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公开(公告)号:GB936355A
公开(公告)日:1963-09-11
申请号:GB1125061
申请日:1961-03-28
Applicant: BASF AG
Inventor: LORENZ ERNST , HIEMENZ WILHELM
Abstract: In a process for the catalytic pressure refining of light oils obtained by gasification, coking, low-temperature carbonization or cracking of liquid or solid fuels with hydrogen or hydrogen-containing gases, the raw materials which contain compounds capable of polymerization and/or condensation are heated up and introduced into a hot stream of hydrogen or hydrogen-containing gases in the form of such a fine mist that an immediate vaporization of the raw materials occurs, the heating-up and vaporization being carried out so rapidly that the speed of the heating-up and vaporization process exceeds the polymerization and/or condensation speed in the liquid phase, and the resultant mixture is heated up to reaction temperature and subjected to catalytic hydrogenative refining, for example over a cobalt-molybdenum-alumina catalyst. The raw material may be sprayed into a preheated gas stream by means of an injection nozzle or atomizer, which is desirably cooled, and may be provided with a filter. A prerefining catalyst may be interposed before or in the heating-up zone.
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公开(公告)号:FR1271834A
公开(公告)日:1961-09-15
申请号:FR840135
申请日:1960-10-03
Applicant: BASF AG
Inventor: HORING MARIA , REITZ ORTWIN , TOUSSAINT HERBERT , LORENZ ERNST , HIEMENZ WILHELM
IPC: C07C7/00
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公开(公告)号:DE1418275A1
公开(公告)日:1968-11-07
申请号:DE1418275
申请日:1959-07-20
Applicant: KOPPERS GMBH HEINRICH , BASF AG
Inventor: SATTLER EMIL , LORENZ ERNST
IPC: C07C7/163
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公开(公告)号:FR1278393A
公开(公告)日:1961-12-08
申请号:FR850120
申请日:1961-01-19
Applicant: BASF AG
Inventor: REITZ ORTWIG , LORENZ ERNST , HOERING MARIA
IPC: C07C7/163
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公开(公告)号:FR1274151A
公开(公告)日:1961-10-20
申请号:FR844752
申请日:1960-11-23
Applicant: BASF AG , HARPENER BERGBAU AG , SCHOLVENCHEMIE AG
Inventor: REITZ ORTWIN , LORENZ ERNST , ENGEL ERICH , URBAN WILHELM , SCHMIDT PAUL
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公开(公告)号:CA1129394A
公开(公告)日:1982-08-10
申请号:CA320147
申请日:1979-01-23
Applicant: BASF AG
Inventor: GALLEI EWALD , MAROSI LASZLO , SCHWARZMANN MATTHIAS , LORENZ ERNST
Abstract: A process for the manufacture of a bifunctional catalyst for the conversion of hydrocarbons, which contains a crystalline aluminosilicate of the type of the Y-zeolites as the acidic component and a noble metal as the hydrogenation component. The process constitutes a technologically simple way of manufacturing bifunctional zeolite catalysts which have at least the same activity and the same life as the catalysts manufactured by conventional methods, coupled with great heat stability and exhibit activity in the presence of H2O, H2S and NH3 at relatively high temperatures.
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公开(公告)号:GB1165064A
公开(公告)日:1969-09-24
申请号:GB92667
申请日:1967-01-06
Applicant: BASF AG
Inventor: NONNENMACHER HELMUT , LORENZ ERNST , WODTCKE FRIEDRICH , REITZ ORTWIN
Abstract: 1,165,064. Refining catalysts. BADISCHE ANILIN-& SODA-FABRIK A.G. 6 Jean., 1967 [8 Jan., 1966], No. 926/67. Heading B1E. [Also in Division C5] A catalyst for the selective hydrofining of pyrolysis gasolines comprises metallic Co and/ or Ni with a small amount of Pd on a carrier having an internal surface area of more than 100 sq. m/g. The carrier may be an active Al 2 O 3 , e.g. boehmite, or a silicate of Mg, Zn, or Al. The content of Co and/or Ni may be from 5-35% and the content of Pd may be 0.01-0.1% by weight.
