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公开(公告)号:WO2020104873A1
公开(公告)日:2020-05-28
申请号:PCT/IB2019/059351
申请日:2019-10-31
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: KLUN, Thomas P. , POKORNY, Richard J. , AMB, Chad M. , COONCE, Benjamin R. , WU, Tianyu , CHAKRABORTY, Saswata , LU, Yongshang , MAC MURRAY, Benjamin C. , CLOUGH, Robert S. , ABUELYAMAN, Ahmed S. , RIEDESEL, John M.
Abstract: In one embodiment, an orthodontic article is described comprising the reaction product of a polymerizable composition comprising: a) 30-70 parts by weight of monofunctional (meth)acrylate monomer, wherein a cured homopolymer of at least one monofunctional (meth)acrylate monomer has a Tg of at least 30, 35, 40, 45, 50, 55, or 60°C; and b) urethane (meth)acrylate polymer comprising polymerized units of an aliphatic polyester diol. Also described are polymerizable compositions, as well as methods and systems for making an article utilizing 3D printing.
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公开(公告)号:WO2019239271A1
公开(公告)日:2019-12-19
申请号:PCT/IB2019/054778
申请日:2019-06-07
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: AMBUR, Gregg A. , SONNEK, Benjamin G. , ETTER, Jo A. , WONG, Timothy L. , KLUN, Thomas P. , POKORNY, Richard J. , COONCE, Benjamin R. , DUNN, Douglas S. , KOSTALIK, Henry A., IV , DEGRAW, Christopher S. , JACOBSON, John R. , ZHANG, Chunjie , WU, Jung-Sheng
Abstract: An optical assembly including an optical element insert molded directly onto an optical stack is provided. The optical stack includes an optical film and may include a liner with the optical film being disposed between the optical element and the liner. The liner, if included, is removable from the optical film without substantial damage to the optical film. An outermost layer of the optical film may be diffusion bonded to a major surface of the optical element. The optical film includes a protective coating having an average thickness of no more than 30 micrometers. The protective coating includes an at least partially cured composition. The composition includes 70 to 96 weight percent of urethane (meth)acrylate compound having an average (meth)acrylate functionality of 2 to 9.5, and 2 to 20 weight percent of (meth)acrylate monomer having a (meth)acrylate functionality of 1 to 2.
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13.
公开(公告)号:WO2019104079A1
公开(公告)日:2019-05-31
申请号:PCT/US2018/062085
申请日:2018-11-20
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: CHAKRABORTY, Saswata , MAC MURRAY, Benjamin C. , NELSON, Eric W. , KLUN, Thomas P. , POKORNY, Richard J. , MAHONEY, Wayne , AMB, Chad M. , GRIESGRABER, George W. , REED, Dana R. , ABUELYAMAN, Ahmed S. , WU, Tianyu , CLOUGH, Robert S. , COONCE, Benjamin R.
Abstract: An orthodontic article is described comprising the reaction product of a free-radically polymerizable resin; a first free-radical photoinitiator having sufficient absorbance at a first wavelength range; and a second free-radical initiator selected from a second photoinitiator having sufficient absorbance at a second wavelength range, wherein the second wavelength range is different than the first wavelength range, or a thermal free-radical initiator. In some embodiments, a 1 g/liter acetonitrile solution, at a pathlength of 1 cm, has an absorbance of greater than 0.01, 0.02, 0.03, 0.04, 0.05, 0.06, 0.07, 0.08, 0.09, or 0.10 at a wavelength of the first wavelength range when measured with a spectrophotometer. In some embodiments, the first free-radical photoinitiator exhibits a maximum absorbance at a wavelength of the range of 370-380 nm or 320-330 nm and/or comprises photoinitiator groups selected from acyl phosphine oxide or alkyl amine acetophenone. Also described are photopolymerizable compositions and methods.
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公开(公告)号:WO2019104072A1
公开(公告)日:2019-05-31
申请号:PCT/US2018/062074
申请日:2018-11-20
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: CHAKRABORTY, Saswata , MAC MURRAY, Benjamin C. , NELSON, Eric W. , KLUN, Thomas P. , POKORNY, Richard J. , MAHONEY, Wayne , AMB, Chad M. , GRIESGRABER, George W. , REED, Dana R. , ABUELYAMAN, Ahmed S. , WU, Tianyu , CLOUGH, Robert S. , COONCE, Benjamin R.
