Ortho-benzoylbenzoic acid prepn
    17.
    发明专利

    公开(公告)号:DE1934086A1

    公开(公告)日:1971-02-25

    申请号:DE1934086

    申请日:1969-07-04

    Applicant: BASF AG

    Abstract: Benzoylbenzoic acid prepn. Oxidation of indanes of formula:- (R1, R2, R3 are each alkyl; R1 and/or R3 can be H), oxidised with HNO3 and/or Cr-VI compounds gives, simply and economically, better yields of high-purity o-benzoylbenzoic acid (valuable for syntheses, especially for anthraquinone) without formation of considerable quantities of o-acetylbenzophenone. Temperature for HNO3 oxidation is 50 - 250 degrees C. Less than 1.5 x stoichiometric requirement of Cr-VI compounds is preferred. In a preferred method, at least 10% stoichiometric requirement of alkaline bichromate is added simultaneously to the HNO3.

    19.
    发明专利
    未知

    公开(公告)号:DE1920246A1

    公开(公告)日:1970-11-12

    申请号:DE1920246

    申请日:1969-04-22

    Applicant: BASF AG

    Abstract: 1298504 Cyanoacetaldehyde; isoxazolines BADISCHE ANILIN. & SODA-FABRIK AG 21 April 1970 [22 April 1969] 18917/70 Heading C2C Cyanoacetaldehyde is obtained by splitting in the presence of alkali-metal or alkaline-earthmetal oxides or hydroxides, either (a) isoxazolines of the formula wherein R is an aromatic radical; or (b) isoxazolines obtained by reacting malonaldehyde dioxime with nitrous acid. Phenyl azide may be produced as a by-product of the above-process, when R is a phenyl group. Isoxazolines of the above formula may be obtained by reacting malonaldehyde dioxime with appropriate diazonium compounds.

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