公开(公告)号：WO2007088131A3

公开(公告)日：2007-10-04

申请号：PCT/EP2007050679

申请日：2007-01-24

Applicant: BASF AG ,  HUGO RANDOLF ,  DAHMEN KIRSTEN ,  HUBER SABINE

Inventor： HUGO RANDOLF ,  DAHMEN KIRSTEN ,  HUBER SABINE

IPC: C07C209/84 ,  C07C211/27

CPC classification number: C07C209/84 ,  Y10S203/20 ,  C07C211/27

Abstract: The invention relates to a method for producing pure xylylenediamine (XDA) by continuous distillation of crude xylylenediamine (XDA) in a column, by using a side stream distillation column, the XDA being drawn off through the lateral discharge and the bottom product of the distillation column being further concentrated in an additional concentration step. The condensate obtained in the concentration step is returned to the side draw distillation column.

Abstract translation: 一种用于通过与侧使用的蒸馏塔在塔通过将粗间苯二甲胺连续蒸馏制备纯苯二甲胺（XDA）工艺绘制和XDA在侧馏分取出并进一步蒸发，蒸馏塔中的附加蒸发阶段的底部产物和该蒸发阶段中的冷凝液 蒸馏塔返回与侧馏分。

公开(公告)号：EP0761676A3

公开(公告)日：1998-07-15

申请号：EP96113453

申请日：1996-08-22

Applicant: BASF AG

Inventor： HERMELING DIETER ,  HUGO RANDOLF ,  LECHTKEN PETER ,  ROTERMUND GERHARD W ,  SIEGEL HARDO

IPC: C07F9/50

CPC classification number: C07F9/509

Abstract: Verfahren zur Herstellung von Triphenylphosphin durch Reduktion von Triphenylphosphindichlorid an unedlen Metallen bei Temperaturen von 50 bis 150°C und Drücken von 0,2 bis 10 bar, indem das Triphenylphosphindichlorid zu 50 bis 100 Gew.-% kovalent und zu 50 bis 0 Gew.-% ionisch vorliegt.

Abstract translation: 一种用于通过减少对贱金属二氯化三苯基膦在50至150℃和0.2至10巴的压力由dichlorotriphenylphosphorus到50〜100重量％共价和50〜0重量制备三苯基膦处理 ％离子。

公开(公告)号：AT380788T

公开(公告)日：2007-12-15

申请号：AT04764997

申请日：2004-09-09

Applicant: BASF AG

Inventor： HUGO RANDOLF ,  WENZ KIRSTEN ,  JOURDAN SABINE ,  PREISS THOMAS

IPC: C07C209/48 ,  C07C211/27

Abstract: The invention relates to a method for the production of diaminoxylene, by continuous hydrogenation of liquid phthalonitrile, on a heterogeneous catalyst, in the presence of liquid ammonia, in a reactor, whereby a part of the reactor product is continuously recycled to the reactor feed as a liquid recycle stream (recirculating loop). A flow of fused phthalonitrile is added as a liquid to the recycle stream around the hydrogenation reactor in a mixing device, whereby the phthalonitrile conversion in the reactor on a single pass is greater than 99 % and the recycle stream comprises more than 93 % by weight of liquid ammonia and diaminoxylene and contains no further solvent for phthalonitrile.

公开(公告)号：DE102005045806A1

公开(公告)日：2007-03-29

申请号：DE102005045806

申请日：2005-09-24

Applicant: BASF AG

Inventor： WENZ KIRSTEN ,  HUBER SABINE ,  HUGO RANDOLF ,  MELDER JOHANN-PETER ,  PREISS THOMAS

IPC: C07C209/48 ,  B01J23/70 ,  C07C209/84 ,  C07C209/86 ,  C07C211/27

Abstract: Process for preparing o-, m- or p-xylylenediamine by hydrogenation of o-, m- or p-phthalonitrile in the presence of a heterogenous catalyst, which comprises feeding a solution of the phthalonitrile in the corresponding isomer of crude xylylenediamine into the hydrogenation reactor, with the crude xylylenediamine having a purity in the range from 85 to 99.7% by weight and a content of higher boilers in the range from 0.3 to 15% by weight.