Abstract: An orthodontic article is described comprising a cured composition comprising the reaction product of free-radically polymerizable resin comprising at least one monomer, oligomer and/or polymer, comprising at least two (meth)acryl moieties; a monofunctional reactive diluent; and a polymer or macromolecule comprising a free-radical photoinitiator group. The polymer or macromolecule has a molecular weight of at least 500 g/mole. In one embodiment, the cured composition comprises a first and second photoinitiator wherein at least one is a polymer or macromolecule. Also described are photopolymerizable compositions and methods.
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公开(公告)号:WO2019003056A1
公开(公告)日:2019-01-03
申请号:PCT/IB2018/054547
申请日:2018-06-20
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: FREY, Matthew H. , CREIGHTON, Megan A. , PRIOLO, Morgan A. , COONCE, Benjamin R.
Abstract: Article (9,19) comprising a substrate (10, 20) comprising a polymer and having first (11,21) and second (12, 22) opposed major surfaces. The first major surface (11, 21) has first surface regions (13, 23) with first nanoparticles (14a, 14b, 14c, 14d, 24a, 24b, 24c, 24d) partially embedded into the first major surface (11, 21), and one of • (a) second surface regions (15) free of nanoparticles; or • (b) second surface regions (25) with at least second nanoparticles (28) on the first major surface (11, 21) or partially embedded into the first major surface (11, 21). The first surface regions (13, 23) have a first average surface roughness, R a1 , of at least 20 nm, wherein the second surface regions (15, 25) have a second average surface roughness, R a2 , of less than 100 nm, wherein the first average surface roughness, R a1 , is greater than the second average surface roughness, R a2 , and wherein there is an absolute difference between the first and second average surface roughness of at least 10 nm.
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公开(公告)号:WO2018147935A3
公开(公告)日:2018-08-16
申请号:PCT/US2017/066084
申请日:2017-12-13
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: KLUN, Thomas P. , POKORNY, Richard J. , COONCE, Benjamin R. , DUNN, Douglas S. , AMBUR, Gregg A. , KOSTALIK, Henry A., IV , JACOBSON, John R. , DEGRAW, Christopher S. , ZHANG, Chunjie
IPC: B32B27/40 , B32B27/26 , B32B27/30 , B32B27/36 , C09J175/16 , C08L53/00 , C08L75/04 , C08L83/04 , C09J7/38 , C09J7/30
Abstract: A method of making an infrared-reflecting optically transparent assembly comprises: coating a curable composition onto a major surface of an optically transparent thermoplastic polymer film; at least partially curing the curable composition, which may be optionally at least partially dried, to provide a thermoformable composite film; and laminating the thermoformable composite film to an infrared-reflecting multilayer optical film to provide the infrared-reflecting optically transparent assembly. The curable composition comprises urethane (meth)acrylate compound, (meth)acrylate monomer, and silicone (meth)acrylate. The infrared-reflecting optically transparent assembly and methods of including it in an infrared-reflecting lens assembly are also disclosed.
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公开(公告)号:WO2022118289A1
公开(公告)日:2022-06-09
申请号:PCT/IB2021/061334
申请日:2021-12-03
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: LAGUDU, Uma Rames Krishna , COONCE, Benjamin R. , PRIOLO, Morgan A. , KOLB, William Blake , NELSON, Eric W.
IPC: C09J7/20 , C09J7/29 , C09J133/10 , C09D5/20
Abstract: The present disclosure provides laminates, which include adhesive materials and methods that allow for the removal of contaminants, e.g. particulate contaminants, from a substrate surface. In one embodiment, the laminates include (i) a substrate with contaminant disposed on its surface, (ii) a liquid, adhesive precursor and (iii) a film layer. The liquid, adhesive precursor is disposed between the substrate and the film layer. In another embodiment, the laminates include (i) a substrate with contaminant disposed on its surface, (ii) a cured adhesive layer and (iii) a film layer. The cured adhesive layer is disposed between the substrate and the film layer. The laminates may be used to remove contaminant from the substrate surface by removal of the film layer and the cured adhesive layer, which entraps the contaminant therein.
