촉매, 마이크로파 합성-
2.发明公开
公开(公告)号：KR1020080114380A
公开(公告)日：2008-12-31
申请号：KR1020070063881
申请日：2007-06-27
Applicant: 한국화학연구원
Abstract: A manufacturing method of porosity organic and inorganic hybrid is provided to manufacture and refine porosity organic and inorganic hybrid by an eco-friendly method using a new manufacturing process which does not use a hydrofluoric acid at all. A manufacturing method of porosity organic and inorganic hybrid comprises steps of: 1) manufacturing the reactant mixed solution by mixing a metal precursor, an organic compound acting on a ligand, an acid and a solvent; 2) heating the reactant mixed solution over 100‹C by electric heating or irradiating a microwave; 3) refining the porosity organic and inorganic hybrid by processing obtained the porosity organic and inorganic hybrid in the step 2) as inorganic salts.
Abstract translation: 提供孔隙有机和无机混合物的制造方法，通过使用不使用氢氟酸的新制造方法的环保方法来制造和精制孔隙有机和无机杂化物。 孔隙有机和无机杂化物的制造方法包括以下步骤：1）通过混合金属前体，作用于配体的有机化合物，酸和溶剂来制备反应混合溶液; 2）通过电加热或照射微波将反应物混合溶液加热至100℃以上; 3）通过加工精制孔隙有机和无机杂化物，得到在步骤2）中的无机杂化物作为无机盐。
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3.发明授权
公开(公告)号：KR100864313B1
公开(公告)日：2008-10-20
申请号：KR1020070049415
申请日：2007-05-21
Applicant: 한국화학연구원
CPC classification number: B01J31/1691 , B01J31/069 , B01J2531/18 , B01J2531/824
Abstract: A preparation method of surface functionalized porous organic-inorganic hybrid materials that can be used in adsorbents, gas storage bodies, sensors, membranes, functional thin films, catalysts, and catalyst carriers is provided, and a catalyst composition for an acid or base reaction, hydrogenation, dehydrogeneration, a carbon-carbon bonding reaction, or an oxidation reaction by using the surface functionalized porous organic-inorganic hybrid materials or porous organic-inorganic mesoporous materials is provided. A preparation method of surface modified porous organic-inorganic hybrid materials is characterized in that the surface modified porous organic-inorganic hybrid materials are prepared by bonding organic materials, polyoxometalates, ionic liquids, organometallic compounds, or mixtures thereof having functional groups selected from an amino group(-NH2), a thiol group(-SH) and a phosphoric group(-PO(OH)2) to porous organic-inorganic hybrid materials with coordinatively unsaturated metal sites or to coordinatively unsaturated metal sites of porous organic-inorganic mesoporous materials. The porous organic-inorganic hybrid materials are polymer compounds formed by bonding core metal ions to organic ligands and have molecular-sized or mamo-sized pore structures, and the porous organic-inorganic mesoporous materials have coordinatively unsaturated metal sites and pores with a pore size of 2 to 50 nm by substituting dissimilar metals. Core metal precursors of the porous organic-inorganic hybrid materials are one or more metals selected from Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Mn, Re, Fe, Ru, Os, Co, Rh, Ir, Ni, Pd, Pt, Cu, Ag, Au, Zn, Cd, Hg, Mg, Ca, Sr, Ba, Sc, Y, Al, Ga, In, Tl, Si, Ge, Sn, Pb, As, Sb and Bi, or compounds thereof.
Abstract translation: 提供了可用于吸附剂，储气体，传感器，膜，功能薄膜，催化剂和催化剂载体的表面官能化多孔有机 - 无机混合材料的制备方法，以及用于酸或碱反应的催化剂组合物， 提供氢化，脱氢生成，碳 - 碳键合反应或通过使用表面官能化的多孔有机 - 无机杂化材料或多孔有机 - 无机介孔材料的氧化反应。 表面改性多孔有机 - 无机杂化材料的制备方法的特征在于表面改性的多孔有机 - 无机杂化材料是通过键合具有选自以下的官能团的有机材料，多金属氧酸盐，离子液体，有机金属化合物或其混合物制备的： 基团（-NH 2），硫醇基（-SH）和磷酸基（-PO（OH）2）与具有配位不饱和金属位点的多孔有机 - 无机杂化材料或多孔有机 - 无机介孔材料的配位不饱和金属部位 。 多孔有机 - 无机杂化材料是通过将核心金属离子与有机配体键合而形成的聚合物化合物，并且具有分子尺寸或mamo尺寸的孔结构，并且多孔有机 - 无机介孔材料具有配位不饱和金属部位和孔径 通过取代异种金属2〜50nm。 多孔有机 - 无机杂化材料的核心金属前体是选自Ti，Zr，Hf，V，Nb，Ta，Cr，Mo，W，Mn，Re，Fe，Ru，Os，Co，Rh中的一种或多种金属， Ir，Ni，Pd，Pt，Cu，Ag，Au，Zn，Cd，Hg，Mg，Ca，Sr，Ba，Sc，Y，Al，Ga，In，Tl，Si，Ge，Sn，Pb， Sb和Bi，或其化合物。
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