公开(公告)号：SA1191B1

公开(公告)日：2006-08-22

申请号：SA00210599

申请日：2000-12-05

Applicant: BASF AG

Inventor： HOLST THOMAS I ,  HUGO RANDOLF ,  WAGNER ROBERT

IPC: B01D53/14 ,  C10K1/14 ,  C10L3/10

Abstract: الملخص: يتضمنهذاالإختراعإزالة COS إنتقائيابالنسبةإلى CO2 منتياراتموائع hydrocarbonaceous التيتحتويعلى CO2 وCOS. تتضمنأمثلةعلىالتيارالمائعتيارغاز،مثلالغازالطبيعي،غازمخلقمنزيتثقيلأوبقاياثقيلةأوغازمكررأومنسائلأومن hydrocarbons مسالةمثل Liquefied) Petroleum Gas) LPG غازبتروليمسالأو Natural Gas Liquids) NGL) سوائلغازطبيعي.تجرىالعمليةبواسطة (١) اتصالجيدللتيارالمائعفيمنطقةإستخلاصأوامتصاصمعسائلغسيلمتكونمنمحلول amine يحتويعلى 1,5-٥جزئجرامي/ لترلمركب aliphatic alkanolamine لهمن٢-carbonatoms١٢و 0,8- 1,7 جزئجرامي/ لترمنعلىالأقلعاملمنشطواحدمختارمنالمجموعةالمتكونةمنmethyl piperazine .،piperazineو morpholine، (٢) إزالةجوهريا COS بالكاملمنتيارالمائعو(٣) فصلجوهرياالتيارالمائعالمزالتلوثهمع COS وسائلالغسيلالمحملمع cos وتفريغهمامنمنطقةالإمتصاصأوالإستخلاص.،

公开(公告)号：DE102005003315A1

公开(公告)日：2006-08-03

申请号：DE102005003315

申请日：2005-01-24

Applicant: BASF AG

Inventor： ERNST MARTIN ,  HAHN THILO ,  WENZ KIRSTEN ,  HUGO RANDOLF ,  MELDER JOHANN-PETER

IPC: C07C209/48 ,  B01J23/86 ,  C07C211/51

Abstract: A process for preparing a xylylenediamine by heterogeneously catalyzed hydrogenation of a phthalonitrile, wherein the hydrogenation is carried out in the presence of a cobalt skeletal catalyst, of an alkali metal hydroxide and of an alcohol and/or ether as the solvent, at an absolute pressure in the range from 1 to 100 bar and a temperature in the range from 40 to 150° C.

公开(公告)号：DE10341615A1

公开(公告)日：2005-04-28

申请号：DE10341615

申请日：2003-09-10

Applicant: BASF AG

Inventor： WENZ KIRSTEN ,  JOURDAN SABINE ,  HUGO RANDOLF ,  MELDER JOHANN-PETER ,  PREISS THOMAS

IPC: C07C209/48 ,  C07C211/27 ,  C07C209/82

公开(公告)号：NO20021590D0

公开(公告)日：2002-04-04

申请号：NO20021590

申请日：2002-04-04

Applicant: BASF AG

Inventor： WAGNER RUPERT ,  HUGO RANDOLF ,  HOLST THOMAS S

IPC: B01D53/14 ,  C10K1/14 ,  C10L3/10 ,  B01D

Abstract: COS is selectively removed with respect to CO2 from a hydrocarbonaceous fluid stream which contains CO2 and COS. Examples of the fluid stream include a gas stream, for example natural gas, synthesis gas from heavy oil or heavy residues or refinery gas, or from liquid or liquefied hydrocarbons, for example LPG (Liquefied Petroleum Gas) or NGL (Natural Gas Liquids). The process is carried out by (1) intimately contacting the fluid stream in an absorption or extraction zone with a scrubbing liquor consisting of an aqueous amine solution containing from 1.5 to 5 mol/l of an aliphatic alkanolamine having of from 2 to 12 carbon atoms and from 0.8 to 1.7 mol/l of at least one activator selected from the group consisting of piperazine, methyl piperazine and morpholine, (2) removing the COS essentially completely from the fluid stream, and (3) separating the substantially COS-decontaminated fluid stream and the COS-loaded scrubbing liquor and discharging them from the absorption or extraction zone.

