PREPARACION DE ESTERES 2-CIAN-3,3-DIARILACRILICOS.

    公开(公告)号:MX9708836A

    公开(公告)日:1998-03-31

    申请号:MX9708836

    申请日:1996-05-24

    Applicant: BASF AG

    Abstract: Un proceso para preparar los ésteres 2-ciano-3,3-diarilacrílicos de la formula general I, en donde R1 y R2 son hidrogeno, grupos alquilo de C1-C12, grupos alcoxi de C1-C12 o grupos dialquil (de C1-C4)amino y R3 es un grupo alquilo de C4-C18 que puede ser interrumpido por átomos de oxígeno que funcionan comoéter, haciendo reaccionar una benzofenona imina de la formula general II, con un éster cianoacético de la formula general III, en donde la reaccion se lleva a cabo desde 20 a 60 degree C y, durante ésta, el amoniaco liberado se elimina continuamente de la mezcla de reaccion con la ayuda de una corriente de gas o reduciendo la presion de 900 a 100 mbar.

    16.
    发明专利
    未知

    公开(公告)号:DK0683785T3

    公开(公告)日:1997-10-13

    申请号:DK94905731

    申请日:1994-01-29

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP94/00254 Sec. 371 Date Aug. 9, 1995 Sec. 102(e) Date Aug. 9, 1995 PCT Filed Jan. 29, 1994 PCT Pub. No. WO94/18210 PCT Pub. Date Aug. 18, 1994Aminovinylphosphonic esters I where R1 is cyano, a radical of the formula -CO-OR6 or a group of the formula R2, R3 and R6 are C1-C20-alkyl, C5-C8-cycloalkyl, C7-C18-aralkyl, phenyl or tolyl, R4 is an unsubstituted or substituted phenyl or heterocyclic group defined below R5 is hydrogen or C1-C12-alkyl, R7 is hydrogen, C1-C6-alkyl, formyl, C2-C6-alkanoyl, C1-C12-alkoxy, C5- or C6-cycloalkoxy, cyanomethyl, 2-hydroxyethyl, benzyl or a radical of the formula -CR8=CH-CO-OR6, R8 is hydrogen, C1-C6-alkyl or a radical of the formula -CO-OR6, and X is oxygen or NH, are used as light, oxygen and heat stabilizers for organic material.

    18.
    发明专利
    未知

    公开(公告)号:NO972157D0

    公开(公告)日:1997-05-09

    申请号:NO972157

    申请日:1997-05-09

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP95/04313 Sec. 371 Date May 12, 1997 Sec. 102(e) Date May 12, 1997 PCT Filed Nov. 3, 1995 PCT Pub. No. WO96/15184 PCT Pub. Date May 23, 1996The use of 3-arylacrylic esters I (I) where Ar is an aryl radical which can additionally carry substituents, R1 is the residue of an n-hydric aliphatic polyol having up to 20 carbon atoms, where the carbon chain can be interrupted by up to 9 non-adjacent oxygen atoms, or of an n-hydric cyclo-aliphatic polyol having 5 to 20 carbon atoms in which ring carbon atoms can also be replaced by non-adjacent oxygen atoms, R2 and R3 are hydrogen or C1-C4-alkyl, and n is a number from l to 10, as stabilizers, in particular against the action of light, for non-living organic material.

    20.
    发明专利
    未知

    公开(公告)号:DE19519894A1

    公开(公告)日:1996-12-05

    申请号:DE19519894

    申请日:1995-05-31

    Applicant: BASF AG

    Abstract: A process for producing 2-cyano-3,3-diary acrylic acid esters of general formula (I) in which R and R are hydrogen, C1-C12 alkoxy groups or di-(C1-C4 alkyl) amino groups and R is a C4-C18 alkyl group which may be interrupted by oxygen atoms in the ether function, by the reaction of benzophenonimine of general formula (II) with a cyanic acid ester of general formula (III), in which the reaction is conducted at 20 to 60 DEG C and the ammonia released is continuously removed from the reaction mixture with the aid of a stream of gas or by reducing the pressure to 900 to 100mbar.

Patent Agency Ranking