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    Urea formaldehyde textile finishing agents and their production
    14.
    发明专利
    Urea formaldehyde textile finishing agents and their production 未知

    公开(公告)号：GB1077344A

    公开(公告)日：1967-07-26

    申请号：GB1171966

    申请日：1966-03-17

    Applicant: BASF AG

    Inventor： GRASSHOFF HANS JOACHIM ,  FIKENTSCHER ROLF ,  RUETTIGER WILHELM

    IPC: C08G12/00 ,  C08G12/12 ,  D06M15/423

    Abstract: A material which is readily soluble in water and suitable for textile finishing is a solid mixture which contains not >0.3% by wt. free HCHO and contains at least two of the components urea, monomethylol urea and dimethylolurea in such proportions that the molar ratio of free and combined urea to combined HCHO ranges from 1:1.4 to 1:1.85. The mixture may be obtained by reacting urea and HCHO in the molar ratio 1:1.4 to 1:1.85 in aqueous solution at pH 6.5 to 8.5 at 30 DEG to 40 DEG C for 1/2 to 5 hours. The reaction mixture is then cooled to 15 DEG to 28 DEG C. and stirred at this temperature for at least 24 hours; the crystal mash obtained is spray dried. The crystal mash may contain at least 30% by wt. of dry residue. The pH of the reaction may be controlled by use of an organic base of medium strength, e.g. triethanolamine.ALSO:Textile materials are rendered crease resistant by treating with an aqueous soln. of a solid mixture which contains not >0.3% by wt. free HCHO and contains at least two of the components urea, monomethylolurea and dimethylolurea in such proportions that the molar ratio of free and combined urea to combined HCHO ranges from 1:1.4 to 1:1.85. The mixture may be obtained by reacting urea and HCHO in the molar ratio 1:1.4 to 1:1.85 in aqueous soln. at pH 6.5 to 8.5, at 30 to 40 DEG C for 1/2 to 5 hours. The reaction mixture is then cooled to 15 to 28 DEG C and stirred at this temp. for at least 24 hours; the crystal mash obtained is spray dried.

    Sizing yarns
    15.
    发明专利
    Sizing yarns 未知

    公开(公告)号：GB1072878A

    公开(公告)日：1967-06-21

    申请号：GB3686565

    申请日：1965-08-27

    Applicant: BASF AG

    Inventor： WOLF HANS ,  RUETTIGER WILHELM ,  GULBINS KLAUS

    IPC: D06M15/263 ,  D06P1/00 ,  D06P5/13

    Abstract: Coloured copolymers used in the sizing of textile materials comprise (a) 72 parts of ethyl acrylate, 10 parts of acrylamide, 7 parts of acrylic acid, 5 parts of methyl methacrylate and 6 parts of a dye having the formula which has been neutralized with caustic soda solution or (b) 70 parts of ethyl acrylate, 7 parts of methyl acrylate, 10 parts of acrylamide, 7 parts of acrylic acid and 6 parts of a dye having the formula which has been neutralized with caustic soda solution, the parts being by weight.ALSO:Yarns, filaments and threads of all types, e.g. of viscose rayon, cellulose acetate, polyesters, cotton, wool, polypropylene or polyacrylonitrile, are sized with a water-soluble film forming addition polymer which is combined with a dye by a covalent bond. Solubility in water is defined as the ability to form true or colloidal solutions with water. The coloured polymers which may subsequently be removed by washing may be water-soluble copolymers of olefinically unsaturated polymerisable colourless compounds and dyes bearing vinyl groups or water-soluble homopolymers or copolymers of olefinically unsaturated polymerisable colourless compounds which by virtue of reactive groups are combined with dyes which bear reactive groups. Water soluble copolymers prepared from (a) azo dyes or anthraquinone dyes which bear a vinyl group, of which numerous examples are given, as the coloured monomers, (b) water soluble monomers, e.g. acrylic, methacrylic, maleic or fumaric acids or their alkali metal or ammonium salts or amides, N-vinyl pyrrolidone, vinyl ethers, and 2-vinyl pyridine, N-vinyl-imidazole and 2-aminoethyl acrylate and salts and quaternisation products thereof, and optionally (c) monomers which form water-insoluble homopolymers, e.g. esters of acrylic, methacrylic, maleic or fumaric acid, acrylonitrile, vinyl esters, p vinyl or vinylidene chloride, styrene, butadiene, ethylene and propylene, may be used, the proportion of coloured monomer preferably being 1-8% by weight. Alternatively the coloured polymer may be prepared from a polymer formed from monomers which bear reactive groups which do not react under the conditions of the polymerisation, e.g. monomers having methylolamide groups and lower ethers thereof such as N-methylol acrylamide, and dyes bearing complementary reactive groups, e.g. carbamoyl groups or chlorine atoms, examples of which are given. The term "dye" is intended to include compounds which are exclusively or mainly absorbent and fluorescent in ultra-violet light.

