公开(公告)号：US20150038037A1

公开(公告)日：2015-02-05

申请号：US14388165

申请日：2013-03-06

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Dirk M. Coppens ,  Rudolph J. Dams ,  Chetan P. Jariwala

IPC: D06M15/576 ,  C08G18/28 ,  C08G18/76 ,  C08G18/62

CPC classification number: D06M15/576 ,  C08G18/2825 ,  C08G18/3812 ,  C08G18/3876 ,  C08G18/5015 ,  C08G18/6279 ,  C08G18/7664 ,  C09D133/16 ,  D06M15/277 ,  D06M2101/32 ,  D06M2101/34 ,  D06M2200/01 ,  D06M2200/10 ,  D06M2200/11 ,  D06M2200/12 ,  Y10T442/2861

Abstract: A fluorinated compound comprising: (i) a fluorochemical oligomeric portion comprising an aliphatic backbone comprising polymerized (meth)acrylate monomeric units, each having a perfluorinated terminal C4-C6 aliphatic group, and an organic residue obtained by removing a hydrogen atom from a functionalized chain transfer agent, wherein: the polymerized (meth)acrylate units are present in a molar ratio of at least 6:1 relative to the functionalized chain transfer agent; and the (meth)acrylate units comprise 0-30 mole-% acrylate units and 70-100 mole-% methacrylate units; (ii) a fluorine-free hydrocarbon moiety; (iii) a di-, tri-, or polymeric isocyanate-derived linking group; and (iv) a group that imparts a durable property when the compound is applied to a fibrous substrate.

Abstract translation: 一种含氟化合物，其包含：（i）包含脂族主链的含氟化合物低聚部分，其包含聚合的（甲基）丙烯酸酯单体单元，各自具有全氟化的末端C 4 -C 6脂族基团，以及通过从官能化链除去氢原子获得的有机残基 转移剂，其中：聚合的（甲基）丙烯酸酯单元相对于官能化的链转移剂以至少6:1的摩尔比存在; （甲基）丙烯酸酯单元包括0-30摩尔％丙烯酸酯单元和70-100摩尔％甲基丙烯酸酯单元; （ii）无氟烃部分; （iii）二异氰酸酯衍生的连接基团; 和（iv）当将化合物施加到纤维基质上时赋予耐久性的基团。

公开(公告)号：US11421378B2

公开(公告)日：2022-08-23

申请号：US16947579

申请日：2020-08-07

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Dirk M. Coppens ,  Rudolf J. Dams ,  Chetan P. Jariwala ,  Lin Chen

IPC: D06M15/263 ,  C14C9/00 ,  D21H21/16 ,  D21H17/54 ,  D06M15/59 ,  D21H19/24 ,  D06M15/653 ,  C08G18/62 ,  C08G18/09 ,  C08G18/16 ,  D21H17/57 ,  C08G18/79 ,  C08G18/02 ,  C09D4/00 ,  D21H17/33 ,  D06M15/01 ,  D21H17/37 ,  D21H19/20

Abstract: A fluorine-free composition includes at least one polycarbodiimide compound derived from a carbodiimidization reaction of a carbodiimidization reaction mixture comprising at least one oligomer, wherein the oligomer comprises at least one isocyanate end group and at least two repeating units, wherein each of the at least two repeating units comprises at least one hydrocarbon group having at least 16 carbon atoms. The composition may also include at least one paraffin wax. Such compositions are useful for treating fibrous substrates to enhance their water-repellency.

公开(公告)号：US11124918B2

公开(公告)日：2021-09-21

申请号：US15548114

申请日：2016-02-01

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Dirk M. Coppens ,  Rudolf J. Dams ,  Chetan P. Jariwala ,  Lin Chen

IPC: D06M15/263 ,  C14C9/00 ,  D21H21/16 ,  C08F220/36 ,  D21H17/54 ,  D06M15/59 ,  D21H19/24 ,  D06M15/653 ,  C08G18/62 ,  C08G18/09 ,  C08G18/16 ,  D21H17/57 ,  C08G18/79 ,  C08G18/02 ,  C09D4/00 ,  D21H17/33 ,  D06M15/01 ,  D21H17/37 ,  D21H19/20

Abstract: A fluorine-free composition includes at least one polycarbodiimide compound derived from a carbodiimidization reaction of a carbodiimidization reaction mixture comprising at least one oligomer, wherein the oligomer comprises at least one isocyanate end group and at least two repeating units, wherein each of the at least two repeating units comprises at least one hydrocarbon group having at least 16 carbon atoms. The composition may also include at least one paraffin wax. Such compositions are useful for treating fibrous substrates to enhance their water-repellency.