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公开(公告)号:WO2020058815A1
公开(公告)日:2020-03-26
申请号:PCT/IB2019/057719
申请日:2019-09-12
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: SHAH, Saagar A. , PEKUROVSKY, Mikhail L. , MAHAJAN, Ankit , PEKUROVSKY, Lyudmila A. , CHIU, Jessica , LARSEN, Jeremy K. , MEYERS, Kara A. , GOEDDEL, Teresa M. , METZLER, Thomas J. , KEMLING, Jonathan W. , POKORNY, Richard J. , COONCE, Benjamin R. , AMB, Chad M. , KLUN, Thomas P.
IPC: H01L23/538 , H01L23/498 , H01L23/50
Abstract: Flexible devices including conductive traces with enhanced stretchability, and methods of making and using the same are provided. The circuit die is disposed on a flexible substrate. Electrically conductive traces are formed in channels on the flexible substrate to electrically contact with contact pads of the circuit die. A first polymer liquid flows in the channels to cover a free surface of the traces. The circuit die can also be surrounded by a curing product of a second polymer liquid.
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公开(公告)号:WO2020005411A1
公开(公告)日:2020-01-02
申请号:PCT/US2019/033241
申请日:2019-05-21
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: KLUN, Thomas P. , PARKAR, Zeba , RIEDESEL, John M. , POKORNY, Richard J. , AMB, Chad M. , COONCE, Benjamin R. , CLOUGH, Robert S. , WU, Tianyu , CHAKRABORTY, Saswata , LU, Yongshang , MAC MURRAY, Benjamin C. , DAILEY, Ian , OLSON, David B.
IPC: A61K6/083 , A61K6/09 , A61C7/08 , B29C64/124
Abstract: The present disclosure provides a photopolymerizable composition. The photopolymerizable composition includes a) 40-60 parts by weight of a monofunctional (meth)acrylate monomer, per 100 parts of the total photopolymerizable composition; b) a photoinitiator; and c) a polymerization reaction product of components. A cured homopolymer of the monofunctional (meth)acrylate monomer has a glass transition temperature of 125 degrees Celsius or greater. The polymerization reaction product of components includes i) a diisocyanate; ii) a hydroxy functional methacrylate; iii) a polycarbonate diol; and iv) a catalyst. The polymerization reaction product includes a polyurethane methacrylate polymer. Often, the polycarbonate diol has a number average molecular weight of greater than 1,000 grams per mole (g/mol) or a weighted average of all polycarbonate diols present in the components has a Mn of greater than 1,000 g/mol; alternatively, the polyurethane methacrylate polymer has a weight average molecular weight of 8,000 g/mol or greater. An article is also provided including the photopolymerizable composition reaction product. Further, the present disclosure provides articles and methods of making articles. Methods are additionally provided, including receiving, by a manufacturing device having one or more processors, a digital object comprising data specifying an article; and generating, with the manufacturing device by an additive manufacturing process, the article based on the digital object. A system is also provided, including a display that displays a 3D model of an article; and one or more processors that, in response to the 3D model selected by a user, cause a 3D printer to create a physical object of an article.
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20.
公开(公告)号:WO2020003197A3
公开(公告)日:2020-01-02
申请号:PCT/IB2019/055455
申请日:2019-06-27
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: KLUN, Thomas P. , PARKAR, Zeba , RIEDESEL, John M. , POKORNY, Richard J. , AMB, Chad M. , COONCE, Benjamin R. , CLOUGH, Robert S. , WU, Tianyu , CHAKRABORTY, Saswata , LU, Yongshang , MAC MURRAY, Benjamin C. , ABUELYAMAN, Ahmed S. , GEISLER, Karl J.L. , CONNELL, Jodi L. , YU, Ta-Hua
IPC: A61K6/083 , A61K6/09 , A61C7/08 , B29C64/124 , A61K6/00 , A61C7/00 , B33Y70/00 , G03F7/027 , G03F7/00
Abstract: The present disclosure provides an orthodontic article including the reaction product of the polymerizable composition. Further, the present disclosure provides polymerizable compositions and methods of making an orthodontic article. The method includes obtaining a polymerizable composition and selectively curing the polymerizable composition to form an orthodontic article. Further, methods are provided, including receiving, by a manufacturing device having one or more processors, a digital object comprising data specifying an orthodontic article; and generating, with the manufacturing device by an additive manufacturing process, the orthodontic article based on the digital object. A system is also provided, including a display that displays a 3D model of an orthodontic article; and one or more processors that, in response to the 3D model selected by a user, cause a 3D printer to create a physical object of an orthodontic article.
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