    Production of dimensionally stable and shape-retaining garments of cellulosic fabrics
    18.
    发明专利
    Production of dimensionally stable and shape-retaining garments of cellulosic fabrics 未知

    公开(公告)号：GB1141515A

    公开(公告)日：1969-01-29

    申请号：GB5287166

    申请日：1966-11-25

    Applicant: BASF AG

    Inventor： BILLE HEINZ ,  RUETTIGER WILHELM

    IPC: D06M15/423

    Abstract: 1,141,515. Mixed aminoplast textile treating compositions. BADISCHE ANILIN- & SODAFABRIK A.G. 25 Nov., 1966 [27 Nov., 1965; 8 June, 1966], No. 52871/66. Heading C3R. [Also in Division D1] A composition suitable for use in the treatment of cellulosic fabrics comprises (a) at least one poly-N-methylol compound which condenses at a temperature less than 140‹ C., (b) at least one poly-N-methylol compound which condenses at a temperature of at least 140‹ C. and (c) at least one acid curing catalyst which forms an acid under the conditions of condensation. The poly-N-methylol compounds contain two or more hydroxymethyl or alkoxymethyl groups having 1-5 carbon atoms in the alkoxy group which are attached to nitrogen. The compounds (a) may have the formula in which each R 1 is a hydrogen atom or when taken together the two substituents R 1 denote and the substituents R 2 which may be the same or different are hydrogen atoms or alkyl groups having 1-4 carbon atoms and the compounds (b) may have the formula or in which R 3 is a hydrogen atom or alkyl group having 1-4 carbon atoms, R 4 is R 5 is a hydrogen atom, an alkyl group having 1-4 carbon atoms or a group of the formula R 3 O-CH 2 -, R 6 is an alkylene group having 2-4 carbon atoms, R 7 is methyl or ethyl and n is 0 or 1, the compounds containing at least two R 3 O-CH 2 - groups. The acid curing catalyst may be aluminium sulphate, zinc chloride, zinc nitrate, ammonium chloride, ammonium nitrate, ammonium phosphate and salts of ethanolamine, diethanolamine, 2- hydroxy - 2 - methylpropylamine with hydrochloric acid, magnesium chloride and magnesium sulphate. The compounds (a), (b) and (c) may be applied to the fabrics from an aqueous bath which may also contain wetting agents, e.g. salts of alkylnaphthalene sulphonic acids, alkali metal salts of sulphonated dioctyl succinate and adducts of alkylene oxides with fatty alcohols, alkyl phenols or fatty amines, water repelling agents, e.g. paraffin wax emulsions containing aluminium or zirconium, silicon containing formulations and perfluorinated aliphatic compounds, softeners, e.g. ethenoxylation products of high molecular weight fatty acids, fatty alcohols or fatty amides, high molecular weight polyglycol ethers and esters thereof, high molecular weight fatty acids, fatty alcohol sulphonates, stearyl-N,N-ethyleneurea and stearylamidomethyl pyridimium chloride, finishes, e.g. cellulose ethers and esters, alginates, polyamides, ether-oxylated polyamides, polyvinyl ethers, polyvinyl alcohol, polyacrylic or methacrylic acid or esters or amides thereof, polyvinyl propionate, polyvinyl pyrrolidone, copolymers of vinyl chloride and acrylic esters, butadiene and styrene or acrylonitrile, α-dichloroethylene, #-chloroalkyl acrylic esters or vinyl-#-chloroethyl ether and acrylamide or amides of crotonic or maleic acid, or N-methylolmethacrylamide and other polymerizable compounds, or polyethylene, and optical brighteners. In examples the aminoplast mixtures are: dimethylol ethyleneurea plus (1) dimethylol glyoxal monoureine or (2) dimethylol ethyl - urethane or (4) dimethylol urea and dimethylol glyoxal monoureine; or (3) dimethylol propyleneurea plus dimethylol 4-methoxy-5: 5- dimethylpropyleneurea; or (5) dimethylol glyoxal monoureine plus dimethylol 5-isobutyl hexahydro - 1: 3: 5 - triazinone - 2. These are used in aqueous solution containing MgCl 2 or Mg(SO 4 ) 2 and optionally polyethylene emulsion and/or a copolymer of butyl acrylate/butylene diacrylate / methylol methacrylamide / acrylamide and optionally ethoxylated iso-octylphenol.