公开(公告)号：US20190177908A1

公开(公告)日：2019-06-13

申请号：US16323736

申请日：2017-08-08

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Dirk M. Coppens ,  Rudolf J. Dams

IPC: D06M15/263 ,  D21H21/16 ,  D21H19/12 ,  D21H19/20 ,  D21H19/30 ,  C09D179/08 ,  C09D133/08 ,  C09D175/14 ,  C09D133/10 ,  D06M15/572 ,  D06M15/59 ,  D06M15/267

Abstract: A fluorine-free treating composition that includes Component A and at least one of Components B and C, wherein: Component (A) includes one or more polymeric compounds derived from the polymerization of at least one (meth)acrylate monomer comprising at least one hydrocarbon group having from 1 to 60 carbon atoms; Component (B) includes one or more compounds derived from reaction, in one or more steps, of components comprising: (i) at least one isocyanate-reactive oligomer comprising 2 to 20 repeating units, or an alcohol having at least one linear or branched hydrocarbon group having from 16 to 40 carbon atoms and optionally one or more ester groups; (ii) at least one polyisocyanate; (iii) optionally at least one additional isocyanate-reactive compound; and (iv) optionally at least one isocyanate blocking agent; and Component (C) includes one or more polycarbodiimide compounds.

公开(公告)号：US10030334B2

公开(公告)日：2018-07-24

申请号：US14388165

申请日：2013-03-06

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Dirk M. Coppens ,  Rudolph J. Dams ,  Chetan P. Jariwala

IPC: D06M15/576 ,  D06M15/277 ,  C09D133/16 ,  C08G18/38 ,  C08G18/50 ,  C08G18/28 ,  C08G18/62 ,  C08G18/76 ,  D06M101/32 ,  D06M101/34

CPC classification number: D06M15/576 ,  C08G18/2825 ,  C08G18/3812 ,  C08G18/3876 ,  C08G18/5015 ,  C08G18/6279 ,  C08G18/7664 ,  C09D133/16 ,  D06M15/277 ,  D06M2101/32 ,  D06M2101/34 ,  D06M2200/01 ,  D06M2200/10 ,  D06M2200/11 ,  D06M2200/12 ,  Y10T442/2861

Abstract: A fluorinated compound comprising: (i) a fluorochemical oligomeric portion comprising an aliphatic backbone comprising polymerized (meth)acrylate monomeric units, each having a perfluorinated terminal C4-C6 aliphatic group, and an organic residue obtained by removing a hydrogen atom from a functionalized chain transfer agent, wherein: the polymerized (meth)acrylate units are present in a molar ratio of at least 6:1 relative to the functionalized chain transfer agent; and the (meth)acrylate units comprise 0-30 mole-% acrylate units and 70-100 mole-% methacrylate units; (ii) a fluorine-free hydrocarbon moiety; (iii) a di-, tri-, or polymeric isocyanate-derived linking group; and (iv) a group that imparts a durable property when the compound is applied to a fibrous substrate.

公开(公告)号：US09410054B2

公开(公告)日：2016-08-09

申请号：US14310688

申请日：2014-06-20

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Dirk M. Coppens ,  Leonardus A. M. Doelen

IPC: C09D133/08 ,  C04B41/00 ,  C04B41/50 ,  C09D133/00 ,  C09D5/16

CPC classification number: C09D133/08 ,  C04B41/009 ,  C04B41/5089 ,  C09D5/1637 ,  C09D5/1668 ,  C09D133/00 ,  C04B41/483 ,  C04B41/4846 ,  C04B41/4876 ,  C04B33/00 ,  C04B14/00 ,  C04B14/048 ,  C04B14/285 ,  C04B28/02 ,  C08L2666/04

Abstract: The present invention provides a composition for treatment, the composition comprising dispersed in water (i) a fluorinated compound, (ii) a potassium or lithium silicate and (iii) an acrylic polymer. The invention further provides a method of treating substrates with the composition.