公开(公告)号：PE20010848A1

公开(公告)日：2001-08-10

申请号：PE0010412000

申请日：2000-10-03

Applicant: BASF AG

Inventor： HUGO RANDOLF ,  WAGNER RUPERT ,  HOLST THOMAS S

IPC: B01D11/04 ,  B01D53/14 ,  C10K1/14 ,  C10L3/10

Abstract: EN DONDE LA CORRIENTE DE FLUIDOS CONTIENE CO2, IMPUREZAS COMO H2S Y MERCAPTANOS, Y COS PROVENIENTE DE CORRIENTES DE GAS NATURAL, GAS DE SINTESIS DE CRUDO PESADO O RESIDUOS PESADOS O GAS DE REFINERIA, O DE HIDROCARBUROS LIQUIDOS O LICUADOS COMO GAS LICUADO DE PETROLEO O LIQUIDO DE GAS NATURAL; Y EL LICOR DE LAVADO COMPRENDE UNA SOLUCION ACUOSA DE AMINA QUE CONTIENE DE 1,5 A 5 MOLES/L DE UNA ALCANOLAMINA TERCIARIA ALIFATICA C2-C12, Y DE 0,8 A 1,7 MOLES/L DE UN ACTIVADOR QUE COMPRENDE UN N-HETEROCICLO SATURADO DE 5 o 6 MIEMBROS EL CUAL CONTIENE OPCIONALMENTE HETEROATOMOS ADICIONALES COMO OXIGENO Y NITROGENO . LA REMOCION COMPRENDE: a) PONER EN CONTACTO LA CORRIENTE DE FLUIDOS Y EL LICOR DE LAVADO, EN UNA ZONA DE ABSORCION O EXTRACCION; b) REMOVER EN FORMA COMPLETA EL COS DE DICHA CORRIENTE; Y, c) SEPARAR LA CORRIENTE DESCONTAMINADA Y EL LICOR CARGADO DE COS, Y DESCARGARLOS DE LA ZONA DE ABSORCION O EXTRACCION, RECICLANDO DICHO LICOR. EL CONTENIDO DE AMINA DEL LICOR DE LAVADO ES DE 20% A 70% EN PESO, DONDE LA ALCANOLAMINA USADA ES METILDIETANOLAMINA O TRIETANOLAMINA. EL ACTIVADOR SELECCIONADO PUEDE SER MONOETANOLAMINA, MONOMETIL-ETANOLAMINA, DIETANOLAMINA, PIPERAZINA, METILPIPERAZINA O MORFOLINA

公开(公告)号：DE59607121D1

公开(公告)日：2001-07-26

申请号：DE59607121

申请日：1996-08-30

Applicant: BASF AG

Inventor： HERMELING DR ,  HUGO RANDOLF ,  SIEGEL DR

IPC: C07F9/02 ,  C07F9/53

Abstract: A process for purifying tert. phosphine oxides of formula (R )(R )(R )P = O (I) in which R , R and R = 1-12 C alkyl, 5-8 FC cycloalkyl, aryl, 7-20 C aralkyl or 7-20 C alkylaryl, comprises reacting the (I) or a (I)-contg. mixt., opt. in an inert solvent, with an (in)organic acid at 0-150 degrees C and subsequently reacting the resulting salt with water or an (in)organic base. Pref. reaction with the acid is pref. carried out in an inert solvent such as aromatic hydrocarbons, aliphatic hydrocarbons, cycloaliphatic hydrocarbons or aromatic nitriles. Suitable acids are eg mineral acids such as HCl, HClO4, H2SO4 or H3PO4, Lewis acids such as BF3 or AlCl3, or organic acids such as acetic acid, formic acid or oxalic acid. The ratio acid to impure (I) is pref. 0.3 : 1 to 20 : 1, esp. 0.7 : 1 to 2 : 1. After crystallisation, the salt is recovered eg by filtration or centrifuging. The free (I) is liberated by treating the salt eg with an (in)organic base, esp. an aq. soln. of a base such as NaOH, KOH, Na2CO3, NH3, triethylamine, etc. The (I) is recovered e.g. by extraction with an inert solvent in the usual way.