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    12.
    发明专利
    未知

    公开(公告)号：ES2113422T3

    公开(公告)日：1998-05-01

    申请号：ES92900007

    申请日：1991-12-03

    Applicant: BASF AG

    Inventor： HAGEN HELMUT ,  NILZ GERHARD ,  WALTER HELMUT ,  LANDES ANDREAS

    IPC: A01N25/32 ,  A01N35/06 ,  A01N39/02 ,  A01N43/10 ,  C07D333/26 ,  C07D333/38 ,  C07D333/62 ,  C07D333/68 ,  C07D333/70 ,  C07D409/04 ,  C07D409/12 ,  C07D417/12

    Abstract: PCT No. PCT/EP91/02287 Sec. 371 Date Jun. 7, 1993 Sec. 102(e) Date Jun. 7, 1993 PCT Filed Dec. 3, 1991 PCT Pub. No. WO92/10094 PCT Pub. Date Jun. 25, 1992.A herbicidal composition containing one or more substituted 2-aminothiophenes of the formula I alkylene chain to which a benzene ring may be fused, R3 is -CN or CX-R6, where R6 is hydroxyl, C1-C4-alkoxy or amino, R4 is hydrogen or a phenyl group which may carry one or two nitro radicals, -PO(OR8)2, -CX-R9, -SO2R10, -CX-N(H) -CO-R8 or -CX-N(R7)-SO2-R11, where R8 is hydrogen, C1-C4-alkyl or phenyl group R9 is C1-C20-alkyl, partially or completely halogenated C1-C6-alkyl, C2-C6-alkenyl, C6-cycloalkyl, or amino, C1-C4-alkylamino, C3-C8-cycloalkylamino, phenyl or phenylamino, where the aromatic moiety may carry at least one of nitro and halogen; R10 is C1-C4-alkyl or phenyl, which may carry one C1-C4-alkyl radical; R11 is pyrrolidin-1-yl, piperidin-1-yl, morpholin-4-yl or piperazin-1-yl, where the heterocyclic structures may carry one C1-C4-group; R5 is hydrogen; or R4 and R5 together form a group =CR12R13 or -CO-W-CO-, where R12 is hydrogen, amino, C1-C4-alkylamino or C3-C8-cycloalkylamino; R13 is amino, C3-C8-cycloalkylamino, phenyl or pyridyl, where the two last mentioned substituents may carry at least one halogen or nitro radicals; W is an ethylene or ethenylene bridge, or a 6-membered 1,2-C-bonded aromatic bridge where these bridge members may carry, on each substitutable carbon atom, at least one halogen a 5-membered or 6-membered 1,2-C-bonded cycloalkylene or cycloalkenylene bridge, and the basic salts of the compounds I in which R3 is hydroxycarbonyl or hydroxythiocarbonyl, and the acidic salts of the compounds I which contain a basic nitrogen atom, as antagonistic compounds and one or more herbicidal active ingredients from the group consisting of the cyclohexenone derivatives of the formula III III

    13.
    发明专利
    未知

    公开(公告)号：DE59108941D1

    公开(公告)日：1998-04-02

    申请号：DE59108941

    申请日：1991-12-03

    Applicant: BASF AG

    Inventor： HAGEN HELMUT ,  NILZ GERHARD ,  WALTER HELMUT ,  LANDES ANDREAS

    IPC: A01N25/32 ,  A01N35/06 ,  A01N39/02 ,  A01N43/10 ,  C07D333/26 ,  C07D333/38 ,  C07D333/62 ,  C07D333/68 ,  C07D333/70 ,  C07D409/04 ,  C07D409/12 ,  C07D417/12

    Abstract: PCT No. PCT/EP91/02287 Sec. 371 Date Jun. 7, 1993 Sec. 102(e) Date Jun. 7, 1993 PCT Filed Dec. 3, 1991 PCT Pub. No. WO92/10094 PCT Pub. Date Jun. 25, 1992.A herbicidal composition containing one or more substituted 2-aminothiophenes of the formula I alkylene chain to which a benzene ring may be fused, R3 is -CN or CX-R6, where R6 is hydroxyl, C1-C4-alkoxy or amino, R4 is hydrogen or a phenyl group which may carry one or two nitro radicals, -PO(OR8)2, -CX-R9, -SO2R10, -CX-N(H) -CO-R8 or -CX-N(R7)-SO2-R11, where R8 is hydrogen, C1-C4-alkyl or phenyl group R9 is C1-C20-alkyl, partially or completely halogenated C1-C6-alkyl, C2-C6-alkenyl, C6-cycloalkyl, or amino, C1-C4-alkylamino, C3-C8-cycloalkylamino, phenyl or phenylamino, where the aromatic moiety may carry at least one of nitro and halogen; R10 is C1-C4-alkyl or phenyl, which may carry one C1-C4-alkyl radical; R11 is pyrrolidin-1-yl, piperidin-1-yl, morpholin-4-yl or piperazin-1-yl, where the heterocyclic structures may carry one C1-C4-group; R5 is hydrogen; or R4 and R5 together form a group =CR12R13 or -CO-W-CO-, where R12 is hydrogen, amino, C1-C4-alkylamino or C3-C8-cycloalkylamino; R13 is amino, C3-C8-cycloalkylamino, phenyl or pyridyl, where the two last mentioned substituents may carry at least one halogen or nitro radicals; W is an ethylene or ethenylene bridge, or a 6-membered 1,2-C-bonded aromatic bridge where these bridge members may carry, on each substitutable carbon atom, at least one halogen a 5-membered or 6-membered 1,2-C-bonded cycloalkylene or cycloalkenylene bridge, and the basic salts of the compounds I in which R3 is hydroxycarbonyl or hydroxythiocarbonyl, and the acidic salts of the compounds I which contain a basic nitrogen atom, as antagonistic compounds and one or more herbicidal active ingredients from the group consisting of the cyclohexenone derivatives of the formula III III