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公开(公告)号:GB1105157A
公开(公告)日:1968-03-06
申请号:GB2913265
申请日:1965-07-09
Applicant: BASF AG
Inventor: NONNENMACHER HELMUT , LORENZ ERNST , WODTCKE FRIEDRICH , REITZ ORTWIN
Abstract: A process for the continuous selective refining of gasolines which have been obtained by pyrolytic cracking of mineral oils or fractions thereof in the presence of hydrogen at elevated temperature and superatmospheric pressure wherein a catalyst is used which contains metallic cobalt with an addition of copper and/or molybdenum oxide supported on a carrier having a specific surface of 100 m.2/gm. or more. The carrier may be a silicate of zirconium, titanium, magnesium or zinc or mixtures thereof, and/or aluminium oxide. A silicate of cobalt may be used, the silicic acid formed by reduction acting as a carrier. The reaction temperature may be 50-250 DEG C., the catalyst loading 0.5 to 5 kg. of gasoline per litre of catalyst per hour, and the ratio of hydrogen to gasoline should be low but not less than 100 litres/kg.; the pressure is such that most of the gasoline is in the liquid phase.
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公开(公告)号:FR1507609A
公开(公告)日:1967-12-29
申请号:FR90270
申请日:1967-01-06
Applicant: BASF AG
Inventor: NONNENMACHER HELMUT , LORENZ ERNST , WODTCKE FRIEDRICH , REITZ ORTWIN
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公开(公告)号:GB899695A
公开(公告)日:1962-06-27
申请号:GB4023060
申请日:1960-11-23
Applicant: BASF AG , HARPENER BERGBAU AG , SCHOLVEN CHEMIE AG
Inventor: REITZ ORTWIN , LORENZ ERNST , ENGEL ERICH , URBAN WILHELM , SCHMIDT PAUL
Abstract: The hydrofining of hydrocarbons, such as crude benzene or sulphur-containing unsaturated gasolines, obtained from the coking, low temperature carbonization or gasification of solid or liquid fuels is effected in the presence of two or more catalysts having different selective activities of which one comprises at least on compound of a Group V or VI metal together with a compound of nickel and/or cobalt and another comprises at least one compound of a Group V or VI metal alone or with a compound of iron. The two catalysts may be mixed or used in series. The former catalysts may comprise the oxides and/or sulphides of vanadiu, molybdenum, tungsten and chromium with an oxide and/or sulphide of nickel or cobalt, the relative proportions being about equal; the catalyst may form 1-20% by weight of a composition, the remainder being a carrier, e.g. alumina magnesia, zinc oxide, titania, silicic acid, a silicate, zirconia or cerium oxide, any of which may be pretreated with hydrogen, hydrogen fluoride, chloride or iodide, a mineral acid or a low molecular weight organic acid. The other catalyst may comprise an oxide and/or sulphide and/or halide of molybdenum, vanadium, chromium or tungsten together with a minor proportion of an oxide, sulphide, halide, formate, acetate or oxalate of iron, if desired. This catalyst may also be carried on a support. Suitable conditions are 300 DEG -450 DEG C., 5-200 atmospheres and 0,3-6 Kg. of hydrocarbon per litre of catalyst per hour, the hydrogenating gas being hydrogen, cokeoven gas, water gas or town gas. The process removes sulphur compounds and reduces the olefin content.ALSO:The hydrofining of hydrocarbons, such as crude benzene or sulphur-containing unsaturated gasolines, obtained from the coking, low temperature carbonisation or gasification of solid or liquid fuels is effected in the presence of two or more catalysts having different selective activities of which one comprises at least one compound of a Group 5 or 6 metal together with acompound of nickel and/or cobalt and another comprises at least one compound of a Group 5 or 6 metal alone or with a compound of iron. The two catalysts may be mixed or used in series. The former catalysts may comprise the oxides and/or sulphides of vanadium, molybdenum, tungsten and chromium with an oxide and/or sulphide of nickel or cobalt, the relative proportions being about equal; the catalyst may form 1%-20% by weight of a composition, the remainder being a carrier, e.g. alumina, magnesia, zinc oxide, titania, silicic acid, a silicate, zirconia or cerium oxide, any of which may be pretreated with hydrogen, hydrogen fluoride, chloride or iodide, a mineral acid or a low molecular weight organic acid. The other catalyst may comprise an oxide and/or sulphide and/or halide of molybdenum, vanadium, chromium or tungsten together with a minor proportion of an oxide, sulphide, halide, formate, acetate or oxalate of iron, if desired. This catalyst may also be carried on a support. Suitable conditions are 300 DEG C.-450 DEG C., 5-200 atmospheres and 0.3-6 Kg. of hydrocarbon per litre of catalyst per hour, the hydrogenating gas being hydrogen, coke-oven gas, water gas or town gas. The process removes sulphur compounds and reduces the olefin content.
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