PROCESS FOR THE SEPARATION OF CATALYSTS FROM POLYPHENYLENE ETHERS

    公开(公告)号:DE3363393D1

    公开(公告)日:1986-06-12

    申请号:DE3363393

    申请日:1983-07-23

    Applicant: BASF AG

    Abstract: High molecular weight polyphenylene ethers are prepared from monohydric phenols by an oxidative coupling reaction with oxygen in the presence of a catalyst complex obtained from a copper salt and an organic amine by a method wherein the metal component of the catalyst is separated off, after the polymerization, by the addition of a polymeric polycarboxylic acid which is essentially composed of unsaturated monofunctional or difunctional carboxylic acids and/or their anhydrides. Advantageously, the polymeric polycarboxylic acids used are homopolymers or copolymers of (a) from 50 to 100% by weight of one or more unsaturated monofunctional acids of 3 to 10 carbon atoms and/or one or more difunctional acids or their anhydrides of 4 to 6 carbon atoms and from 0 to 50% by weight of one or more monomers which do not possess an acid function and can be copolymerized with (a).

    Thermoplastic moulding composition
    16.
    发明专利

    公开(公告)号:DE3425458A1

    公开(公告)日:1986-01-23

    申请号:DE3425458

    申请日:1984-07-11

    Applicant: BASF AG

    Abstract: The invention relates to a moulding composition containing a hard matrix A of polystyrene in a proportion of from 70 to 95 % by weight, based on the moulding composition of A+B, and a soft phase B, distributed therein, in a proportion of from 30 to 35 % by weight, based on the moulding composition of A+B, which has a mean particle size in the range of from 0.1 to 1.5 mu m (number average). The soft phase is a graft copolymer of styrene on an elastomeric monovinylaromatic-butadiene two-block copolymer. The monovinylaromatic monomer for building up the two-block copolymer comprises ring-alkylated methyl styrenes such that the soft phase B contains more than 70% (number average) of shell particles.

    Flameproofed thermoplastic moulding compound

    公开(公告)号:DE3414120A1

    公开(公告)日:1985-10-24

    申请号:DE3414120

    申请日:1984-04-14

    Applicant: BASF AG

    Abstract: The invention relates to a flameproofed thermoplastic moulding compound containing a thermoplastic resin A and, in each case based on 100 parts by weight of the resin A, if appropriate an elastomer B, 5 to 50 parts by weight of at least one halogen-containing organic compound C (flame retardant) and, if appropriate, up to 20 parts by weight of a metal-containing or non-metal-containing compound (synergist) D. The flame retardant (C) used comprises brominated triarylamines of the general formula (I) where aryl represents a phenyl, naphthyl, anthracenyl, phenanthrenyl, fluorenyl or fluoranthenyl, biphenyl, triphenylenyl or acenaphthenylene radical and the radicals can be substituted if appropriate with alkyl, alkoxy or aryloxy, and where, furthermore, m, n and p represent integers with the proviso that m = 1-5, and n and p can be the same or different and can each have values from 0-5. The moulding compounds according to the invention are used for producing mouldings.

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