    Improving cellulosic fibrous materials
    19.
    发明专利
    Improving cellulosic fibrous materials 未知

    公开(公告)号：GB1081039A

    公开(公告)日：1967-08-31

    申请号：GB5012465

    申请日：1965-11-25

    Applicant: BASF AG

    Inventor： PETERSEN HARRO ,  RUEMENS WILHELM ,  RUETTIGER WILHELM ,  FEINAUER ANTON

    IPC: D06M15/423

    Abstract: An aqueous polymer dispersion suitable for use in the treatment of textiles is prepared by mixing while stirring a solution of methylolmethacrylamide dissolved in butylacrylate with a solution of potassium persulphate and the sodium salt of a paraffinsulphonic acid (C12-C18) in water at 80 DEG C. and holding the mixture at 80-90 DEG C. for about an hour, after the addition of further quantities of monomers, persulphate and sulphonate.ALSO:Cellulosic fibrous materials are crease-proofed, by impregnating them with an aqueous solution or dispersion of a substance having a molecular weight of up to 350 containing at least one N-methylol group and/or N-methylol ether group and with an aqueous solution or dispersion of an acid or potentially acid catalyst and reacting the N-methylol groups and N-methylol ether groups with each other, with other groups of the substances bearing them and/or with the cellulosic material in the presence of trioxane in an amount of 0.1-4 times the total molar amount present of the N-methylol groups and N-methylol ether groups. Suitable compounds containing N-methylol groups or N-methylol ether groups are those derived from compounds having the formulae:- in which X is a sulphur or oxygen atom, R1 and R2 are alkyl radicals having 1-5 carbon atoms, hydrogen atoms or radicals having the formulae, which are connected together directly or via radicals having the formula or is an alkyl radical having 1-5 carbon atoms, an aryl radical or a hydrogen atom, R4 is an alkyl group having 1-5 carbon atoms, a hydrogen atom, a hydroxy group or an alkoxy group having 1-5 carbon atoms or if the two groups are connected together direct, both R4 groups together may form the radical , R5 is an alkyl radical having 1-5 carbon atoms or a hydrogen atom, R6 is an alkoxy group having 1-5 carbon atoms, a hydrogen atom or a hydroxy group, R7 is a hydrogen atom or an alkyl or hydroxyalkyl radical having 1-5 carbon atoms, R8 is a hydrogen atoms an alkyl group having 1-5 carbon atoms or a radical of the formula -NHR11 and R9, R10 and R11 are alkyl groups having 1-5 carbon atoms or hydrogen atoms, or of the formula:- in which R12 and R13 are hydrogen atoms or alkyl radicals having 1-5 carbon atoms, A is a divalent hydrocarbon radical having 2 - 8 carbon atoms, x = 0 or 1, y = 0 or 1, z = 0 or 1 and (x + y) = 1 or 2. Reaction may be effected by drying the impregnated material and then heating to a temperature of up to 180 DEG C or by drying at an elevated temperature and then maintaining the material at a temperature of about 60 DEG C for 4 - 10 hours. The materials may be mechanically shaped, e.g. by compression, crimping, goffering, ironing, calendering, embossing or pleating, during or after drying and rendered permanent by the reaction. The treating liquor may also contain wetting agents, water repellents, e.g. paraffin wax emulsions containing aluminium or zirconium, silicones or perfluorinated aliphatic compounds, plasticizing agents, e.g. ethenoxylation products of high molecular weight fatty acids, alcohols or acid amides, high molecular weight polyglycol ethers and esters thereof, high molecular weight fatty acids, fatty alcohol sulphonates, stearyl-N, N-ethylenurea and stearylaminomethyl pyridinium chloride and finishing agents, e.g. cellulose esters or ethers, alginates, polyamides, polyvinyl ethers, polyvinyl alcohol, polyacrylic or polymethacrylic acid or esters or amides thereof, polyvinyl propionate, polyvinyl pyrrolidone, copolymers of vinyl chloride and acrylic esters, butadiene and styrene or acrylonitrile, a -dichloroethylene, b -chloroalkylacrylic esters or vinyl-b -ethyl ethers and acrylamide or the amides of crotonic or maleic acid or of N-methylolmethacrylamide, isocyanates, diisocyanates, polyethylenimines, polyamines, ethenoxylated polyamides, silicic esters and dyes which are azo compounds and contain metals, e.g. chromium, cobalt or copper, combined therein. Threads, filaments, fibres, bands, non-woven knitted, woven or netted fabrics comprising cotton, linen or regenerated cellulose fibres alone or in admixture with wool, silk, cellulose ester, acrylonitrile, polyamide, polyester or polyolefin fibres may be treated. In Example 8 cotton is simultaneously dyed with an acid dye Acid blue 158.

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