公开(公告)号：DE102005003315A1

公开(公告)日：2006-08-03

申请号：DE102005003315

申请日：2005-01-24

Applicant: BASF AG

Inventor： ERNST MARTIN ,  HAHN THILO ,  WENZ KIRSTEN ,  HUGO RANDOLF ,  MELDER JOHANN-PETER

IPC: C07C209/48 ,  B01J23/86 ,  C07C211/51

Abstract: A process for preparing a xylylenediamine by heterogeneously catalyzed hydrogenation of a phthalonitrile, wherein the hydrogenation is carried out in the presence of a cobalt skeletal catalyst, of an alkali metal hydroxide and of an alcohol and/or ether as the solvent, at an absolute pressure in the range from 1 to 100 bar and a temperature in the range from 40 to 150° C.

公开(公告)号：DE102005044187A1

公开(公告)日：2007-03-22

申请号：DE102005044187

申请日：2005-09-15

Applicant: BASF AG

Inventor： HAHN THILO ,  ERNST MARTIN ,  MELDER JOHANN-PETER

IPC: C07C209/48 ,  B01J23/00 ,  B01J37/00 ,  C07C211/09 ,  C07C253/30 ,  C07C255/24

Abstract: Hydrogenation of oligonitriles exhibiting at least two nitrile groups, in the presence of a catalyst, which is pre-treated before the hydrogenation process by contacting with a compound A, where the compound A is alkaline metal carbonates, alkaline-earth metal carbonates, ammonium carbonate, alkaline metal hydrogencarbonate, alkaline-earth metal hydrogencarbonate, ammonium hydrogencarbonate or alkaline-earth metal oxycarbonate. Independent claims are included for: (1) an oligo amine or amino nitrile, obtained from an oligo nitrile; (2) a catalyst comprising a metal from group VIII to X, which is pretreated with the compound A, where the cobalt or nickel catalyst is pre-treated with compound A excluding alkali metal carbonate or alkali metal hydrogen carbonate; and (3) a method for preparing the catalyst comprising treating a metal from the group VIII to X with the compound A.

公开(公告)号：CA3006736A1

公开(公告)日：2017-07-06

申请号：CA3006736

申请日：2016-12-02

Applicant: EXXONMOBIL RES & ENG CO ,  BASF AG

Inventor： PEREIRA CARLA S ,  SISKIN MICHAEL ,  INGRAM THOMAS ,  VORBERG GERALD ,  ERNST MARTIN

IPC: B01D53/14 ,  C10L3/10

Abstract: A process for selectively separating H2S from a gas mixture which also comprises CO2 is disclosed. A stream of the gas mixture is contacted with an absorbent solution comprising one or more amines, alkanolamines, hindered alkanolamines, capped alkanolamines, or mixtures thereof. The H2S/CO2 selectivity of the absorbent solution is preferably greater than about 4.0 for an acid gas loading [mol(CO2 + H2S)/mol(amine)] between about 0.2 and about 0.6, and is achieved by reducing pH of the absorbent solution.

公开(公告)号：DE102006058624A1

公开(公告)日：2007-07-19

申请号：DE102006058624

申请日：2006-12-13

Applicant: BASF AG

Inventor： KOTREL STEFAN ,  ERNST MARTIN

IPC: B01J32/00 ,  B01J35/02 ,  B01J37/00

Abstract: Catalyst carrier (I), preferably of metallic oxide of the group 4, where the catalyst carrier exhibits an essential monomodal pore radius distribution. Independent claims are included for: (1) a catalyst comprising (I) and a catalytic active material; (2) the preparation of the catalyst comprising converting catalyst carrier with at least bimodal pore radius distribution into catalyst carrier with monomodal pore radius distribution; providing an active component on the catalyst carrier; and drying the obtained catalyst, where the steps of providing and drying is repeated several time to obtain the product; (3) a procedure for the preparation of the catalyst carrier comprising treating (I) with at least bimodal pore radius distribution to obtain an essentially monomodal pore radius distribution; and (4) a procedure for recycling the catalyst containing catalyst carrier comprising two successive steps, in which the catalyst is heated in presence of oxygen with the condition that in each following steps, the temperature and oxygen content lies more higher with the previous steps.

公开(公告)号：DE102005008929A1

公开(公告)日：2006-08-31

申请号：DE102005008929

申请日：2005-02-24

Applicant: BASF AG

Inventor： ERNST MARTIN ,  WENZ KIRSTEN ,  HUGO RANDOLF ,  MELDER JOHANN-PETER ,  HAHN THILO

IPC: C07C209/36 ,  B01J23/86 ,  C07C211/51

Abstract: Preparation of xylylenediamine compounds (I) comprises heterogeneous catalyzed hydrogenation of phthalodinitrile compound (II), where the hydrogenation takes place in the presence of a nickel containing catalyst (III), water, alkali metal hydroxide (IV) and ethers as solvents, at 1-100 bars and 40-150[deg]C and in the absence of ammonia.