Abstract translation: 本发明提供了一种用于处理的组合物，该组合物包括分散在水中（i）氟化化合物，（ii）硅酸钾或硅酸锂和（iii）丙烯酸类聚合物。 本发明还提供了一种用该组合物处理底物的方法。

公开(公告)号：US20180016739A1

公开(公告)日：2018-01-18

申请号：US15547932

申请日：2016-02-05

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Dirk M. Coppens ,  Rudolf J. Dams ,  Chetan P. Jariwala

IPC: D06M15/267 ,  C08F20/36

CPC classification number: D06M15/267 ,  C08F20/36 ,  C08F120/36 ,  C08F214/08 ,  C08F220/34 ,  C08F220/36 ,  D06M15/564 ,  D06M2200/12 ,  C08F2220/346 ,  C08F220/58 ,  C08F2220/325

Abstract: A method of treating a fibrous substrate, the method including applying a fluorine-free treating composition in an amount sufficient to make the fibrous substrate water repellent, wherein the treating composition includes one or more polymeric compounds derived from the polymerization of at least one (meth)acrylate monomer comprising at least one isocyanate-derived group and at least one hydrocarbon group having at least 16 carbon atoms.

公开(公告)号：US20180016738A1

公开(公告)日：2018-01-18

申请号：US15548114

申请日：2016-02-01

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Dirk M. Coppens ,  Rudolf J. Dams ,  Chetan P. Jariwala ,  Lin Chen

IPC: D06M15/263 ,  D21H19/20 ,  C08F220/36 ,  D06M15/01 ,  C14C9/00 ,  D21H17/37 ,  D21H21/16

CPC classification number: D06M15/263 ,  C08F220/36 ,  C08G18/025 ,  C08G18/095 ,  C08G18/168 ,  C08G18/6229 ,  C08G18/6283 ,  C08G18/797 ,  C09D4/00 ,  C14C9/00 ,  D06M15/01 ,  D06M15/59 ,  D06M15/653 ,  D06M2200/12 ,  D21H17/33 ,  D21H17/37 ,  D21H17/54 ,  D21H17/57 ,  D21H19/20 ,  D21H19/24 ,  D21H21/16 ,  C09D175/04 ,  C08L91/08

Abstract: A fluorine-free composition includes at least one polycarbodiimide compound derived from a carbodiimidization reaction of a carbodiimidization reaction mixture comprising at least one oligomer, wherein the oligomer comprises at least one isocyanate end group and at least two repeating units, wherein each of the at least two repeating units comprises at least one hydrocarbon group having at least 16 carbon atoms. The composition may also include at least one paraffin wax. Such compositions are useful for treating fibrous substrates to enhance their water-repellency.

公开(公告)号：US20130296216A1

公开(公告)日：2013-11-07

申请号：US13938711

申请日：2013-07-10

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Dirk M. Coppens ,  Leonardus A. M. Doelen

IPC: C11D3/00

CPC classification number: C11D3/0036 ,  B05D5/083 ,  B05D2203/30 ,  C04B41/009 ,  C04B41/4846 ,  C09D5/1637 ,  C04B41/4994 ,  C04B33/00 ,  C04B14/00 ,  C04B14/043 ,  C04B14/048 ,  C04B14/285 ,  C04B28/02

Abstract: The present invention provides a composition for treatment, the composition comprising a fluorinated compound and a phosphate ester having at least one hydrocarbon residue having at least 6 carbon atoms. There is further provided a method of treatment applying the composition to a substrate.

Abstract translation: 本发明提供一种用于处理的组合物，所述组合物包含含氟化合物和具有至少一个具有至少6个碳原子的烃残基的磷酸酯。 还提供了一种将组合物施用于基材的方法。