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    PROCESS FOR THE PREPARATION OF HIGH PURITY PROPYLENE POLYMERS
    11.
    发明申请
    PROCESS FOR THE PREPARATION OF HIGH PURITY PROPYLENE POLYMERS 审中-公开
    制备高纯丙烯聚合物的方法

    公开(公告)号：WO2013041470A1

    公开(公告)日：2013-03-28

    申请号：PCT/EP2012/068195

    申请日：2012-09-17

    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

    Inventor： GALVAN, Monica ,  PANTALEONI, Roberto ,  FUSCO, Ofelia ,  GADDI, Benedetta ,  NEUMANN, Andreas ,  MAZZUCCO, Antonio ,  COLLINA, Gianni ,  SARTORI, Gabriella

    IPC: C08F4/651 ,  C08F4/654 ,  C08F10/06 ,  C08J5/18 ,  C08F4/649

    CPC classification number: C08F10/06 ,  C08J5/18 ,  C08J2323/14 ,  C08F4/651 ,  C08F4/6543 ,  C08F110/06 ,  C08F2500/04 ,  C08F2500/12 ,  C08F2500/15

    Abstract: A process for the preparation of high purity propylene polymers carried out in the presence of a catalyst comprising the product obtained by contacting: (a) a solid catalyst component comprising Mg, Ti and at least a first internal electron donor compound (1ID) selected among the succinates and a second internal electron donor compound (2ID) selected among the 1,3-diethers, wherein the molar ratio of first internal donor over second internal donor 1ID:2ID is comprised between 4:6 and 9:1, with (b) an organo-aluminium compound, and optionally with (c) an external electron donor compound, said process being carried out at a temperature equal or higher than78°C and by employing a molar ratio of organo-aluminum compound over solid catalyst component (b):(a) of lower than 5.

    Abstract translation: 一种制备高纯度丙烯聚合物的方法，该催化剂在催化剂存在下进行，所述催化剂包括通过使（a）包含Mg，Ti和至少第一内电子给体化合物（1ID）的固体催化剂组分与 所述琥珀酸盐和选自所述1,3-二醚中的第二内部电子给体化合物（2ID），其中所述第一内给体相对于所述第二内供体1ID：2ID的摩尔比为4：6至9：1，与（b ）有机铝化合物和任选与（c）外电子给体化合物反应，所述方法在等于或高于78℃的温度下进行，并且通过使用有机铝化合物与固体催化剂组分（b ）:( a）低于5。

    ELASTOMERIC POLYOLEFIN COMPOSITIONS
    13.
    发明申请
    ELASTOMERIC POLYOLEFIN COMPOSITIONS 审中-公开
    弹性聚烯烃组合物

    公开(公告)号：WO2006037705A1

    公开(公告)日：2006-04-13

    申请号：PCT/EP2005/054370

    申请日：2005-09-05

    Applicant: Basell Poliolefine Italia s.r.l. ,  MASSARI, Paola ,  NEUMANN, Andreas ,  COLLINA, Gianni ,  FUSCO, Ofelia

    Inventor： MASSARI, Paola ,  NEUMANN, Andreas ,  COLLINA, Gianni ,  FUSCO, Ofelia

    IPC: C08L23/10

    CPC classification number: C08F210/06 ,  C08F10/00 ,  C08F110/06 ,  C08F210/16 ,  C08L23/0815 ,  C08L23/10 ,  C08L23/16 ,  C08F4/651 ,  C08F2/001 ,  C08L2666/06 ,  C08F2500/15 ,  C08F2500/12 ,  C08F2500/17 ,  C08F2500/04 ,  C08F210/08 ,  C08F2500/21 ,  C08F210/14

    Abstract: An olefin polymer composition comprising (by weight, unless otherwise specified): A) 60-85% of a crystalline propylene homopolymer or a crystalline copolymer of propylene containing 3% or less of ethylene or C 4 -C 10 α-olefin(s) or of combinations thereof, said homopolymer or copolymer having a Polydispersity Index (P.I.) value of from 4.5-6 and a content of isotactic pentads (mmmm), measured by 13 C NMR on the fraction insoluble in xylene at 25 °C, higher than 96%; B) 15-40% of a partially amorphous copolymer of ethylene containing from 35% to 70% of propylene or C 4 -C 10 α-olefin(s) or of combinations thereof, and optionally minor proportions of a diene. The said olefin polymer composition exhibits a value of elongation at break ranging from 150 to 600% according to ISO method 527.

    Abstract translation: 包含（按重量计，除非另有说明）的烯烃聚合物组合物：A）60-85％的结晶丙烯均聚物或含有3％或更少乙烯或C 4 -C 3的丙烯的结晶共聚物 所述均聚物或共聚物的多分散指数（PI）值为4.5-6，全同立构五单元组（mmmm）的含量由 25℃，高于96％的不溶于二甲苯的级分的13 C NMR; B）15-40％的含有35％至70％丙烯或C 4 -C 10α-烯烃的部分无定形乙烯共聚物或 它们的组合，和任选的少量二烯。 所述烯烃聚合物组合物根据ISO方法527显示出150至600％的断裂伸长率值。

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