11.
    发明专利
    未知

    公开(公告)号:DE3222912A1

    公开(公告)日:1983-12-22

    申请号:DE3222912

    申请日:1982-06-18

    Applicant: BASF AG

    Abstract: An insoluble biocatalyst is prepared by forming a mixture consisting essentially of the biocatalyst, one or more water-soluble compounds having two or more acrylamide or meth-acrylamido groups and one or more water soluble amines possessing two or more hydrogen atoms bonded to an amine nitrogen, and forming a gel from the mixture. The water-soluble amine is selected from ammonia, lower diamines, lower polyamines, primary monoamines, polyethyleneimine and polyvinylamine. Beads containing the biocatalyst may be formed by suspending the mixture in a water-immiscible solvent to form droplets prior to gelling. The biocatalyst may be an enzyme, cells or cell fragments.

    13.
    发明专利
    未知

    公开(公告)号:DE2834539A1

    公开(公告)日:1980-02-21

    申请号:DE2834539

    申请日:1978-08-07

    Applicant: BASF AG

    Abstract: A macroporous crosslinked styrene resin, used as a carrier for covalently binding proteins, which resin contains isocyanate, thioisocyanate or aldehyde groups as protein-binding groups and may or may not contain sulfonic acid groups-which may also be in the form of the sodium salt or of sulfonic acid amide groups-as hydrophilic groups. The carrier according to the invention is prepared from a sulfochlorinated macroporous crosslinked styrene resin by reacting the sulfonic acid chloride groups with an alpha , omega -diamino compound, with hydrazine or with an alpha , omega -diamino-diether, converting any sulfonic acid chloride groups which may still be present to free sulfonic acid groups, their sodium salt or a sulfonamide group, and then reacting the terminal amino groups with phosgene, thiophosgene or a diisocyanate in order to produce the binding groups, which in turn fix a biologically active protein by covalent bonds.

    Textile detergents contg. water-insoluble cation-exchangers - prepd. by polymerizing mixt. contg. (meth)acrylic acid

    公开(公告)号:DE2327249A1

    公开(公告)日:1974-12-19

    申请号:DE2327249

    申请日:1973-05-29

    Applicant: BASF AG

    Abstract: Textiles are washed with phosphate-free or -deficient detergent compsns. contng. water-insoluble, solid, powdery cation exchangers having a Ca-bonding power >=80 (>=120) mg. CaO/g. through COOH gps. in alkali salt form, and prepd. by (a) polymerising a monomer mixt. contng. (i) acrylic and/or methacrylic acid or alkali salts and (ii) acrylamide and/or methacrylamide and HCHO (condensates) opt. with NH3 and/or (iii) (meth)acrylamide and cpds. contg. >=2 N-methylol gps. in molecule and/or (iv) N-methylol-(meth)acrylamide or its ethers with 1-6C alkanols, in an aq. medium contng. a radical former, at 180 (100-160) degrees C., with cross-linking and removal of water from polymer obtd.; and (b) communiting polymer to particle size 0.8 mm. Conversion of COOH gps. to alkali salt form takes place, if necessary, before or after (b). Environmental pollution and drinking water contamination are prevented.

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