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公开(公告)号:CA702547A
公开(公告)日:1965-01-26
申请号:CA702547D
Applicant: BASF AG
Inventor: ZACHER WIELAND , GOEBEL SIEBERT , FRIEDENREICH HEINRICH , EILBRACHT HANS
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公开(公告)号:GB962433A
公开(公告)日:1964-07-01
申请号:GB778461
申请日:1961-03-03
Applicant: BASF AG
Inventor: ZACHER WIELAND , EILBRACHT HANS , FRIEDENREICH HEINRICH , GOEBEL SIEBERT
Abstract: A colourless lubricant for gas compressors comprises a turbid suspension of 0.01% to 5% by weight of a hard wax (as defined in the Specification) containing polar groups, e.g. ester, amide or free acid groups, in a colourless lubricating oil, preferably paraffinum liquidum. The wax is montan wax, montan wax acid, montan wax esterified with an alcohol, e.g. ethylene glycol or butylene glycol, or a mixture of a montan wax acid and an ester of a higher alcohol. Calcium salts of montan wax acid may be added to the hard wax in amounts of 10, 20 or 30% by weight.
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公开(公告)号:GB956738A
公开(公告)日:1964-04-29
申请号:GB2388362
申请日:1962-06-21
Applicant: BASF AG
Inventor: EILBRACHT HANS , FRIEDENREICH HEINRICH , GOEBEL SIEBERT , HAEBERLE MANFRED , LEHMANN BORIS
IPC: C08F10/00
Abstract: Ethylene is polymerized in tubular reactors at 1,000-4,000 Atm and 150-300 DEG C. with feeding of cold ethylene at several successive points in the reactor and using up to 10-1% oxygen as catalyst which is added preferably in solution, to the cold ethylene in such amount that the oxygen concentration in the united gas stream at the points of confluence in the reactor is at least 0.5 x 10-3%, preferably 10-3-10-2%, and the speed of the reaction mixture in the reactor is at least 2.5 m/sec., e.g. up to 10 m/sec. The main ethylene stream may first be heated to e.g. 170-200 DEG C. The cold ethylene stream may be at 10-100 DEG C. and the oxygen concentration may be higher in the second cold ethylene stream than in the first. The oxygen may be dissolved in water, alcohols, e.g. methanol, or hydrocarbons e.g. benzene. The polyethylene may be used to form articles or tubular film.
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公开(公告)号:FR1300593A
公开(公告)日:1962-08-03
申请号:FR873388
申请日:1961-09-16
Applicant: BASF AG
Inventor: SCHMIDT-THOMEE GEORG , EILBRACHT HANS , KINKEL KLAUS , TRIESCHMANN HANS GEORG , URBAN FRIEDRICH , ZOCHE GUENTER
IPC: C08F10/00
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公开(公告)号:CA663654A
公开(公告)日:1963-05-21
申请号:CA663654D
Applicant: BASF AG
Inventor: PFANNMUELLER HELMUT , URBAN FRIEDRICH , ZACHER WIELAND , TRIESCHMANN HANS G , EILBRACHT HANS , ROTZOLL RUDI-HEINZ
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公开(公告)号:GB918459A
公开(公告)日:1963-02-13
申请号:GB4322761
申请日:1961-12-04
Applicant: BASF AG
Inventor: EILBRACHT HANS , PFANNMUELLER HELMUT , ROTZOLL RUDI-HEINZ , URBAN FRIEDRICH , ZACHER WIELAND
IPC: C08F10/00
Abstract: A process for removing solvent from polyethylene produced in a high pressure continuous process and from the low-pressure recycle gas comprises the steps of separating the polyethylene from the reaction mixture in a high pressure separator 10 at a pressure of more than 150 atmospheres and while maintaining a definite level of liquid therein is decompressed into a low-pressure separator 13 from which the entrained residual ethylene and solvent are led through a gas cooler 23 into a third separator 24 where the ethylene is substantially freed from solvent and led at atmospheric pressure with the remaining solvent to a countercurrent heat-exchanger 26. The ethylene separated in the high-pressure separator with the bulk of the solvent is cooled in a precooler 16, part of this is expanded and separated from the solvent in a low-temperature separator 19 and returned through said heat-exchanger 26 and a second heat-exchanger 28 to the precompressor 3 where it is mixed with fresh ethylene 1. The remainder of the ethylene from the precooler 16 is further cooled in an after-cooler 21 and supplied to the after-compressor 5 before passing to the reaction vessel 7. Solvent is removed from the system by valves 20 and 25 and enters the system by valve 31. Polyethylene is removed through valve 14.
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公开(公告)号:GB917387A
公开(公告)日:1963-02-06
申请号:GB3262461
申请日:1961-09-12
Applicant: BASF AG
Inventor: SCHMIDT-THOMEE GEORG , EILBRACHT HANS , KINKEL KLAUS , TRIESCHMANN HANS GEORG , URBAN FRIEDRICH , ZOCHE GUENTER
IPC: C08F10/00
Abstract: Polyethylene of density more than 0,924 and suitable for the production of film is produced by polymerizing ethylene in a tubular system in the presence of hydrogen as chain transfer agent and oxygen as catalyst, the polymerization being in the absence of solvents or diluents, at pressures between 2000 and 4000 atmospheres and at temperatures between 200 DEG and 300 DEG C., and the ethylene containing 0,05 to 2% of hydrogen and 5 to 20 p.p.m. of oxygen.
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公开(公告)号:FR1304493A
公开(公告)日:1962-09-21
申请号:FR877038
申请日:1961-10-25
Applicant: BASF AG
Inventor: EILBRACHT HANS , PFANNMUELLER HELMUT , ROTZOLL RUDI-HEINZ , TRIESCHMANN HANS GEORG , URBAN FRIEDRICH , ZACHER WIELAND
IPC: C08F10/00
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公开(公告)号:FR1283554A
公开(公告)日:1962-02-02
申请号:FR855229
申请日:1961-03-10
Applicant: BASF AG
Inventor: ZACHER WIELAND , EILBRACHT HANS , FRIEDENREICH HEINRICH , GOEBEL SIEBERT
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