Abstract:
The present invention provides a thermoplastic elastomer (TPE), in particular a polyurethane-based thermoplastic elastomer (TPU), that has exceptional elongation, strength, and wear resistance, and in particular has exceptional wear resistance. The present invention provides: a thermoplastic elastomer composition containing A) a thermoplastic urethane elastomer composition having A1) at least one polyol selected from the group consisting of polyether polyols, polyesterpolyols, and polycarbonate polyols, A2) a diisocyanate, and A3) a chain extender, and B) polyrotaxane formed by arranging blocking groups, at both ends of pseudo-polyrotaxane formed by inclusion of the openings of cyclic molecules in a shape skewered by linear molecules, so that the cyclic molecules are not eliminated; and a thermoplastic elastomer derived from this composition.
Abstract:
A polyrotaxane is blended into a polyol composition, which can reduce the tensile stress of a flexible polyurethane foam. A vertical compressive stress due to the weight of a sitting user and a tensile stress due to the input of lateral vibrations act on a urethane pad. However, by reducing the tensile stress of the flexible polyurethane foam, the direction (inclination) of a resultant force obtained by combining the compressive stress and the tensile stress can be brought close to the vertical direction. Thus, the angle of inclination of the user's hip (ischium) on the urethane pad to the vertical direction due to the input of lateral vibrations can be reduced, so that the sense of wobble of the urethane pad can be reduced.
Abstract:
A material comprising crosslinked polyrotaxanes which exhibits desired viscoelasticity, particularly stress-strain characteristics with a wide low-stress region, in spite of being free from solvent; and a process for production of the same. The material comprises a first polyrotaxane bearing first cyclic molecules and a second polyrotaxane bearing second cyclic molecules, and the first and second polyrotaxanes are crosslinked via the first and second cyclic molecules. The material is free from solvent and exhibits a stress of 2.0 MPa or below at 50% strain.