    HERBICIDES CONTAINING SUBSTITUED 5-AMINOPYRAZOLS AS ANTIDOTES AND PROCESS FOR PRODUCING THE COMPOUNDS
    15.
    发明专利
    HERBICIDES CONTAINING SUBSTITUED 5-AMINOPYRAZOLS AS ANTIDOTES AND PROCESS FOR PRODUCING THE COMPOUNDS 未知

    公开(公告)号：HUT65435A

    公开(公告)日：1994-06-28

    申请号：HU172093

    申请日：1991-12-03

    Applicant: BASF AG

    Inventor： HAGEN HELMUT ,  NILZ GERHARD ,  LANDES ANDREAS ,  WALTER HELMUT

    IPC: A01N43/56 ,  A01N25/32 ,  C07D231/38 ,  C07D231/40 ,  C07D309/12 ,  C07D335/02 ,  C07D403/04

    Abstract: PCT No. PCT/EP91/02286 Sec. 371 Date Jun. 7, 1993 Sec. 102(e) Date Jun. 7, 1993 PCT Filed Dec. 3, 1991 PCT Pub. No. WO92/10480 PCT Pub. Date Jun. 25, 1992.Substituted 5-aminopyrazoles I I where R1 is C1-C8-alkyl, C1-C8-hydroxyalkyl, phenyl which may carry 1-3 of the following radicals: halogen, nitro, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio or -NR6R7, and which may additionally carry a number of halogen atoms so that the total number of radicals is 5, R6 and R7 are each H or C1-C4-alkyl, R2 is H, C1-C4-alkyl or C1-C4-haloalkyl, R3 is CN, -CO-R8 or -CS-R8, R8 is OH, C1-C4-alkoxy, NH2, C1-C4-alkylamino or di-C1-C4-alkylamino, R4 and R5 are each H, C1-C4-alkyl, PX(OR9)2, -SO2-R9, -CX-R10, -CX-NH-CY-R9 or CX-NH-SO2-R11, X and Y are each O or S, R9 is one of the substituents R1, R10 is C1-C20-alkyl, C1-C4-alkoxy, unsubstituted or substituted phenyl or unsubstituted or substituted NH2, R11 is NH2, C1-C4-alkylamino, di-C1-C4-alkylamino, pyrrolidinyl, piperidinyl or morpholinyl, R4 and R5 together form a group =CR12R13 or -CO-W-CO-, R12 is H, NH2, C1-C4-alkylamino or C3-C8-cycloalkylamino, R13 is NH2, C1-C4-alkylamino, di-C1-C4-alkylamino, C3-C8-cycloalkylamino, pyrrolidin-1-yl, piperidin-1-yl, morpholin-4-yl, unsubstituted or substituted phenyl or unsubstituted or substituted pyridyl and W is an unsubstituted or substituted ethylene or ethenylene bridge, an unsubstituted or substituted 5-membered or 6-membered 1,2-C-bonded aromatic or heteroaromatic bridge, or an unsubstituted or substituted 5-membered or 6-membered 1,2-C-bonded cycloalkylene or cycloalkenylene bridge, and the basic salts of the compounds I in which R3 is hydroxycarbonyl or hydroxythiocarbonyl, and the acidic salts of the compounds I which contain a basic nitrogen atom, with the exception of 1-phenyl- and 1-methyl-4-cyano-5-acylaminopyrazole, 1-methyl-4-cyano-5-(chloromethylcarbonylamino)-pyrazole, 1-methyl-4-cyano-5-(phenylcarbonylamino)-pyrazole, 1-methyl-4-cyano-5-(p-chlorophenylcarbonylamino)-pyrazole and the compounds I in which R1 is methyl, phenyl, 4-chlorophenyl or 4-nitrophenyl, R2 is hydrogen, methyl or trifluoromethyl, R3 is cyano and R4 and R5 are simultaneously hydrogen, and herbicides which contain 2-(4-hetaryloxy)- and 2-(4-aryloxy)-phenoxyacetic acid or -propionic acid derivatives and/or cyclohexenone derivatives as herbicidal active ingredients and substituted 5-aminopyrazoles I' or, in the case of acidic terminal groups or basic nitrogen atoms, the salts of I' as antidotes.

    18.
    发明专利
    未知

    公开(公告)号：DE59108668D1

    公开(公告)日：1997-05-22

    申请号：DE59108668

    申请日：1991-11-29

    Applicant: BASF AG

    Inventor： HAGEN HELMUT ,  NILZ GERHARD ,  WALTER HELMUT ,  LANDES ANDREAS ,  FREUND WOLFGANG

    IPC: A01N25/32 ,  A01N43/16 ,  A01N43/18 ,  A01N47/38 ,  C07D311/22

    Abstract: PCT No. PCT/EP91/02268 Sec. 371 Date Jun. 7, 1993 Sec. 102(e) Date Jun. 7, 1993 PCT Filed Nov. 29, 1991 PCT Pub. No. WO92/10489 PCT Pub. Date Jun. 25, 1992.2-Amino-4-oxo-4H-benzopyrans I I (m=0, 1 or 2; R1-R4 have the meanings stated in the description) and the salts of I, and herbicides which contain 2-(4-hetaryloxy)- and 2-(4-aryloxy)-phenoxyacetic acid derivatives and/or cyclohexenone derivatives as herbicidal active ingredients and 2-amino-4-oxo-4H-benzopyrans I' as antidotes.

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