公开(公告)号：US3449414A

公开(公告)日：1969-06-10

申请号：US3449414D

申请日：1966-04-19

Applicant: BASF AG

Inventor： BOETTGER GUENTHER ,  GUENTHERT PAUL ,  KINDLER HUBERT ,  STANGER HANS

IPC: C07C20060101 ,  C07C101/26

公开(公告)号：GB948695A

公开(公告)日：1964-02-05

申请号：GB909162

申请日：1962-03-09

Applicant: BASF AG

Inventor： NEBEL HANS-JOACHIM ,  STANGER HANS ,  HERTEL OTTO ,  PALM ALBERT

IPC: C07C309/35 ,  C07C309/36 ,  C07C309/43 ,  C07C311/00 ,  C07G99/00 ,  C14C3/08 ,  C14C3/20

Abstract: Condensation of naphthalenesulphonic acids with aldehydes or with substances yielding aldehydes in an acid medium, to give products containing two or three napthalenesulphonic acid groups linked by aldehyde residues, is effected above 100 DEG C. at increased hydrostatic pressure. Preferred reactants are the 2-sulphonic acid and formaldehyde (or paraformaldehyde, hexamethylenetetramine or trioxymethylene) but the 1-sulphonic acid, the 1,6- ,2,6- and 2,7-disulphonic acids, acetaldehyde, paraldehyde, propionaldehyde, butyraldehyde, glyoxal and furfural are also mentioned.

公开(公告)号：FR1345389A

公开(公告)日：1963-12-06

申请号：FR921182

申请日：1963-01-11

Applicant: BASF AG

Inventor： STANGER HANS ,  FUST KLAUS JUERGEN ,  STOLZE FRIEDRICH

IPC: B03D1/01

公开(公告)号：CA763506A

公开(公告)日：1967-07-18

申请号：CA763506D

Applicant: BASF AG

Inventor： STANGER HANS ,  SANNE WALTER

公开(公告)号：FR1477228A

公开(公告)日：1967-04-14

申请号：FR58903

申请日：1966-04-25

Applicant: BASF AG

Inventor： BOETTGER GUENTER ,  GUENTHERT PAUL ,  KINDLER HUBERT ,  STANGER HANS

公开(公告)号：FR1403592A

公开(公告)日：1965-06-18

申请号：FR984662

申请日：1964-08-08

Applicant: BASF AG

Inventor： SCHENK WALTER ,  STANGER HANS

IPC: B01J19/12 ,  C07C309/80

公开(公告)号：CA698751A

公开(公告)日：1964-11-24

申请号：CA698751D

Applicant: BASF AG

Inventor： SANNE WALTER ,  STANGER HANS

公开(公告)号：BE608204A

公开(公告)日：1962-03-15

申请号：BE608204

申请日：1961-09-15

Applicant: BASF AG

Inventor： STADLER JOSEF ,  THEWIS JOSEF ,  STANGER HANS ,  SANNE WALTER

公开(公告)号：GB1066253A

公开(公告)日：1967-04-26

申请号：GB3196264

申请日：1964-08-06

Applicant: BASF AG

Inventor： SCHENK WALTER ,  STANGER HANS

IPC: B01J19/12 ,  C07C309/80

Abstract: b -Chloroethane sulphochloride is prepared by reacting ethane, SO2 and Cl2 under the action of high-energy radiation and/or in the presence of substances forming free radicals and in the presence of an inert solvent, and then fractionally distilling the reaction mixture, at least 1 mole of SO2 and at least 2 moles of Cl2 being used for each mole of ethane. The solvent may be the reaction mixture obtained in a previous reaction. Hydrogen chloride gas may be passed in at the beginning of the reaction. In examples, CHCl2-CH3, CCl3-CH3, CHCl2-CH2Cl, CCl3-CH2Cl and C2H5SO2Cl are obtained as by-products. b -Chloroethane sulphochloride may be reacted with methanolic caustic soda solution to give methyl vinylsulphonate.

公开(公告)号：CA757666A

公开(公告)日：1967-04-25

申请号：CA757666D

Applicant: BASF AG

Inventor： GUENTHERT PAUL ,  STANGER HANS ,  BOETTGER GUENTER ,  KINDLER HUBERT