11.
    发明专利
    未知

    公开(公告)号:DE2355840A1

    公开(公告)日:1975-05-22

    申请号:DE2355840

    申请日:1973-11-08

    Applicant: BASF AG

    Abstract: A process for the manufacture of improved magnetic discs by applying a thin layer of a fluid dispersion of magnetic pigments and optional non-magnetic pigments in a binder mixture to a non-magnetic rigid base and curing the magnetic layer which has been applied. The binder consists essentially of from 60 to 90 percent by weight of a solid curable polycondensate of 2,2-bis-(4-hydroxyphenyl)-propane and epichlorohydrin having an epoxide equivalent weight of approximately 400 to 5,000, from 5 to 25 percent by weight of a curable allyloxybenzene-formaldehyde condensate of the resol type with free or alcohol-etherified methylol groups and a molecular weight of less thah 1,000, and from 5 to 30 percent by weight of a curable melamine-formaldehyde condensate with more than two alcohol-etherified methylol groups and a molecular weight of less than 3,000, from 10 to 35 percent by weight of the above epoxy resin being replaced by a reaction product of an epoxy group-containing polycondensate of 2,2-bis-(4-hydroxyphenyl)-propane and epichlorohydrin with the N-methylolamide of a copolymerizable olefinically unsaturated carboxylic acid of 3 to 5 carbon atoms. The magnetic layers thus produced adhere firmly to the base, can be readily ground and polished and are particularly resistant to wear when the magnetic discs are in use.

    Magnetic recording tape with backing layer - contg. polymeric binder, carbon black and fillers, giving resistance to dust, and improved bonding

    公开(公告)号:DE2364878A1

    公开(公告)日:1975-07-03

    申请号:DE2364878

    申请日:1973-12-28

    Applicant: BASF AG

    Abstract: A magnetic recording tape consists of a non-magnetic carrier film, a magnetic layer contg. a finely divided magnetic pigment in a binder, and on the back of the carrier a non-magnetic backing layer, with higher electrical conductivity than the carrier, consisting of a mixt. of (A) an organic polymeric binder and (B) a powder mixt. of (a) 15-60 (15-35) pts. wt. conducting carbon black particles, (bi) 5-40(25-35) pts. of a reaction rpod. of montmorillonite, Al2(OH)2 Si4O10 .H2O, with an alkylammonium base, or (b2) 15-85 pts. of a powdered mixt. of 15-90(24-31) wt. % flaky silicate particles with Mohs hardness >6(>5) and 85-10 wt. % cubic or spherical particles of hard, durable oxides of Al, Si and/or Cr, and (c) 20-55 pts. wt. of a finely divided inorganic non-magnetic filler. The backing layer resists rapid coiling of the tape, is not sensitive to dust, and has improved bonding and crack-resistance. (A) The binder is esp. an elastomeric polyurethane free from NCO, prepd. from a polyester of a 4-6C aliphatic dicarboxylic acid and 3-10C diol, and a 6-24C (8-20C) diisocyanate, with a glycol extender; the polyurethane may be mixed with is not >40 (10-30) wt. % of other binders, e.g. vinyl(idene) chloride polymers or an epoxy resin, esp. from bisphenol A and epichlorohydrin. Copolymers of 70-95(75-90) wt. % vinyl chloride and 50-5% of a 1-3C alkyl ester of a 3-5C unsatd. acid may also be used as binder, e.g. a copolymer of 70-90% vinyl chloride, 5-15% dimethyl maleate and 5-15% diethyl maleate.

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