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公开(公告)号:FR1502238A
公开(公告)日:1967-11-18
申请号:FR84657
申请日:1966-11-23
Applicant: BASF AG
Inventor: PRIEBE EDMUND , WEBER HEINZ , WILLERSINN HERBERT
IPC: C08K5/24
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公开(公告)号:FR1495352A
公开(公告)日:1967-09-15
申请号:FR78374
申请日:1966-09-30
Applicant: BASF AG
Inventor: NAARMANN HERBERT , KASTNING ERNST-GUENTHER , WILLERSINN HERBERT , PRIEBE EDMUND
IPC: C08F36/04
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公开(公告)号:CA1183984A
公开(公告)日:1985-03-12
申请号:CA395387
申请日:1982-02-02
Applicant: BASF AG
Inventor: BRANDSTETTER FRANZ , MUENCH VOLKER , NAARMANN HERBERT , PRIEBE EDMUND
IPC: C08L25/00 , C08K5/00 , C08L7/00 , C08L21/00 , C08L51/00 , C08L51/02 , C08L51/04 , C08L71/00 , C08L71/12 , C08L71/04
Abstract: Self-extinguishing molding materials, comprising (A) a polymer of a vinyl-aromatic compound, especially a styrene polymer, which has been made impact-resistant, (B) a polyphenylene ether and (C) a flameproofing additive, with or without (D) conventional additives, wherein one part of the soft component of the impact-resistant polymer of the vinyl-aromatic compound has a mean particle size of ? 1.5 .mu.m and the other part has a mean particle size of >3 .mu.m. Such molding materials not only have good self-extinguishing properties but also give moldings having a particularly uniform matt surface.
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公开(公告)号:CA1167583A
公开(公告)日:1984-05-15
申请号:CA394064
申请日:1982-01-13
Applicant: BASF AG
Inventor: BRANDSTETTER FRANZ , MCKEE GRAHAM E , PRIEBE EDMUND
IPC: C08L51/00 , C08L7/00 , C08L21/00 , C08L25/00 , C08L51/02 , C08L51/04 , C08L51/06 , C08L71/00 , C08L71/12 , C08L71/04
Abstract: O.Z.0050/034892 of the disclosure: The use of butyl acrylate in the preparation of the soft component of impactresistant polystyrene based on polystyrene-grafted butadiene mixed with polyphenylene ether reduces the dust attraction of moldings prepared from this type of mixture.
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公开(公告)号:CA858621A
公开(公告)日:1970-12-15
申请号:CA858621D
Applicant: BASF AG
Inventor: TRIESCHMANN HANS-GEORG , PRIEBE EDMUND , WILLERSINN HERBERT , SCHULLER HELMUT , WEBER HEINZ , HIRSCH GUENTHER
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公开(公告)号:GB1166290A
公开(公告)日:1969-10-08
申请号:GB5812466
申请日:1966-12-29
Applicant: BASF AG
Inventor: WILLERSINN HERBERT , PRIEBE EDMUND , KASTNING ERNST-GUENTHER , NAARMANN HERBERT
IPC: C08F279/02 , C08J9/00 , C08L15/02 , C08L25/04
Abstract: 1,166,290. Self-extinguishing thermoplastic compositions. BADISCHE ANILIN- & SODAFABRIK A.G. 29 Dec., 1966 [5 Jan., 1966], No. 58124/66. Headings C3C and C3P. A self-extinguishing thermoplastic composition having a bromine content of at least 0.1% by wt. consists of a thermoplastic polymer which contains more than 50% by wt. of styrene or a nuclear alkyl-substituted styrene and a polymer of butadiene and/or isoprene which has at least 50% of its base units combined by 1,2-linkages and which is brominated to a content of 40-75% by wt. of bromine. The styrene polymer may be polystyrene. In an example, a mixture of styrene and acrylonitrile was polymerized in an aq. mixture of benzoyl peroxide, barium sulphate and the brominated polyisoprene. In comparative examples brominated polymers of butadiene and isoprene having 1,4-linkages were used. Porous polymers are produced in the examples by polymerizing styrene in an aq. mixture of (A) polyvinylpyrrolidone and sodium pyrophosphate; (B) barium sulphate; or (C) a copolymer of N-vinyl-pyrrolidone and methyl acrylate, sodium pyrophosphate and a polymer of diisopropylbenzene; and pentane, benzoyl peroxide and the brominated polybutadiene and the polystyrene beads produced are preexpanded in steam and then formed into blocks by further steam treatment.
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公开(公告)号:FR1513291A
公开(公告)日:1968-02-16
申请号:FR73831
申请日:1966-08-23
Applicant: BASF AG
Inventor: BURGER HEINZ , MOHR HEINRICH , PRIEBE EDMUND , REUTER LOTHAR , WEBER HEINZ
Abstract: A self-extinguishing composition consists of (a) a normally solid thermoplastic homopolymer or copolymer of styrene which may be substituted by alkyl groups in the nucleus or side chain and which contains more than 50% by wt. of styrene or the substituted styrene having intimately incorporated therewith (b) an organic bromide having a plurality of bromine atoms attached to the carbon atoms and the bromine atoms constituting more than 40% of the bromide, in such an amount that the composition has a bromine content of 0.1-5%, and (c) 0.01-5% of (a) of a compound of formula where RA and RB are a phenyl radical which may be substituted by at least one C1- 3 aliphatic hydrocarbon radical, a C1- 4 alkoxy radical, Cl or Br; R1 and R2 are H, Cl, Br, a C1- 6 aliphatic hydrocarbon radical or cyclohexyl; R3 and R4 are Cl, Br, cyano, nitro, a C1- 6 aliphatic hydrocarbon radical or phenyl. The (a) polymer may be polystyrene and/or a copolymer of styrene and acrylonitrile. Compound (c) may be 2,3-diethyl - 2,3 - diphenylbutane; 2,2,3,3 - tetraphenylbutane or 2,3 - dimethyl - 2,3 - di - p - tolylbutane. The bromide (b) may be hexabromododecane, tris - (2,3 - dibromopropyl)-phosphate or tetrabromoethane. The composition may be made by dissolving the three components in methylene chloride. The composition may also contain a foaming agent, e.g. pentane, and may be formed into a foamed sheet.
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公开(公告)号:FR1507474A
公开(公告)日:1967-12-29
申请号:FR89950
申请日:1967-01-04
Applicant: BASF AG
Inventor: NAARMANN HERBERT , PRIEBE EDMUND , KASTNING ERNST-GUENTHER , WILLERSINN HERBERT , WEBER HEINZ
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公开(公告)号:IS1594A7
公开(公告)日:1966-10-08
申请号:IS1594
申请日:1966-08-24
Applicant: BASF AG
Inventor: BURGER HEINZ , MOGR HEINRICH , PRIEBE EDMUND , REUTER LOTHAR , WEBER HEINZ
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