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    Emulsifiers for dye emulsions of the water-in-oil type
    11.
    发明专利
    Emulsifiers for dye emulsions of the water-in-oil type 未知

    公开(公告)号：GB998311A

    公开(公告)日：1965-07-14

    申请号：GB1336664

    申请日：1964-04-01

    Applicant: BASF AG

    Inventor： BLUM ADOLF ,  UHL GUENTER ,  SANNE WALTER

    IPC: C09B67/46 ,  D06P1/645 ,  D06P1/649 ,  D06P1/92

    Abstract: An emulsifier composition for a water-in-oil dye emulsion comprises (a) a hydroxyalkylamide having 16-19 C atoms in the carboxylic acid radical, and (b) a hydroxyalkylamine having up to 6 C atoms. The specified components (a) are oleic di- and mono-ethanolamide, linseed oil fatty acid diethanolamide, tallow fatty acid isopropanolamide and amides derived from palmitic, margaric and stearic acid and mixtures of synthetic acids with monopropanolamine, diisopropanolamine, butanolamine and methylisobutanolamine, and (b) are mono-, di- and tri-ethanolamine, diethanolethylamine, mono- and di-iso-propanolamine, isobutanolamine and methylisobutanolamine. Dye emulsions may be prepared by dissolving the emulsifier composition in a solvent and stirring in the aqueous dye liquor. Specified solvents are hydrocarbons (many examples of aliphatic, cycloaliphatic and aromatic type, commerical mixtures thereof, terpenes), carbon tetrachloride, di-, tri- and tetrachloroethane, mono-chlorobenzene, methyl isobutyl ketone, mesityl oxide, diacetone alcohol, methyl cyclohexanone and isopropyl ether. Specified dye types are vat, sulphur, carbazole, acid, dispersion, metal complex, developed (azoic) and reactive dyes, examples of some being given. Other specified components are thickeners (alginate, carob flour and starch ether), sodium formaldehyde sulphoxylate and potassium carbonate. Specifications 733,099, 759,293 and 768,745 are referred to.ALSO:An emulsifier for a water-in-oil dye emulsion comprises (a) a hydroxyalkyl-amide having 16-19 C-atoms in the carboxylic acid radical and (b) a hydroxyalkylamine having up to 6-C atoms. Suitable dyes are vat, sulphur, acid, disperse, metal complex, reactive and developed (azoic) dyes. Many suitable solvents are specified for the outer phase including hydrocarbon. Solvents with boiling ranges from 120 DEG C. up to 190 DEG C. The specified components (a) include oleic di- and monoethanolamide, linseed oil fatty acid diethanolamide, tallow fatty acid isopropanolamide and (b) include di- and triethanolamine and diisopropanolamine. The emulsion may be prepared by dissolving the emulsifier in e.g. gasoline (boiling range 160-200 DEG C.) and stirring in the aqueous dye liquor. Examples are given. Specifications 733,099, 759,293 and 768,745 are referred to.

    N-substituted morpholines having fungicidal activity
    12.
    发明专利
    N-substituted morpholines having fungicidal activity 未知

    公开(公告)号：GB988630A

    公开(公告)日：1965-04-07

    申请号：GB646262

    申请日：1962-02-20

    Applicant: BASF AG

    Inventor： SANNE WALTER ,  KOENIG KARL-HEINZ ,  POMMER ERNEST-HEINRICH ,  STUMMEYER HERBERT

    IPC: C07D263/04 ,  C07D295/02 ,  C07D295/03 ,  C07D295/033

    Abstract: The invention comprises compounds of the general formula and salts and molecular or addition compounds thereof, in which R1 denotes a cyclalkyl radical with more than 6 annular carbon atoms or a tridecyl or alkyl-phenyl radical, R2, R3, R4 and R5 may be identical or different, each denoting an unsubstituted or substituted methylene radical, the substituents being one or two methyl and/or ethyl and/or phenyl groups, with the proviso that, when R1 represents a tridecyl or an alkyl-phenyl radical, at least one of the radicals R2, R3, R4 and R5 is a substitute methylene radical as defined above. The compounds may be prepared by (a) reaction of primary amines or alkanolamines with alkylene oxides to form dialkanolamines which are then cyclised by treatment with dehydrating agents, (b) hydrogenating amination of ketones with primary amino alcohols to form N-substituted alkanolamines which are then reacted with alkylene oxides and cyclised as described above, or (c) reaction of unsubstituted or substituted 2,21-dichloroalkyl ethers with primary amines in the presence of acid-binding agents. The morpholine salts may be prepared by mixing the initial materials, optionally in the presence of solvents, or by treatment of N-substituted dialkanolamines with thionyl halides. The preparation of N-bis-(2-hydroxypropyl)-tridecylamine is described. Many other compounds of the invention are listed. The compounds are fungicides (see Division A5).ALSO:Fungicidal compositions comprise an inert carrier or diluent and a compound of the general formula or salts, or molecular or addition compounds thereof, wherein R1 denotes a cycloalkyl radical with more than 6 annular carbon atoms or a tridecyl or alkyl-phenyl radical, R2, R3, R4 and R5 may be identical or different, each denoting an unsubstituted or substituted methylene radical, the substituents being one or two methyl and/or ethyl and/or phenyl groups, with the proviso that, where R1 represents a tridecyl or an alkyl-phenyl radical, at least one of the radicals R2, R3, R4 and R5 is a substituted methylene radical as defined above (see Division C2). The compositions may be in the form of (a) dusting powders containing inert pulverulent carriers or diluents, (b) solid or liquid compositions for the production of sprays containing inert dispersing agents, wetting agents, adhesives or emulsifiers, or (c) admixtures with other fungicides and/or insecticides. Examples are given.

    FUNGICIDAL AGENT
    20.
    发明专利
    FUNGICIDAL AGENT 未知

    公开(公告)号：CS180631B2

    公开(公告)日：1978-01-31

    申请号：CS262274

    申请日：1974-04-11

    Applicant: BASF AG

    Inventor： POMMER ERNST-HEINRICH ,  KRADEL JUERGEN ,  KOENIG KARL-HEINZ ,  SANNE WALTER

    IPC: A01N47/14 ,  A01N20060101 ,  A01N43/84 ,  A01P3/00 ,  A01N9/02

    Abstract: A fungicidal composition comprising N-tridecyl-2,6-dimethylmorpholine in combination with a compound selected from the group consisting of manganese ethylenebisdithiocarbamate, manganese zinc ethylenediaminebisdithiocarbamate and an ammonia complex of zinc-(N,N alkylenebisdithiocarbamate) and N,N'-polyethylene bis-(thiocarbamoyl)-disulfide which has a strong synergistic fungicidal action, and a process for controlling the spread of fungi, i.e. inhibiting the growth of fungi, with this composition.

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