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    Moulding materials based on polyethylene and having an antistatic finish
    19.
    发明专利
    Moulding materials based on polyethylene and having an antistatic finish 未知

    公开(公告)号：GB1103666A

    公开(公告)日：1968-02-21

    申请号：GB2561165

    申请日：1965-06-17

    Applicant: BASF AG

    Inventor： POHLEMANN HEINZ ,  CHRISTOPH HELMUT ,  STASSEN ALEXANDER ,  WEGERLE DIETER

    IPC: C08K5/20

    Abstract: Moulding materials based on polyethylene having a density of 0.915 to 0.940 g./cm.3 contain as an antistatic agent 0.01 to 5% by weight of an amide of the formula R-CONR1R2 in which R denotes an aliphatic hydrocarbon radical having 7-29 carbon atoms, R1 denotes H or R2, and R2 denotes the group -(A-O)m-(B-O)n-(D-O)pH, in which A, B and D are the same or different alkylene radicals of 2-4 carbon atoms, and the total of m+n+p is an integer of from 8-22 when R1 is H and an integer of from 4-11 when R1=R2. Additives such as fillers, dyes, light stabilizers, heat stabilizers, lubricants and anti-blocking agents (all unspecified) may also be included. Products such as film, sheeting, sections and household articles may be obtained from the moulding material which is generally in granular form.

    Stoving lacquers
    20.
    发明专利
    Stoving lacquers 未知

    公开(公告)号：GB1092545A

    公开(公告)日：1967-11-29

    申请号：GB830365

    申请日：1965-02-26

    Applicant: BASF AG

    Inventor： DAUMILLER GUENTHER ,  POHLEMANN HEINZ ,  SCHAUDER FRIEDRICH

    IPC: C08L61/04 ,  C09D133/08

    Abstract: A stoving lacquer contains (I) water, and (II) a mixture of (1) 65 to 75% by weight of at least one water-soluble salt of (a) at least one water-soluble volatile tertiary amine and (b) a copolymer comprising 82 to 88% isobutyl acrylate, 8 to 12% acrylic acid and 4 to 6% of N-(hydroxymethyl) methacrylamide, the sum of the percentages of these monomers being 100%, and (2) 35 to 25% of a water-soluble cocondensate of formaldehyde, a 1:3 to 1:6 by weight mixture of 2,2-bis-(p-hydroxyphenyl)-propane and phenol and, optionally, at least one alkanol having 1 to 4 carbon atoms. Suitable amines (a) are trimethylamine, tri-(b -hydroxyethyl) - amine, N,N - dimethyl - N - (b - hydroxypropyl) - amine, triethylamine and N,N - dimethyl - N - (b - hydroxyethyl) - amine. The lacquers may also contain organic solvents, e.g. monoalkyl ethers of diethylene and triethylene glycol, hexavalent chromium compounds, e.g. ammonium dichromate and pigments, e.g. TiO2. In examples, the lacquers are applied to sheet metal, exposed to air and stoved (see Division B2).ALSO:A stoving lacquer comprises (I) water and (II) a mixture of (1) 65 to 75% of at least one water soluble salt of (a) at least one water-soluble volatile tertiary amine and (b) a copolymer containing 82 to 88% isobutyl acrylate, 8 to 12% acrylic acid and 4 to 6% of N-(hydroxymethyl) methacrylamide and (2) 35 to 25% of a water soluble cocondensate of formaldehyde and a 1:3 to 1:6 mixture of 2, 2 bis - (p - hydroxyphenyl) - propane and phenol. Cocondensate (2) may also contain at least one alkanol having 1 to 4 carbon atoms. Suitable amines (a) are trimethylamine, tri-(b -hydroxyethyl)-amine, N, N-dimethyl-N-(b -hydroxyethyl)-amine, triethylamine and N, N-dimethyl-N- (b -hydroxypropyl)-amine. The lacquer may be applied to sheet metal e.g. by electrodeposition and stoved at 80 DEG to 180 DEG C.

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