公开(公告)号：NO872383D0

公开(公告)日：1987-06-05

申请号：NO872383

申请日：1987-06-05

Applicant: BASF AG

Inventor： EGGERSDORFER MANFRED ,  SIEGEL HARDO ,  SCHUHMACHER ALFRED ,  GROSCH WALTER ,  HENKELMANN JOCHEN

IPC: C07B41/06 ,  B01J31/00 ,  B01J31/12 ,  B01J31/14 ,  C07B31/00 ,  C07B61/00 ,  C07C45/00 ,  C07C45/46 ,  C07C49/76 ,  C07C51/083 ,  C07C51/373 ,  C07C65/34 ,  C07C67/00 ,  C07C

Abstract: 1. A process for the acylation of an aromatic by the Friedel-Crafts method, wherein the acylation is carried out in the presence of a metalalkyl or metalalkyl halide of a metal or semimetal of main groups two to five and/or of a metal of subgroups two or four of the Periodic Table.

公开(公告)号：FI88914C

公开(公告)日：1993-07-26

申请号：FI872515

申请日：1987-06-04

Applicant: BASF AG

Inventor： EGGERSDORFER MANFRED ,  SIEGEL HARDO ,  SCHUHMACHER ALFRED ,  GROSCH WALTER ,  HENKELMANN JOCHEN

IPC: C07B41/06 ,  B01J31/00 ,  B01J31/12 ,  B01J31/14 ,  C07B31/00 ,  C07B61/00 ,  C07C45/00 ,  C07C45/46 ,  C07C49/76 ,  C07C51/083 ,  C07C51/373 ,  C07C65/34 ,  C07C67/00

公开(公告)号：DE3879935D1

公开(公告)日：1993-05-06

申请号：DE3879935

申请日：1988-09-21

Applicant: BASF AG

Inventor： EGGERSDORFER MANFRED ,  HENKELMANN JOCHEN ,  GROSCH WALTER

IPC: B01J31/00 ,  B01J31/02 ,  C01B15/023 ,  C07B61/00 ,  C07C46/00 ,  C07C46/02 ,  C07C50/16 ,  C07C50/18

Abstract: 2-Neophentylanthraquinone (I), prepd. by Friedel-Crafts acylation of neopentylbenzyene (II) with phthalic anhydride (III) and cyclisation of the resultinq adduct (IV), is new. Preferred catalysts for the conversion of (II) to (IV) are aluminium halogenides, esp. ALBr3 and partic. AlCl3, or mixts. thereof. The reaction is carried out in halogenated aromatic solvent (C6H5Cl, C6H4Cl2 or C6H3Cl3), ClCH2CH2Cl, CS2, CH3NO2, or C6H5NO2. The cyclisation step (obtd. (IV) to cpd. (I) is performed in 95 to 105% H2SO4 at a temp. between 20 and 220 deg. C.

公开(公告)号：AT87606T

公开(公告)日：1993-04-15

申请号：AT89900203

申请日：1988-09-21

Applicant: BASF AG

Inventor： EGGERSDORFER MANFRED ,  HENKELMANN JOCHEN ,  GROSCH WALTER

IPC: C07C50/18

公开(公告)号：NO165392C

公开(公告)日：1991-02-06

申请号：NO872383

申请日：1987-06-05

Applicant: BASF AG

Inventor： EGGERSDORFER MANFRED ,  SIEGEL HARDO ,  SCHUHMACHER ALFRED ,  GROSCH WALTER ,  HENKELMANN JOCHEM

IPC: C07B41/06 ,  B01J31/00 ,  B01J31/12 ,  B01J31/14 ,  C07B31/00 ,  C07B61/00 ,  C07C45/00 ,  C07C45/46 ,  C07C49/76 ,  C07C51/083 ,  C07C51/373 ,  C07C65/34 ,  C07C67/00

Abstract: 1. A process for the acylation of an aromatic by the Friedel-Crafts method, wherein the acylation is carried out in the presence of a metalalkyl or metalalkyl halide of a metal or semimetal of main groups two to five and/or of a metal of subgroups two or four of the Periodic Table.

公开(公告)号：ES2010203B3

公开(公告)日：1989-11-01

申请号：ES87108066

申请日：1987-06-04

Applicant: BASF AG

Inventor： EGGERSDORFER MANFRED ,  GROSCH WALTER ,  HENKELMANN JOCHEM ,  SIEGEL HARDO ,  SCHUHMACHER ALFRED

IPC: C07B41/06 ,  B01J31/00 ,  B01J31/12 ,  B01J31/14 ,  C07B31/00 ,  C07B61/00 ,  C07C45/00 ,  C07C45/46 ,  C07C49/76 ,  C07C51/083 ,  C07C51/373 ,  C07C65/34 ,  C07C67/00

Abstract: PROCEDIMIENTO PARA LA ACILACION DE COMPUESTOS AROMATICOS POR REACCION DE FRIEDEL-CRAFTS EN EL QUE SE EFECTUA LA ACILACION EN PRESENCIA DE ALQUILOS METALICOS O HALOGENUROS DE ALQUILOS METALICOS DE METALES O SEMIMETALES DE LOS GRUPOS PRINCIPALES PRIMERO A QUINTO Y/O METALES DEL SEGUNDO O DEL CUARTO SUBGRUPO DEL SISTEMA PERIODICO.

公开(公告)号：ZA874035B

公开(公告)日：1989-02-22

申请号：ZA874035

申请日：1987-06-05

Applicant: BASF AG

Inventor： EGGERSDORFER MANFRED ,  MANFRED EGGERSDORFER ,  SIEGEL HARDO ,  HARDO SIEGEL ,  SCHUMACHER ALFRED ,  ALFRED SCHUMACHER ,  GROSCH WALTER ,  WALTER GROSCH ,  HENKELMANN JOCHEM ,  JOCHEM HENKELMANN

IPC: C07C45/46 ,  C07C49/76 ,  C07C51/373 ,  C07C

公开(公告)号：AU7389387A

公开(公告)日：1987-12-10

申请号：AU7389387

申请日：1987-06-05

Applicant: BASF AG

Inventor： EGGERSDORFER MANFRED ,  SIEGEL HARDO ,  SCHUHMACHER ALFRED ,  GROSCH WALTER ,  HENKELMANN JOCHEM

IPC: C07B41/06 ,  B01J31/00 ,  B01J31/12 ,  B01J31/14 ,  C07B31/00 ,  C07B61/00 ,  C07C45/00 ,  C07C45/46 ,  C07C49/76 ,  C07C51/083 ,  C07C51/373 ,  C07C65/34 ,  C07C67/00

Abstract: 1. A process for the acylation of an aromatic by the Friedel-Crafts method, wherein the acylation is carried out in the presence of a metalalkyl or metalalkyl halide of a metal or semimetal of main groups two to five and/or of a metal of subgroups two or four of the Periodic Table.