Abstract:
Free radical polymerizations are immediately terminated by adding a phenothiazine-containing solution whose solvent comprises at least 50% of its weight of an N-alkylpyrrolidone.
Abstract:
The invention relates to a method for intermediate termination of radical polymerisation by adding a solution containing phenothiazine, the solvent of which consists of at least 50 wt. % N-alkyl pyrrolidone.
Abstract:
The invention concerns a process for the esterification of (meth)acrylic acid with an alkanol, oxyesters formed as a by-product of esterification being cleaved in turn in an acid-catalysed manner by the addition of monomeric and/or oligomeric (meth)acrylic acid and water.
Abstract:
A supply system for feeding a fluid to a vessel (1) is described, which is provided with a feedline (10), having a reservoir which is filled with the fluid and a compressed-gas store (14) which can be brought into communication with this reservoir (13), in which system the reservoir (13) and the compressed-gas store (14) are arranged in immediate proximity to one another, and wherein the reservoir (13) can, when required, be brought into communication with the feedline (10) via connection pieces (11, 12).
Abstract:
An apparatus for introducing a fluid into a container includes a supply leading into the interior of the container, closed by a bursting disk and connected to a supply line for the fluid. In order to increase the operational safety and to avoid clogging of the bursting disk, the supply is in the form of a telescopic tube which can be extended by the pressure of the fluid into the interior of the container and is mounted above the highest level in the container.
Abstract:
In a process for esterifying (meth)acrylic acid with an alkanol, oxy ester formed as a byproduct of the esterification is recleaved under acid catalysis with addition of monomeric and/or oligomeric (meth)acrylic acid and water.
Abstract:
A process for the esterification of (meth)acrylic acid with an alkanol in presence of a catalyst, in which unreacted starting cpds. and the required ester are sepd. by distn. and a bottom prod. contg. an oxy-ester is obtd. The process involves taking off the bottom prod., sepn. of the oxy-ester by distn. and cleavage of the distillate in presence of acid (I) at elevated temp.
Abstract:
En un procedimiento para esterificar ácido (met)acrílico con un alcanol en presencia de un catalizador de esterificacion, en donde los compuestos iniciales no convertidos y el (met)acrilato a formar se separan mediante destilacion y se forma un producto de fondo que contiene oxiésteres, el producto de fondo se separa primero, los oxiésteres contenidos ahí se separan después mediante destilacion y el destilado resultante se disocian en presencia de ácidos a temperaturas elevadas. El procedimiento puede efectuarse en presencia de oxígeno molecular. El destilado se disocia a temperaturas ubicadas entre 170 y 250 degree C, de preferencia entre 180 a 230 degree C.
Abstract:
In a process for esterifying (meth)acrylic acid with an alkanol, oxy ester formed as a byproduct of the esterification is recleaved under acid catalysis with addition of monomeric and/or oligomeric (meth)acrylic acid and water.
Abstract:
An apparatus for introducing a fluid into a container includes a supply leading into the interior of the container, closed by a bursting disk and connected to a supply line for the fluid. In order to increase the operational safety and to avoid clogging of the bursting disk, the supply is in the form of a telescopic tube which can be extended by the pressure of the fluid into the interior of the container and is mounted above the highest level in the container.