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公开(公告)号:AU8074775A
公开(公告)日:1976-11-04
申请号:AU8074775
申请日:1975-05-02
Applicant: BASF AG
Inventor: VOSS HARRO , MOELLER ROLF , SCHICK RUPERT , STAHNECKER ERHARD
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公开(公告)号:AU2825677A
公开(公告)日:1979-03-01
申请号:AU2825677
申请日:1977-08-26
Applicant: BASF AG
Inventor: KEPPLER HANS GEORG , STAHNECKER ERHARD , MOELLER ROLF
Abstract: Process for the manufacture of styrene polymers optionally containing blowing agent by polymerization in aqueous suspension using as the suspension stabilizer a calcium phosphate which after its manufacture by precipitation has been heated in aqueous dispersion for at least 2 hours at from 70 DEG to 130 DEG C. The styrene polymers may be used for the manufacture of foams.
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公开(公告)号:CA1046700A
公开(公告)日:1979-01-16
申请号:CA226046
申请日:1975-05-01
Applicant: BASF AG
Inventor: VOSS HARRO , MOELLER ROLF , SCHICK RUPERT , STAHNECKER ERHARD
Abstract: The present invention relates to novel coating agents based on mono- and/or poly- urethanes melting below 150.degree.C for expandable particulate styrene polymers. These agents have no detrimental effect on the styrene polymers, lead to very fast-cooling moldings showing uniform density distribution throughout and good fusion, and give higher space/time yields during prefoaming.
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公开(公告)号:AU2165277A
公开(公告)日:1978-08-03
申请号:AU2165277
申请日:1977-01-26
Applicant: BASF AG
Inventor: KEPPLER HANS GEORG , MOELLER ROLF , STAHNECKER ERHARD
Abstract: Styrene polymers are prepared by suspension polymerization using, as suspension stabilizers, mixtures of (A) a sparingly soluble inorganic metal compound and (B) a fine polymer dispersion. The styrene polymers may be used, together with blowing agents, for the manufacture of foams.
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公开(公告)号:AU5408073A
公开(公告)日:1974-10-10
申请号:AU5408073
申请日:1973-04-04
Applicant: BASF AG
Inventor: ZUERN LUDWIG , STAHNECKER ERHARD , FRIED MICHAEL , MOELLER ROLF
IPC: C08F2/00 , C08F20060101 , C08F2/04 , C08F2/10 , C08F26/00 , C08F26/08 , C08F26/10 , C08F7/12 , C08F1/60 , C08F1/76 , C08F1/78
Abstract: Solutions of N-vinylpyrrolidone polymers can be prepared with particular advantage by polymerization of N-vinylpyrrolidone in an aqueous medium by adding the polymerization catalyst in portions or continuously to the monomer solution in the form of a finely divided suspension in an aqueous solution of N-vinylpyrrolidone polymer.
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公开(公告)号:AU4811372A
公开(公告)日:1974-04-26
申请号:AU4811372
申请日:1972-10-25
Applicant: BASF AG
Inventor: STAHNICKER IERHARD , RUPPERT GEORG , MOELLER ROLF , SCHICK RUPERT , ZUERN LUDWIG
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公开(公告)号:CA847415A
公开(公告)日:1970-07-21
申请号:CA847415D
Applicant: BASF AG
Inventor: HINTZ HANS , MOELLER ROLF , WEBER HEINZ
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公开(公告)号:GB1090121A
公开(公告)日:1967-11-08
申请号:GB612665
申请日:1965-02-12
Applicant: BASF AG
Inventor: STAHNECKER ERHARD , MOELLER ROLF
IPC: C08J9/224
Abstract: Expandable finely-particled synthetic resin material comprises a styrene polymer and an expanding agent wherein the particles are coated with 0.005 to 0.5% by weight (with reference to the material) of a polymer containing an hydrophilic group and having a softening point more than 30 DEG C. The styrene polymer may be polystyrene or a copolymer of styrene with one or more other a ,b -unsaturated polymerizable compounds containing at least 50% by weight of styrene units. The expanding agent may be normally gaseous or liquid hydrocarbons or halo-hydrocarbons which do not dissolve the styrene polymers and whose boiling-points are below the softening points of the polymers, e.g. propane, butane, pentane, hexane, cyclohexane, dichlorodifluoromethane or trifluorochloromethane. The preferred amount of expanding agent is 2 to 10% by weight of the styrene polymer. The preferred amount of hydrophilic polymer is 0.01 to 0.1% by weight and it may be a polymerizate, polycondensate or polyadduct containing hydroxyl, carboxyl, amino, amido or ether groups, e.g. a condensation product of hexanetriol and phthalic acid, alkaline condensation product of methylcyclohexanone, condensation product of glycerine and an adduct of acrylic acid to colophony or a condensation product of dipropylene triamine and an adduct of acrylic acid to colophony. The synthetic resin material may be coated by applying a solution of the hydrophilic polymer to a finely-particled styrene polymer containing expanding agent and then evaporating the solvent.
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公开(公告)号:FR1463625A
公开(公告)日:1966-12-23
申请号:FR45943
申请日:1966-01-14
Applicant: BASF AG
Inventor: BUCHHOLZ KARL , STAHNECKER ERHARD , GROHMANN JOHANNES , MOELLER ROLF
IPC: C08F291/00 , C08J9/00 , C08J9/20
Abstract: 1,126,913. Expandable styrene polymers. BADISCHE ANILIN- & SODA-FABRIK A.G. 14 Jan., 1966 [16. Jan., 1965], No. 1819/66. Headings C3C and C3P. Particulate expandable styrene polymers are produced by polymerizing styrene with or without one or more olefinically unsaturated monomeric polymerizable compounds in aqueous suspension in the presence of an expanding agent and 0À001 to 1% by weight on the monomers of a water-insoluble polymer of a vinyl ester, vinyl ether, acrylic ester or methacrylic ester of molecular weight 10 4 to 10 6 which will dissolve in the monomers and which is not homogeneously miscible with the styrene polymers obtained. In examples styrene, with optionally acrylonitrile, was polymerized in an aqueous mixture of a copolymer of N-vinylpyrrolidone and methyl acrylate, sodium pyrophosphate, benzoyl peroxide; pentane, hexane, butane and/or dichlorofluoromethane; and either polyvinyl isobutyl ether, polymethyl acrylate or methacrylate, poly-2-ethylhexyl acrylate, polyvinyl acetate, a butyl acrylate/vinyl acetate copolymer, polyethyl acrylate or polyvinyl propionate.
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公开(公告)号:FR1424707A
公开(公告)日:1966-01-14
申请号:FR5482
申请日:1965-02-13
Applicant: BASF AG
Inventor: STAHNECKER ERHARD , MOELLER ROLF
IPC: C08J9/224
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