公开(公告)号：AT76647T

公开(公告)日：1992-06-15

申请号：AT89111191

申请日：1989-06-20

Applicant: BASF AG

Inventor： MUEHLENBERND THOMAS DR ,  HASENBEIN NORBERT DR

IPC: C08F8/44 ,  C08F210/00 ,  C08F210/02 ,  C08F220/00 ,  C08F220/04

公开(公告)号：DE3830007A1

公开(公告)日：1990-03-15

申请号：DE3830007

申请日：1988-09-03

Applicant: BASF AG

Inventor： HASENBEIN NORBERT DR ,  MUEHLENBERND THOMAS DR ,  KOEHLER GERNOT DR

IPC: C08F2/44 ,  C08F8/00 ,  C08F8/32 ,  C08F210/02

Abstract: A high molecular weight ethylene copolymer is prepared by high-pressure copolymerization of ethylene with an alpha , beta -ethylenically unsaturated carboxylic acid, carboxylic anhydride or a derivative thereof in the presence of a tertiary organic monoamine, preferably from 10 to 100 mol % thereof, based on the unsaturated carboxylic acid used, and can be used for preparing adhesion promoters and cable sheathing.

公开(公告)号：ES2048800T3

公开(公告)日：1994-04-01

申请号：ES89115873

申请日：1989-08-29

Applicant: BASF AG

Inventor： HASENBEIN NORBERT DR ,  MUHLENBERND THOMAS DR ,  KOEHLER GERNOT DR

IPC: C08F2/44 ,  C08F8/00 ,  C08F8/32 ,  C08F210/02

Abstract: A high molecular weight ethylene copolymer is prepared by high-pressure copolymerization of ethylene with an alpha , beta -ethylenically unsaturated carboxylic acid, carboxylic anhydride or a derivative thereof in the presence of a tertiary organic monoamine, preferably from 10 to 100 mol % thereof, based on the unsaturated carboxylic acid used, and can be used for preparing adhesion promoters and cable sheathing.

公开(公告)号：DE58906979D1

公开(公告)日：1994-03-24

申请号：DE58906979

申请日：1989-08-29

Applicant: BASF AG

Inventor： HASENBEIN NORBERT DR ,  MUEHLENBERND THOMAS DR ,  KOEHLER GERNOT DR

IPC: C08F2/44 ,  C08F8/00 ,  C08F8/32 ,  C08F210/02

Abstract: A high molecular weight ethylene copolymer is prepared by high-pressure copolymerization of ethylene with an alpha , beta -ethylenically unsaturated carboxylic acid, carboxylic anhydride or a derivative thereof in the presence of a tertiary organic monoamine, preferably from 10 to 100 mol % thereof, based on the unsaturated carboxylic acid used, and can be used for preparing adhesion promoters and cable sheathing.

公开(公告)号：AT101624T

公开(公告)日：1994-03-15

申请号：AT89115873

申请日：1989-08-29

Applicant: BASF AG

Inventor： HASENBEIN NORBERT DR ,  MUEHLENBERND THOMAS DR ,  KOEHLER GERNOT DR

IPC: C08F2/44 ,  C08F8/00 ,  C08F8/32 ,  C08F210/02

公开(公告)号：DE3786884D1

公开(公告)日：1993-09-09

申请号：DE3786884

申请日：1987-11-19

Applicant: BASF AG

Inventor： HASENBEIN NORBERT DR ,  BAUER PETER ,  SCHLEMMER LOTHAR ,  HAUSS ALFRED FRIEDRICH DR ,  GROPPER HANS DR ,  OHLINGER RAINER DR

IPC: C08F2/02 ,  C08F8/44 ,  C08F255/02 ,  C09J4/00 ,  C09J151/06

Abstract: Grafting of ethylenically unsatd. acids or anhydrides (or their derivs.) onto ethylene homo- or co-polymers of density 0.930 g/cc or higher is carried out in a conventional extruder or mixer at 1-500 bar in the absence of a catalyst which decomposes to give radicals. This is achieved by mixing 0.01-0.5 wt. pts. of the grafting monomer with 100 wt. pts. of molten ethylene polymer at 140 deg.C or above and then carrying out grafting at 210-300 deg.C..

公开(公告)号：AT76648T

公开(公告)日：1992-06-15

申请号：AT89111193

申请日：1989-06-20

Applicant: BASF AG

Inventor： MUEHLENBERND THOMAS DR ,  HASENBEIN NORBERT DR ,  KOEHLER GERNOT DR ,  SCHLEMMER LOTHAR

IPC: C08F8/44 ,  C08F210/00 ,  C08F210/02 ,  C08F220/00 ,  C08F220/04

公开(公告)号：DE3844047A1

公开(公告)日：1990-07-05

申请号：DE3844047

申请日：1988-12-28

Applicant: BASF AG

Inventor： HASENBEIN NORBERT DR ,  MUEHLENBERND THOMAS DR ,  KOEHLER GERNOT DR

IPC: C08F2/00 ,  C08F2/02 ,  C08F210/02 ,  C08F210/16

Abstract: The copolymers comprise from 96 to 99.6 mol% of ethylene and from 0.4 to 4 mol% of a C3-C6-alkenecarboxylic acid or an ester of this acid having a total of up to 14 carbon atoms, or mixtures of these monomers, and are obtainable by polymerisation in a continuous tubular reactor at a pressure of from 500 to 5000 bar and at elevated temperature in the presence of initiators which decompose to form free radicals, by adding a mixture of said reaction components only at the inlet point of the tubular reactor, the temperature in a first reaction zone being limited to about 240 DEG C, further initiator being metered in at the beginning of a second reaction zone after the temperature has been reduced by from 5 to 20 DEG C, and the reaction being completed at temperatures of up to 300 DEG C.

公开(公告)号：AT92504T

公开(公告)日：1993-08-15

申请号：AT87117082

申请日：1987-11-19

Applicant: BASF AG

Inventor： HASENBEIN NORBERT DR ,  BAUER PETER ,  SCHLEMMER LOTHAR ,  HAUSS ALFRED FRIEDRICH DR ,  GROPPER HANS DR ,  OHLINGER RAINER DR

IPC: C08F2/02 ,  C08F8/44 ,  C08F255/02 ,  C09J4/00 ,  C09J151/06

公开(公告)号：DE58901527D1

公开(公告)日：1992-07-02

申请号：DE58901527

申请日：1989-06-20

Applicant: BASF AG

Inventor： HASENBEIN NORBERT DR ,  SCHLEMMER LOTHAR ,  MUEHLENBERND THOMAS DR ,  KOEHLER GERNOT DR

IPC: C08F8/44 ,  C08F210/00 ,  C08F210/02 ,  C08F220/00 ,  C08F220/04

Abstract: The invention relates to a process for the preparation of ionically crosslinked ethylene copolymers by mixing the carboxyl group-containing copolymers with an aqueous metal salt solution in the reaction zone of a twin-screw extruder and transferring the reaction mixture into a degassing zone, to an ionically crosslinked ethylene copolymer, and to its use as a coupling agent, injection-moulded article or coating film.