ALIGNMENT RESIN FILM AND ITS PRODUCTION AS WELL AS OPTICAL ELEMENT USING THIS ALIGNMENT RESIN FILM

    公开(公告)号:JPH11160708A

    公开(公告)日:1999-06-18

    申请号:JP25983898

    申请日:1998-09-14

    Abstract: PROBLEM TO BE SOLVED: To improve stability and to increase the area with a uniform film thickness by a simple method by subjecting a resin film including dichromatic photoreactive constitution units to irradiation with light of linearly polarized light or the irradiation with non-polarized light from a diagonal direction and a heat treatment. SOLUTION: The alignment film is formed by subjecting the resin film including the dichromatic photoreactive constitution units, more preferably the latently liquid crystalline or crystalline resin film to the irradiation with the light of the linearly polarized light or the irradiation with the non-polarized light from the diagonal direction and the heat treatment. The dichromatic photoreactive constitution units included in the resin film are particularly preferably the liquid crystalline or crystalline units substituted with the azobenzene expressed by the formula. In the formula, X is a bivalent residue bonded to a high polymer main chain; Y denotes a hydrogen atom, up to 8C alkyl group, cycloalkyl group, cyano group, nitro group, up to 6C alkoxy group, up to 6C alkoxycarbonyl group, halogen group, trifluoromethyl group or trifluoromethoxy group.

    PHOTOSENSITIVE MATERIAL FOR HOLOGRAM RECORDING

    公开(公告)号:JPH03278082A

    公开(公告)日:1991-12-09

    申请号:JP7849090

    申请日:1990-03-27

    Abstract: PURPOSE:To provide the photosensitive material which has excellent chemical stability, high resolution, high diffraction efficiency, etc., and has an excellent photosensitive characteristic to long-wavelength laser beams by combining poly-N-vinyl carbazole, a compd. having polymerizable ethylenic unsatd. bonds and a specific photopolymn. initiator. CONSTITUTION:The photopolymn. initiator, consisting of the combination of the tetrabenzoporphyrins expressed by formula I or metal complex thereof and an electron-accepting radical generator, the poly-N-vinyl carbazole as a supporting material having a refractive index as high as 1.68 and the compd. having at least >=1 pieces of the polymerizable ethylenic unsatd. bonds are combined. In the formula I, R denotes a hydrogen atom, alkyl group or a residual arom. group which may have a substituent; the respective benzene rings may have an alkyl group or alkoxy group as a substituent. The photosensitive material for hologram recording which has the excellent chemical stability, the high resolution and the high diffraction efficiency based on high-refractive index modulation and has the excellent photosensitive material to the long- wavelength laser beams of >=600nm is obtd. in this way.

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